Renjusha, S; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, April , 2012)
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Abstract:
Thiosemicarbazones have recently attracted considerable attention due to
their ability to form tridentate chelates with transition metal ions through either
two nitrogen and sulfur atoms, N–N–S or oxygen, nitrogen and sulfur atoms,
O–N–S. Considerable interest in thiosemicarbazones and their transition metal
complexes has also grown in the areas of biology and chemistry due to
biological activities such as antitumoral, fungicidal, bactericidal, antiviral and
nonlinear optical properties. They have been used for metal analyses, for
device applications related to telecommunications, optical computing, storage
and information processing.The versatile applications of metal complexes of thiosemicarbazones in various fields prompted us to synthesize the tridentate NNS-donor
thiosemicarbazones and their metal complexes. As a part of our studies on
transition metal complexes with these ligands, the researcher undertook the current work
with the following objectives.
1. To synthesize and physico-chemically characterize the following
thiosemicarbazone ligands:
a. Di-2-pyridyl ketone-N(4)-methyl thiosemicarbazone (HDpyMeTsc)
b. Di-2-pyridyl ketone-N(4)-ethyl thiosemicarbazone (HDpyETsc)
2. To synthesize oxovanadium(IV), manganese(II), nickel(II), copper(II),
zinc(II) and cadmium(II) complexes using the synthesized
thiosemicarbazones as principal ligands and some anionic coligands.
3. To study the coordination modes of the ligands in metal complexes by
using different physicochemical methods like partial elemental analysis,
thermogravimetry and by different spectroscopic techniques.
4. To establish the structure of compounds by single crystal XRD studies
Description:
Department of Applied Chemistry, Cochin University of Science and Technology
Manju, Sebastian; Dr.Mohammed Yusuff,K K(Cochin University of Science & Technology, July , 2010)
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Abstract:
Schiff base complexes of transition metal ions have played a significant role in coordination chemistry.The convenient route of synthesis and thermal stability of Schiff base complexes have contributed significantly for their possible applications in catalysis,biology,medicine and photonics.Significant variations in cataltytic activity with structure and type are observed for these complexes.The thesis deals with synthsis and characterization of transition metal complexes of quinoxaline based Schiff base ligands and their catalytic activity study.The Schiff bases synthesized in the present study are quinoxaline-2-carboxalidine-2-amino-5-methylphenol,3-hydroxyquinoxaline-2-carboxalidine-2-amino-5-methylphenol,quinoxaline-2-aminothiophenol.They provide great structural diversity during complexation.To the best of our knowledge, the transition metal complexes of quinoxaline based Schiff bases are poorly utilised in academic and industrial research.
Description:
Dept.of Applied Chemistry,Cochin University of Science and Technology
Sreesha, Sasi; Dr.Prathapachandra Kurup,M R(Cochin University of Science & Technology, October , 2008)
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Abstract:
Metallo-organic chemistry,incorporating the frontiers of both inorganic and organic chemical aspects,is a topic of utility concern.The first exploration of coordinated metal complexes dates back to the ninettenth century,during the days of Alfred Werner.Thereafter,inorganic chemistry witnessed a great outflow of coordination compounds,with unique structural characteristics and diverse applicatons.The diversity in structures exhibited by the coordination complexes of multidentate ligands have led to their usage as sensors,models for enzyme mimetic centers,medicines etc.The liganda chosen are of prime importance in determining the properties of coordination compounds.Schiff bases are compounds obtained by the condensation of an aidehyde or ketone with an amine.The chemical properties of Schiff bases and their complexes are widely explored in recent years owing to their pharmacological activity,their catalytic activities and so on.On the other hand pseudohalides like azide and thiocyanate are versatile candidates for the construction of dimeric or polymeric complexes having excellent properties and diverse applications.So a combination of the Schiff bases and the pseudohalogens for the synthesis of metal complexes can bring about interesting results.An attempt into this area is the besis of this Ph.D theis.
Description:
Department of Applied Chemistry,
Cochln University of Science and Technology
Suja, Krishnan; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, June , 2008)
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Abstract:
Coordination chemistry of pentadentate 2,6-diacetylpyridine
bis(thiosemicarbazone) Schiff base ligands has been intensively studied due to the versatility of the molecular chain in order to obtain very different
geometries as well as their broad therapeutic activity. Metal complexes of
thiosemicarbazone with aldehydes and ketones have been widely reported.
