| Abstract: | The design and fabrication of fiber based ammonia sensors employing Bromothymol blue and Chitosan as sensing elements are presented in this paper. In the presence of ammonia gas the absorption of Bromothymol blue changes while in the case of Chitosan the refractive index changes which in turn modulates the intensity of light propagating through a fiber. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/2042 |
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| Comparative performance of two...pdf | (162.7Kb) |
| Abstract: | This study was conducted to identify the concentration dependence of the operating wavelengths and the relative intensities in which a dye mixture doped polymer optical fibre can operate. A comparative study of the radiative and Forster type energy transfer processes in Coumarin 540:Rhodamine 6G, Coumarin 540:Rhodamine B and Rhodamine 6G:Rhodamine B in methyl methacrylate (MMA) and poly(methyl methacrylate) (PMMA) was done by fabricating a series of dye mixture doped polymer rods which have two emission peaks with varying relative intensities. These rods can be used as preforms for the fabrication of polymer optical fibre amplifiers operating in the multi-wavelength regime. The 445 nm line from an Nd:YAG pumped optical parametric oscillator (OPO) was used as the excitation source for the first two dye pairs and a frequency doubled Nd:YAG laser emitting at 532 nm was used to excite the Rh 6G:Rh B pair. The fluorescence lifetimes of the donor molecule in pure form as well as in the mixtures were experimentally measured in both monomer and polymer matrices by time-correlated single photon counting technique. The energy transfer rate constants and transfer efficiencies were calculated and their dependence on the acceptor concentration was analysed. It was found that radiative energy transfer mechanisms are more efficient in all the three dye pairs in liquid and solid matrices. |
| URI: | http://dyuthi.cusat.ac.in/purl/2421 |
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| Dyuthi-P0269.pdf | (903.9Kb) |
| Abstract: | A comparative study of two biopolymer based fiber optic humidity sensors is presented in this paper. Sensing elements Agarose and Chitosan swells in the presence of water vapour and undergoes changes in refractive index and modulates the intensity of light propagating through a fiber with Agarose or Chitosan as cladding. |
| URI: | http://dyuthi.cusat.ac.in/purl/2590 |
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| Dyuthi-P0150.pdf | (563.6Kb) |
| Abstract: | The principal objective of this study was to explore the compatibility of a blend of two synthetic elastomers viz., ethylene-propylene-diene rubber (EPDM) and chlorobutyl rubber (CIIR). Various commercial grades of EPDM were blended with a specific grade of CIIR at different proportions. The mechanical properties such as tensile strength, tear strength, ageing resistance, etc. were studied. On the basis of the observed physical properties, two particular grades of EPDM were found to be compatible with CIIR. Differential scanning calorimetry and scanning electron microscopy confirmed the results. Chlorosulphonated polyethylene was added as a compatibilizing agent to overcome the phase separation of the other two incompatible grades of EPDM in blending with CIIR. The results revealed that the addition of compatibilizer greatly improves the compatibility and thereby the properties of the blends. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/2001 |
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| Compatibility studies on....pdf | (403.3Kb) |
| Abstract: | n this paper, a time series complexity analysis of dense array electroencephalogram signals is carried out using the recently introduced Sample Entropy (SampEn) measure. This statistic quantifies the regularity in signals recorded from systems that can vary from the purely deterministic to purely stochastic realm. The present analysis is conducted with an objective of gaining insight into complexity variations related to changing brain dynamics for EEG recorded from the three cases of passive, eyes closed condition, a mental arithmetic task and the same mental task carried out after a physical exertion task. It is observed that the statistic is a robust quantifier of complexity suited for short physiological signals such as the EEG and it points to the specific brain regions that exhibit lowered complexity during the mental task state as compared to a passive, relaxed state. In the case of mental tasks carried out before and after the performance of a physical exercise, the statistic can detect the variations brought in by the intermediate fatigue inducing exercise period. This enhances its utility in detecting subtle changes in the brain state that can find wider scope for applications in EEG based brain studies. |
| URI: | http://dyuthi.cusat.ac.in/purl/2602 |
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| Dyuthi-P0162.pdf | (1.121Mb) |
| Abstract: | We show numerically that direct delayed optoelectronic feedback can suppress hysteresis and bistability in a directly modulated semiconductor laser. The simulation of a laser with feedback is performed for a considerable range of feedback strengths and delays and the corresponding values for the areas of the hysteresis loops are calculated. It is shown that the hysteresis loop completely vanishes for certain combinations of these parameters. The regimes for the disappearance of bistability are classified globally. Different dynamical states of the laser are characterized using bifurcation diagrams and time series plots. |
| URI: | http://dyuthi.cusat.ac.in/purl/2531 |
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| Dyuthi-P0106.pdf | (671.3Kb) |