But there have been fewer reports on potential pentadentate
bis(thiosemicarbazones) formed from 2,6-diacetylpyridine. Keeping these in
view, we have synthesized four bis(thiosemicarbazone) systems with
2,6-diacetylpyridine. In the present work, the chelating behavior of
bis(thiosemicarbazones) are studied, with the aim of investigating the
influence of coordination exerts on their conformation and or configuration, in
connection with the nature of the metal and of the counter ion. The selection
of the 2,6-diacetylpyridine as the ketonic part was based on its capability to
form polynuclear complexes with different coordination number. The doubled
armed bis(thiosemicarbazones) can coordinate to a metal centre as dianionic
ligand by losing its amide protons or it can coordinate as monoanionic ligand
by losing its amide proton from one of the thiosemicarbazone moiety or it can
also be coordinate as neutral ligand. Hence it is interesting to explore the
coordinating capabilities of these ligands whether in neutral form or anionic
form and to study the structural variations occurring in the ligands during
complexation such as change in conformation.
Description:
Department of Applied Chemistry,
Cochin university of Science and Technology
Maheswaran, Sithambaresan; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, April , 2012)
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Abstract:
The unusual coordination modes of semicarbazones when bound to
metals, the wide applications and structural diversity of metal complexes of
semicarbazones provoked us to synthesize and characterize the tridentate ONO
and NNO-donor semicarbazones and their transition metal complexes. This
work is focused on the studies on complexes of three N4-phenylsemicarbazones
synthesized by changing the carbonyl compounds. This work is concerned with the studies of two new semicarbazones, 2- formylpyridine-N4-phenylsemicarbazone (HL1) and 3-ethoxysalicylaldehyde- N4-phenylsemicarbazone (H2L2) and a reported semicarbazone
2-benzoylpyridine-N4-phenylsemicarbazone (HL3) [29]. The compositions of
these semicarbazones were determined by the CHN analyses and IR, UV and
NMR spectral studies were used for the characterization of these compounds.
The molecular structure of 3-ethoxysalicylaldehyde-N4-phenylsemicarbazone
(H2L2) was obtained by single crystal X-ray diffraction studies. Also, we have
synthesized Cu(II), Cd(II), Zn(II) and Ni(II) complexes of these three
semicarbazones. The complexes were characterized by various spectroscopic
techniques, magnetic and conductivity studies. We could isolate single crystals
of some complexes of all metals suitable for X-ray diffraction studies. This
thesis is divided into six chapters.
Description:
Department of Applied Chemistry, Cochin University of Science and Technology
Maheswaran Sithambaresan; Dr. M. R. Prathapachandra Kurup(Cochin University of Science and Technology, April 18, 2012)
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Abstract:
The work embodied in this thesis was carried out by the author in the
Department of Applied Chemistry, CUSAT, Kochi, during the period 2009-2012.
The thesis is an introduction to our attempts to evaluate the coordination behavior
of some compounds of our interest. The biological activities of semicarbazones
and their metal complexes have been an active area of research during the past
years because of their significant role in naturally occurring biological systems.
Tridentate NNO and ONO semicarbazone systems formed from heterocyclic and
aromatic carbonyl compounds and their transition metal complexes are wellauthenticated
compounds in this field and their synthesis, crystal structures and
spectral studies are well desirable. Hence, we decided to develop a research
program aimed at the syntheses, crystal structures and spectral studies of new N4-
phenylsemicarbazones derived from 2-formylpyridine and 3-ethoxysalicylaldehyde
and their transition metal complexes and new transition metal complexes of 2-
benzoylpyridine-N4-phenylsemicarbazone. In addition to various physicochemical
methods of analysis, single crystal X-ray diffraction studies were also
used for the characterization of the complexes.
Laly, K; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, July , 2011)
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Abstract:
In the present work,the chelating behaviour of thiosemicarbazones of a heterocyclic diketone, 2,6-diacetylpyridine is studied,with the aim of investigating the influence coordination exerts on their conformation and /or configuration, in connection with the nature of the metal and of the counter ion.The various possibilities like unsubstitution,ring incorporation at terminal nitrogen and condensation of one of the ketone group alone have been tried for ligand selection.Mainly first row transition metals like manganese,iron,nickel,copper,zinc and cadmium are studied.Metals like cobalt also were studied but could not result in fruitful isolation of the compound due to solubility problems.Different spectroscopic and characterization techniques have been utilized to reveal the nature of the metal and the ligands in coordinated metal complex.