| Abstract: | Cryptosystem using linear codes was developed in 1978 by Mc-Eliece. Later in 1985 Niederreiter and others developed a modified version of cryptosystem using concepts of linear codes. But these systems were not used frequently because of its larger key size. In this study we were designing a cryptosystem using the concepts of algebraic geometric codes with smaller key size. Error detection and correction can be done efficiently by simple decoding methods using the cryptosystem developed. Approach: Algebraic geometric codes are codes, generated using curves. The cryptosystem use basic concepts of elliptic curves cryptography and generator matrix. Decrypted information takes the form of a repetition code. Due to this complexity of decoding procedure is reduced. Error detection and correction can be carried out efficiently by solving a simple system of linear equations, there by imposing the concepts of security along with error detection and correction. Results: Implementation of the algorithm is done on MATLAB and comparative analysis is also done on various parameters of the system. Attacks are common to all cryptosystems. But by securely choosing curve, field and representation of elements in field, we can overcome the attacks and a stable system can be generated. Conclusion: The algorithm defined here protects the information from an intruder and also from the error in communication channel by efficient error correction methods. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/2007 |
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| A Cryptosystem using....pdf | (93.25Kb) |
| Abstract: | Photothermal deflection technique was used for determining the laser damage threshold of polymer samples of teflon (PTFE) and nylon. The experiment was conducted using a Q-switched Nd-YAG laser operating at its fundamental wavelength (1-06μm, pulse width 10 nS FWHM) as irradiation source and a He-Ne laser as the probe beam, along with a position sensitive detector. The damage threshold values determined by photothermal deflection method were in good agreement with those determined by other methods. |
| URI: | http://dyuthi.cusat.ac.in/purl/2629 |
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| Dyuthi-P0188.pdf | (288.5Kb) |
| Abstract: | Four distinct peaks are observed at 140, -26, -132 and -140°C in the sigma x* against T-1 plot between 200 and - 196°C for (NH4)3H(SO4)2, corresponding to four different phase transitions of which the one at -26°C is reported here for the first time. Data on doped samples reveal the charge transport mechanism in the crystal. |
| URI: | http://dyuthi.cusat.ac.in/purl/2424 |
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| Dyuthi-P0278.pdf | (326.3Kb) |
| Abstract: | Here we report measurements of third-order susceptibility χ(3), figure of merit F defined as χ(3)/α (where α is the absorption coefficient) and second hyperpolarizability 〈γ〉 of some metal substituted phthalocyanines and a naphthalocyanine in solutions of dimethyl formamide using degenerate four wave mixing at 532 nm under nanosecond excitation. It was found that among samples investigated, bis-naphthalocyanine possessed the highest value of 〈γ〉 followed by the bis-phthalocyanine. This observation is explained on the basis that bis-naphthalocyanine followed by bis-phthalocyanine has higher degree of π electron conjugation. |
| URI: | http://dyuthi.cusat.ac.in/purl/2410 |
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| Dyuthi-P0238.pdf | (107.3Kb) |
| Abstract: | The density of states and the low temperature specific heat of higb-Tc superconductors are calculated in a functional integral formalism using the slave boson technique. The manybody calculation in a saddle point approximation shows that the Iow energy sector is dominated by 3 single band. The calculated values of density of states are in good agreement with experimental results. |
| URI: | http://dyuthi.cusat.ac.in/purl/2563 |
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| Dyuthi-P0122.pdf | (304.2Kb) |
| Abstract: | The design and development of a cost-effective, simple, sensitive and portable LED based fiber optic evanescent wave sensor for simultaneously detecting trace amounts of chromium and nitrite in water are presented. In order to obtain the desired performance, the middle portions of two multimode plastic clad silica fibers are unclad and are used as the sensing elements in the two arms of the sensor. Each of the sensor arms is sourced by separate super bright green LEDs, which are modulated in a time-sharing manner and a single photo detector is employed for detecting these light signals. The performance and characteristics of this system clearly establish the usefulness of the technique for detecting very low concentrations of the dissolved contaminants. |
| URI: | http://dyuthi.cusat.ac.in/purl/2594 |
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| Dyuthi-P0154.pdf | (176.0Kb) |
| Abstract: | This article reports a new in vitro bile analysis based on the measurement of the dielectric properties at microwave frequencies. The measurements were made using rectangular cavity perturbation technique at the S-band of microwave frequency with the different samples of bile obtained from healthy persons as well as from patients. It is observed that an appreciable change in the dielectric properties of patient’s samples with the normal healthy samples and these measurements were in good agreement with clinical analysis. These results prove an alternative in-vitro method of detecting bile abnormalities based on the measurement of the dielectric properties of bile samples using microwaves without surgical procedure. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/2049 |
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| Detection of biliary functional...pdf | (162.2Kb) |
| Abstract: | A pulsed Nd-YAG laser beam is used to produce a transient refractive index gradient in air adjoining the plane surface of the sample material. This refractive index gradient is probed by a continuous He-Ne laser beam propagating parallel to the sample surface. The observed deflection signals produced by the probe beam exhibit drastic variations when the pump laser energy density crosses the damage threshold for the sample. The measurements are used to estimate the damage threshold for a few polymer samples. The present values are found to be in good agreement with those determined by other methods. |
| URI: | http://dyuthi.cusat.ac.in/purl/2439 |