Description:
Department of Applied Chemistry,Cochin University of Science and Technology
Bhoodes, R.K.; Dr. Francis C.A.(Cochin University of Science and Technology, November , 2014)
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Abstract:
Cashew is an important commodity traded across the continents and the
world cashew industry is the livelihood of more than three million people
worldwide, the majority of whom are womenfolk from the socially and
economically backward community of the developing nations. Cashew tree
was originally planted to prevent soil erosion and it was during the beginning
of the 19th century that cashew kernels attained the status of a food item.
Further, the cashew kernels attained the status of an international commodity
with India exporting its first consignment of cashew kernels to U.S.A. in 1920.
India was the first country to hit the world market with cashew as a
commodity and it was she who pioneered cashew processing as an industry.
For decades together India was enjoying a monopoly in the world cashew
industry in the fields of raw nut production (cultivation), processing and the
market share in the international trade. The liberalisation of international trade
has brought in a big transition in the world of cashew. India started to benefit
from the trade policy, that improved her supply positions of raw nuts from
other producing countries, accelerated her growth in processing of raw nuts
and exports of cashew kernels. On the other side, her domestic consumption
started growing up that by the beginning of the new century, she emerged out
as the world’s largest consumer of cashew kernels as well.
Philip,M P; George,K K(Department of Applied Economics, 2006)
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Abstract:
The study documents the long-term trends in financial intermediation by the principal player in Kerala’s credit system i.e., banking. The process of financial intermediation by the banking system, involving mobilization of deposits from savers and disbursal of credit to investors, is considered to be crucial in the process of economic development. The objective of the study is to explore the interrelationship between financial intermediation and economic growth in Kerala. In order to pursue this objective, the study examine, the trends in intermediation by the banking system in Kerala over a long period, the trend and pattern of bank deposits and credit in the State and Kerala’s economic growth, the trend in the growth and performance of financial intermediaries like the All India Financial Institutions, the links between banking and economic variables, and the difference in the growth trends of banking and economic variables between Kerala and India and the probable reasons for the difference
Mini, Kuriakose; Dr.Prathapachandra Kurup,M R(Cochin University of Science & Technology, December , 2006)
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Abstract:
The present work deals with the complexation of Schiff
bases of aroylhydrazides with various transition metal ions. The hydrazone
systems selected for study are capable of forming bridged polymeric structures
which is one of the fascinating subjects in the crystal engineering of coordination
polymers owing to their attractive new topologies and intriguing structural
features. Complexation with metal ions like copper, manganese, vanadium,
nickel, palladium, zinc and cadmium are tried. Various spectral techniques are
employed for characterization. The structures of some complexes have been well
established by single crystal X-ray diffraction studies.The work is presented in seven chapters and the last section deals with
summary and conclusion. The studies reveal that the aroylhydrazone systems vary
in their geometrical configuration depending on the substituents. The coordination
modes of the ligands also differ upon chelating with metal ions. One of the
hydrazone system selected for study proved that it could give rise to polymeric
metal complexes.
Description:
Dept.of Applied Chemistry,Cochin University of Science and Technology
Ratheesh Kumar, C S; Dr.Chandramohanakumar, N(Cochin University of Science and Technology, August , 2011)
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Abstract:
This thesis entitled triterpenoids as biomarkers of mangrove organic matter in cochin estuarine system.Mangrove forests, known as rainforests of the sea are one of the most important coastal ecosystems in the world in terms of primary production and coastal protection.Estuaries, the important areas of world’s coastal zones link the carbon cycle of the oceans to the continents.Three mangrove
ecosystems and three estuarine stations around Cochin region, southwest coast of India were selected for the present study. The thesis is divided into five chapters. Chapter 1 is the Introduction and it deals with the aim and scope of the present study. Chapter 2 is Materials and Methods. This chapter deals with the nature and general geographical features of the study area. It also contains the details of the sampling and analytical methodology.the present study. Chapter 3 is Geochemistry and it includes the seasonal and spatial variations of the geochemical parameters in the surface sediments.Chapter 4 is Biochemical Composition. It covers the biochemical composition of organic matter in the surface sediments to examine the quality and quantity of organic matter.Chapter 5, Triterpenoid Biomarkers in Sediments, characterize the organic matter in the sediments of the mangrove and estuarine ecosystems under study, to assess the possible sources with the help of triterpenoid biomarkers along with other lipid biomarkers.
Description:
Department of Chemical Oceanography, School of Marine Sciences, Cochin University of Science and Technology
Abhilash, S; Dr.Mohan Kumar, K(Cochin University of Science and Technology., December , 2007)
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Abstract:
The main purpose of the thesis is to improve the state of knowledge and understanding
of the physical structure of the TMCS and its short range prediction. The present
study principally addresses the fine structure, dynamics and microphysics of severe convective
storms.The structure and dynamics of the Tropical cloud clusters over Indian region is not well
understood. The observational cases discussed in the thesis are limited to the temperature
and humidity observations. We propose a mesoscale observational network along with all
the available Doppler radars and other conventional and non—conventional observations.
Simultaneous observations with DWR, VHF and UHF radars of the same cloud system will
provide new insight into the dynamics and microphysics of the clouds. More cases have to
be studied in detail to obtain climatology of the storm type passing over tropical Indian
region. These observational data sets provide wide variety of information to be assimilated
to the mesoscale data assimilation system and can be used to force CSRM.The gravity wave generation and stratosphere troposphere exchange (STE) processes
associated with convection gained a great deal of attention to modem science and meteorologist.
Round the clock observations using VHF and UHF radars along with supplementary
data sets like DWR, satellite, GPS/Radiosondes, meteorological rockets and aircrafl
observations is needed to explore the role of convection and associated energetics in detail.
Description:
Department of Atmospheric Sciences,
Cochin University of Science and Technology
Shaji,S; Abdul Rasheed, T M(Cochin University of Science and Technology, April , 2003)
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Abstract:
The present work is mainly concentrated on setting up a NIR tunable diode laser absorption (TDLA) spectrometer for high-resolution molecular spectroscopic studies. For successfully recording the high-resolution tunable diode laser spectrum, various experimental considerations are to be taken into account like the setup should be free from mechanical vibrations, sample should be kept at a low pressure, laser should be in a single mode operation etc. The present experimental set up considers all these factors. It is to be mentioned here that the setting up of a high resolution NIR TDLA spectrometer is a novel experiment requiring much effort and patience. The analysis of near infrared (NIR) vibrational overtone spectra of some substituted benzene compounds using local mode model forms another part of the present work. An attempt is made to record the pulsed laser induced fluorescence/Raman spectra of some organic compounds. A Q-switched Nd:YAG laser is used as the excitation source. A TRIAX monochromator and CCD detector is used for the spectral recording. The observed fluorescence emission for carbon disulphide is centered at 680 nm; this is assigned as due to the n, p* transition. Aniline also shows a broad fluorescence emission centered at 725 nm, which is due to the p,p* transition. The pulsed laser Raman spectra of some organic compounds are also recorded using the same experimental setup. The calibration of the set up is done using the laser Raman spectra of carbon tetrachloride and carbon disulphide. The observed laser Raman spectra for aniline, o-chloroaniline and m-chlorotoluene show peaks characteristics of the aromatic ring in common and the characteristics peaks due to the substitutuent groups. Some new peaks corresponding to low-lying vibrations of these molecules are also assigned
Alex,A V; Jacob, Philip(Cochin University of Science and Technology, May , 2001)
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Abstract:
Ultrasonic is a good tool to investigate the elastic properties of crystals. It enables one to determine all the elastic constants, Poisson’s ratios, volume compressibility and bulk modulus of crystals from velocity measurements. It also enables one to demonstrate the anisotropy of elastic properties by plotting sections of the surfaces of phase velocity, slowness, group velocity, Young’s modulus and linear compressibility along the a-b, b-c and a-c planes. They also help one to understand more about phonon amplification and help to interpret various phenomena associated with ultrasonic wave propagation, thermal conductivity, phonon transport etc. Study of nonlinear optical crystals is very important from an application point of view. Hundreds of new NLO materials are synthesized to meet the requirements for various applications. Inorganic, organic and organometallic or semiorganic classes of compounds have been studied for several reasons. Semiorganic compounds have some advantages over their inorganic and inorganic counterparts with regard to their mechanical properties. High damage resistance, high melting point, good transparency and non-hygroscopy are some of the basic requirements for a material to be suitable for device fabrication. New NLO materials are being synthesized and investigation of the mechanical and elastic properties of these crystals is very important to test the suitability of these materials for technological applications