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| Dyuthi-P0302.pdf | (343.3Kb) |
| Abstract: | We describe the synthesis of diblock and triblock copolymers by sequential atom transfer radical polymerization of styrene and acetoxymethylstyrene. Contrary to the usual block copolymerization involving isolation of the macroinitiator, a convenient one-pot procedure is developed. This is possible because of the preferential polymerization of acetoxymethylstyrene, even in the presence of residual styrene, as inferred from characterization of the intermediate polystyrenes and the block copolymers by size exclusion chromatography, 1H NMR, Fourier transform infrared spectroscopy, differential scanning calorimetry, and GPEC techniques. The latent acetoxy functionalities in these block copolymers are shown to be easily unmasked to OOH and OBr functionalities, with the potential for block ionomers and dense graft architectures. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/1995 |
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| Diblock and triblock....pdf | (136.8Kb) |
| Abstract: | The dielectric properties of vacuum-deposited europium oxide films have been investigated in the frequency range from 1 kHz to 1 MHz at various temperatures (300-543 K). The dielectric constant is found to depend on film thickness and it attains a constant value beyond 1000 Å. Films deposited at higher substrate temperatures (above 423 K) exhibit improved dielectric properties owing to the recovery of stoichiometry. The frequency variation of the loss factor exhibits a minimum which increases with rise in temperature. The breakdown field strength (about 106V cm-1) is found to be thickness dependent and it varies in accordance with the Forlani-Minnaja relation. The films exhibit ohmic conduction with an activation energy of 0.86 eV at low electric fields but at higher fields the conductivity becomes space charge limited. X-ray studies show that the films are amorphous in nature. The a.c. conductivity is proportional to ω at low frequency, whereas a square law dependence is observed at higher frequencies. The optical constants n, α and k and optical band gap are calculated from the UV-visible-near-IR spectra. |
| URI: | http://dyuthi.cusat.ac.in/purl/2652 |
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| Dyuthi-T0334.pdf | (403.4Kb) |
| Abstract: | The dielectric properties of electron beam evaporated Sm2O3 films have been investigated in the frequency range from 1 kHz to 1 MHz at various temperatures (300 K-453 K). The dielectric constant is found to depend on film thickness and it attains a constant value beyond 1000 A. The present electron beam evaporated Sm2O3 films have a high dielectric constant of 43. The frequency dependence of and tan teeta at various temperatures is also studied. |
| URI: | http://dyuthi.cusat.ac.in/purl/2467 |
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| Dyuthi-P0297.pdf | (244.2Kb) |
| Abstract: | Nonlinear time series analysis is employed to study the complex behaviour exhibited by a coupled pair of Rossler systems. Dimensional analysis with emphasis on the topological correlation dimension and the Kolmogorov entropy of the system is carried out in the coupling parameter space. The regime of phase synchronization is identified and the extent of synchronization between the systems constituting the coupled system is quantified by the phase synchronization index. The effect of noise on the coupling between the systems is also investigated. An exhaustive study of the topological, dynamical and synchronization properties of the nonlinear system under consideration in its characteristic parameter space is attempted. |
| URI: | http://dyuthi.cusat.ac.in/purl/2651 |
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| Dyuthi-P0333.pdf | (178.6Kb) |
| Abstract: | The dynamic mechanical properties such as storage modulus, loss modulus and damping properties of blends of nylon copolymer (PA6,66) with ethylene propylene diene (EPDM) rubber was investigated with special reference to the effect of blend ratio and compatibilisation over a temperature range –100°C to 150°C at different frequencies. The effect of change in the composition of the polymer blends on tanδ was studied to understand the extent of polymer miscibility and damping characteristics. The loss tangent curve of the blends exhibited two transition peaks, corresponding to the glass transition temperature (Tg) of individual components indicating incompatibility of the blend systems. The morphology of the blends has been examined by using scanning electron microscopy. The Arrhenius relationship was used to calculate the activation energy for the glass transition of the blends. Finally, attempts have been made to compare the experimental data with theoretical models. |
| URI: | http://dyuthi.cusat.ac.in/xmlui/purl/1998 |
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| Dynamic mechanical analysis...pdf | (518.2Kb) |
| Abstract: | Laser produced plasma from silver is generated using a Q-switched Nd:YAG laser. Optical emission spectroscopy is used to carry out time of flight (TOF) analysis of atomic particles. An anomalous double peak profile in the TOF distribution is observed at low pressure. A collection of slower species emerge at reduced pressure below 4 X lO-3 mbar and this species has a greater velocity spread. At high pressure the plasma expansion follows the shockwave model with cylindrical symmetry whereas at reduced pressure it shows unsteady adiabatic expansion (UAE). During UAE the species show a parabolic increases in the expansion time with radial distance whereas during shock wave expansion the exponent is less than one. The angular distribution of the ablated species in the plume is obtained from the measurement of optical density of thin films deposited on to glass substrates kept perpendicular to the plume. There is a sharp variation in the film thickness away from the film centre due to asymmetries in the plume. |
| URI: | http://dyuthi.cusat.ac.in/purl/2385 |
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| Dyuthi-P0206.pdf | (829.2Kb) |
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