Godfrey,Louis; Jacob, Philip(Department of Physics, 1994)
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Abstract:
The thesis investigated the elastic properties and phase transitions in selected mixed sulphate crystals – Lithium Hydrazinium Sulphate [LiN2H2SO4], Lithium Ammonium Sulphate [LiNH4SO4] and Lithium Potassium Sulphate [LiKSO4] – using ultrasonic technique. The pulse echo overlap technique has been used for measuring ultrasonic velocity and its dependence on temperature along different directions with waves of longitudinal and transverse polarizations. Two major numerical techniques and the corresponding computer programs developed as part of present work are presented in this thesis. All the 9 elastic constants of LHS are determined accurately from ultrasonic measurements and applying misorientation correction refines the constants. Ultrasonic measurements are performed in LAS to determine the elastic constants and to study the low temperature phase transitions. Temperature variation studies of elastic constant of LAS are performed for 6 different modes of propagation for heating and cooling at low temperatures. All the 5 independent elastic constants of LPS is determined using ultrasonic measurements. It is concluded that LPS crystal does not undergo a phase transition near this temperature. A comparison of the three crystals studied shows that LPS has maximum number of phase transitions and LHS has the least number. It is interesting to note that LPS has the simplest formula unit among the three. There is considerable scope for the future work on these crystals and others belonging to the sulphate family.
Prabha, C; Dr.Pillai, P R S(Cochin University of Science And Technology, July 24, 2013)
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Abstract:
Underwater target localization and tracking attracts tremendous research interest due to various impediments to the estimation task caused by the noisy ocean environment. This thesis envisages the implementation of a prototype automated system for underwater target localization, tracking and classification using passive listening buoy systems and target identification techniques. An autonomous three buoy system has been developed and field trials have been conducted successfully. Inaccuracies in the localization results, due to changes in the environmental parameters, measurement errors and theoretical approximations are refined using the Kalman filter approach. Simulation studies have been conducted for the tracking of targets with different scenarios even under maneuvering situations. This system can as well be used for classifying the unknown targets by extracting the features of the noise emanations from the targets.
Description:
Department of Electronics, Cochin University of Science and Technology.
Nify, Benny; Dr.Sujatha, C H(Cochin University of Science and Technology, June , 2009)
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Abstract:
The thesis deals with a benchmark study of dissolved and sedimentary sulphur
compounds which play prominent roles in the prevailing redox conditions in the
selected sites of Cochin estuarine system. Sulphur and its analogues play prominent
roles in estuarine biochemical processes. A complete knowledge on the sulphur
involvement in these processes is restricted due to the lacking of data on the organic
sulphur compounds. Sulphate and sulphide in surface and bottom water and
Sulphate, acid volatile sulphide and total sulphur in sediments were studied and
correlated to know their interrelations in determining the redox condition of the
environment. It also characterises the sediments of the sites on the basis of total
organic carbon: total sulphur ratio. The study had attempted to decrease the
concentration levels of sulphur in the sedimentary environment by the application of
a remedial measure. Knowledge of sulphur uptake by plants from prior literatures
has prompted to use phytoremediation for decreasing the sulphur concentration.
Phytoremediation is an emerging technology that uses plants to clean up or remediate
contaminated soil, sludges, sediments, and ground water through contaminant
removal, degradation or containment. The plant selected was wheat grass since
earlier studies have shown that wheat grass is effective in remediating pollutants
particularly trace metals. So reduction in the concentration of selected trace metals
was also focussed.
Description:
Department of Chemical Oceanography, Cochin University of Science and Technology
Radhakrishnan, N; Dr.Meera Bai,M(Cochin University of Science and Technology, November 20, 2003)
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Abstract:
Studies in urban water supply system are few in the state of Kerala.
It is a little researched area. In the case of water pricing a number of studies are
available. In Kerala state, exception to Jacob John’s study on “Economics of
Public Water Supply System”, which is a case study of Trivandrum Water Supply
System in 1997, no exhaustive research work has so far come out in this field.
loreover no indepth research study has come up, so far, relating to household
ater demand analysis and the distribution system of urban piped water supply.
he proposed study is first of its kind, which focuses on the distributional and
Iailability problems of piped water supply in an urban centre in Kerala state.
Hence there is a felt need for enquiring into the sufficiency of
)table water supplied to people in urban areas and the efficiency maintained in
roviding the scarce resource and preventing its misuse by the consumers. It is in
llS backdrop that this study was undertaken and its empirical part was conducted
|Calicut city in the state of Kerala. Study is confined to the water supply system
ithe city of Calicut
Description:
Department of Applied Economics,
Cochin University of Science and Technology
Babu, K K; Dr. Beena, K S(Cochin University of Science and Technology, May , 2007)
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Abstract:
The increasing tempo of construction activity the world over creates heavy pressure
on existing land space. The quest for new and competent site often points to the needs
for improving existing sites, which are otherwise deemed unsuitable for adopting
conventional foundations. This is accomplished by ground improvement methods,
which are employed to improve the quality of soil incompetent in their natural state.
Among the construction activities, a well-connected road network is one of the basic
infrastructure requirements, which play a vital role for the fast and comfortable
movement of inter- regional traffic in countries like India.One of the innovative ground improvement techniques practised all over the world is
the use of geosynthetics, which include geotextiles, geomembranes, geogrids, etc .
They offer the advantages such as space saving, enviromnental sensitivity, material
availability, technical superiority, higher cost savings, less construction time, etc .
Because of its fundamental properties, such as tensile strength, filtering and water
permeability, a geotextile inserted between the base material and sub grade can
function as reinforcement, a filter medium, a separation layer and as a drainage
medium. Though polymeric geotextiles are used in abundant quantities, the use of
natural geotextiles (like coir, jute, etc.) has yet to get momentum. This is primarily
due to the lack of research work on natural geotextilcs for ground improvement,
particularly in the areas of un paved roads. Coir geotextiles are best suited for low cost
applications because of its availability at low prices compared to its synthetic
counterparts. The proper utilisation of coir geotextilcs in various applications demands large quantities of the product, which in turn can create a boom in the coir
industry. The present study aims at exploring the possibilities of utilising coir
geotextiles for unpaved roads and embankments.The properties of coir geotextiles used have been evaluated. The properties studied
include mass per unit area, puncture resistance, tensile strength, secant modulus, etc .
The interfacial friction between soils and three types of coir geotextiles used was also
evaluated. It was found that though the parameters evaluated for coir geotextiles have
low values compared to polymeric geotextiles, the former are sufficient for use in
unpaved roads and embankments. The frictional characteristics of coir geotextile - soil
interfaces are extremely good and satisfy the condition set by the International
Geosynthetic Society for varied applications.The performance of coir geotextiles reinforced subgrade was studied by conducting
California Bearing Ratio (CBR) tests. Studies were made with coir geotextiles placed
at different levels and also in multiple layers. The results have shown that the coir
geotextile enhances the subgrade strength. A regression analysis was perfonned and a
mathematical model was developed to predict the CBR of the coir geotextile
reinforced subgrade soil as a function of the soil properties, coir geotextile properties,
and placement depth of reinforcement.The effects of coir geotextiles on bearing capacity were studied by perfonning plate
load tests in a test tan1e This helped to understand the functioning of geotextile as
reinforcement in unpaved roads and embankments. The perfonnance of different
types of coir geotextiles with respect to the placement depth in dry and saturated
conditions was studied. The results revealed that the bearing capacity of coir-reinforced soil is increasing irrespective of the type of coir geotextiles and saturation
condition.The rut behaviour of unreinforced and coir reinforced unpaved road sections were
compared by conducting model static load tests in a test tank and also under repetitive
loads in a wheel track test facility. The results showed that coir geotextiles could
fulfill the functions as reinforcement and as a separator, both under static and
repetitive loads. The rut depth was very much reduced whik placing coir geotextiles
in between sub grade and sub base.In order to study the use of Coir geotextiles in improving the settlement
characteristics, two types of prefabricated COlf geotextile vertical drains were
developed and their time - settlement behaviour were studied. Three different
dispositions were tried. It was found that the coir geotextile drains were very effective
in reducing consolidation time due to radial drainage. The circular drains in triangular
disposition gave maximum beneficial effect.In long run, the degradation of coir geotextile is expected, which results in a soil -
fibre matrix. Hence, studies pertaining to strength and compressibility characteristics
of soil - coir fibre composites were conducted. Experiments were done using coir
fibres having different aspect ratios and in different proportions. The results revealed
that the strength of the soil was increased by 150% to 200% when mixed with 2% of
fibre having approximately 12mm length, at all compaction conditions. Also, the
coefficient of consolidation increased and compression index decreased with the
addition of coir fibre.Typical design charts were prepared for the design of coir geotextile reinforced
unpaved roads. Some illustrative examples are also given. The results demonstrated that a considerable saving in subase / base thickness can he achieved with the use of
eoir geotextiles, which in turn, would save large quantities of natural aggregates.
Description:
Division of Civil Engineering,
Cochin University of Science and Technology
Anil, Loveson; Rajathy, Sivalingam(Cochin University of Science And Technology, August , 2014)
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Abstract:
One of the objectives of the current investigation was to evaluate the effectiveness of Spirodela polyrhiza to remove heavy metals and other contaminants from the water samples collected from wetland sites of Eloor and Kannamaly under controlled conditions .The results obtained from the current study suggest that the test material S. polyrrhiza should be used in the biomonitoring and phytoremediation of municipal, agricultural and industrial effluents because of their simplicity, sensitivity and cost-effectiveness. The study throws light on the potential of this plant which can be used as an assessment tool in two diverse wetland in Ernakulum district. The results show the usefulness of combining physicochemical analysis with bioassays as such approach ensures better understanding of the toxicity of chemical pollutants and their influence on plant health. The results shows the suitability of Spirodela plant for surface water quality assessment as all selected parameters showed consistency with respect to water samples collected over a 3-monitoring periods. Similarly the relationship between the change in exposure period (2, 4 and 8 days) with the parameters were also studied in detail. Spirodela are consistent test material as they are homogeneous plant material; due to predominantly vegetative reproduction. New fronds are formed by clonal propagation thus, producing a population of genetically homogeneous plants. The result is small variability between treated individuals. It has been observed that phytoremediation of water samples collected from Eloor and Kannamaly using the floating plant system is a predominant method which is economic to construct, requires little maintenance and eco friendly.
Ganapathy, Rajendran; Dr.Kuriakose, A P(Cochin University of Science and Technology, August 21, 1995)
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Abstract:
The thesis consists of seven chapters. The first
chapter is a general introduction on rice by-products,
their composition and utilization at present. The
different milling processes adopted in paddy and the major
by-products obtained from these processes viz. rice husk,
rice bran, rice bran oil and rice husk ash are described.
The physical properties and chemical composition of the
rice husk and its general uses are given in detail. The
chemical composition of the rice bran and its separation
from paddy is also included. The details of solvent
extraction process used for obtaining rice bran oil and
also its chemical constitution is discussed in this
chapter. Also described is the preparation and the
different uses of rice husk ash. A literature survey is
also done on the utilization of rice by-products in rubber
and plastics as on today. The scope and objectives of the
present study is also included at the end of this chapter.
Description:
Department of
Polymer Science and Rubber Technology, Cochin University of
Science and Technology
Thomas,C J; Dr.Ramachandra, Poduval P(Cochin University of Science And Technology, April , 1997)
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Abstract:
The present study is on
value orientation of professional students•and as such the theoretical value is
inherent and implied. Variation on this value is likely to be limited among
the subjects.
The relevance of the present study is with particular reference, to
management as a profession. In organisational settings motivation plays an
important role. According to McClelland's theory of needs, achievement,
power, and affiliation are the three important needs that help in understanding
motivation. Achieve~ent need may be defined as the drive to excel, to achieve
in relation to a set of standards, and to strive to succeed. Some people have a
compelling drive to succeed. They have a desire to do something better or
more efficiently than it has been done before. McClelland found that high
achievers differentiate themselves from others by their desire to do things
. better. Considering this fact, 'achievement' is included as one of the values
for the study
Description:
School of Management Studies, Cochin University of Science and Technology
Radhika, T; Dr.Mohanan, P V; Dr.Sugunan, S(Cochin University of Science and Technology, November 23, 2005)
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Abstract:
The selective oxidation of alkylaromatics is one of the main processes since the reaction products are important as intermediates in numerous industrial organic chemicals. Side-chain oxidation of alkyl aromatic compounds catalyzed by heterogeneous catalysts using cleaner peroxide oxidants is an especially attractive goal since classical synthetic laboratory procedures preferably use permanganate or acid dichromate as stoichiometric oxidants. In spite of many studies, there are very few which use hydrogen peroxide as a source of oxygen in the C-H activation of alkanes. Eflective utilization of ethylbenzene, available in the xylene stream of the petrochemical industry to more value added products is a promising one in chemical industry. The oxidation products of ethylbenzene are widely employed as intermediates in organic, steroid and resin synthesis.
Description:
Department of Chemistry, Cochin University of Science andTechnology,
Surekhamol, I S; Dr.Bright Singh,I S(Cochin University of Science and Technology, November , 2012)
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Abstract:
Aquaculture is a global industry providing food and employment thereby contributing to the economy. For the sustenance of aquaculture, disease management is a major requirement. Among the bacterial pathogens Vibrio harveyi remains to be the major one especially in shrimp culture systems. Rapid
and mass mortality of shrimp larvae due to Vibrio harveyi infection is well known, and the pathogen causes serious economic losses in grow out systems as well. It suggests that a well defined management strategy has to be built up to protect the crop from Vibrio harveyi infection in aquaculture systems. Antibiotics have been the choice for quite some times which led to residues in meat and development of multidrug resistant bacteria which invited ban on their application. In this context several alternate options have been thought off such as probiotics, immunostimulants and vaccines. Phage therapy is yet another option. Phages being natural parasites of bacteria and are abundant in aquatic environments their application to control bacterial pathogens in aquaculture has commendable potential in lieu of antibiotics. For that matter the therapeutic effect of phages has been proven in several antibiotic resistant pathogens inclusive of Vibrio harveyi.
Description:
National Centre for Aquatic Animal
Health, School of Environmental Studies, Cochin University of Science and Technology
Anil Kumar, R; Dr.George, Varghese K(Cochin University Of Science And Technology, November , 2012)
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Abstract:
This study analyses the socio-economic backgrounds and entrepreneurial
profiles of the students and pass outs of the Vocational Higher Secondary
Education in Kerala and the academic achievements of the Vocational Higher
Secondary students and pass outs in Kerala in terms of their performance in the
examinations. The study also analyses the quality and availability of the various
training and support facilities of the Vocational Higher Secondary Schools in
Kerala, nature and rate of employment and higher studies among the pass outs
of the Vocational Higher Secondary Education in Kerala and the awareness of
students, pass outs, teachers and principals regarding the goals and objectives,
mode of implementation, apprenticeship training and higher study and
employment opportunities of the programme of the Vocational Higher
Secondary Education in Kerala.
Description:
School of Management Studies,
Cochin University of Science and Technology
Laina, A L; Dr.Girish Kumar, K(Cochin University Of Science And Technology, April , 2013)
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Abstract:
Electrochemical sensors are increasingly being investigated to perform
measurements for single or multiple analytes. Demanded by modern medical
diagnosis, advances in microfabrication technology have led to the development
of fast, sensitive and selective electrochemical sensors for drug analysis.
Electrochemical sensors for the measurement of analytes of interest in clinical
chemistry are ideally suited for these applications, due to their high sensitivity
and selectivity, simple-to-operate, rapid response time and low-cost.
As part of the present investigations eight voltammetric sensors have been
fabricated for six drugs such as PAM Chloride, Tamsulosin Hydrochloride,
Hesperidin Methyl Chalcone, Guaiphenesin, Cephalexin and Amoxicillin
trihydrate. The modification techniques adopted as part of the present work
include multiwalled carbon nanotube (MWNT) based modifications,
electropolymerization, gold nanoparticle (AuNP) based modifications and
platinum nanoparticle (PtNP) based modifications.
The thesis is divided into nine chapters
Description:
Department of Applied Chemistry
Cochin University of Science and Technology