Girijavallabhan, C P; Nampoori, V P N; Harilal, S S; Riju, C Issac; Bindhu, C V(Journal of Physics D : Applied Physics, January 24, 1997)
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Abstract:
Optical emission studies of C2 molecules in plasma obtained by Nd:YAG
laser ablation of graphite in a helium atmosphere are reported for irradiances in the
range (1–9:2/ x 1010 W cm−2. The characteristics of the spectral emission intensity
from the C2 (Swan band) species have been investigated as functions of the
distance from the target, ambient pressure and laser irradiance. Estimates of
vibrational temperatures of C2 species under various irradiance conditions are
made. Results of measurements performed under different ambient helium gas
pressures are also discussed.
Riju, C Issac; Harilal, S S; Geetha K, Varier; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(Society of Photo-Optical Instrumentation Engineers, February , 1997)
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Abstract:
Pulsed photoacoustic studies in solutions of C70 in toluene are made using the 532-nm radiation from a frequency-doubled Nd:YAG laser. It is found that contrary to expectation, there is no photoacoustic (PA) signal enhancement in the power-limiting range of laser fluences. Instead, the PA signal tends to saturate during optical power-limiting phenomenon. This could be due to the enhanced optical absorption from the photoexcited state and hence the depletion of the ground-state population. PA measurements also ruled out the possibility of multiphoton absorption in the C70 solution. We demonstrate that the nonlinear absorption leading to optical limiting is mainly due to reverse saturable absorption.
Harilal, S S; Issac, Riju C; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, April , 1997)
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Abstract:
The emission features of laser ablated graphite plume generated in a helium ambient atmosphere have been investigated with time and space resolved plasma diagnostic technique. Time resolved optical emission spectroscopy is employed to reveal the velocity distribution of different species ejected during ablation. At lower values of laser fluences only a slowly propagating component of C2 is seen. At high fluences emission from C2 shows a twin peak distribution in time. The formation of an emission peak with diminished time delay giving an energetic peak at higher laser fluences is attributed to many body recombination. It is also observed that these double peaks get modified into triple peak time of flight distribution at distances greater than 16 mm from the target. The occurrence of multiple peaks in the C2 emission is mainly due to the delays caused from the different formation mechanism of C2 species. The velocity distribution of the faster peak exhibits an oscillating character with distance from the target surface.
Harilal, S S; Issac, Riju C; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(Pramana, September , 1997)
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Abstract:
Time resolved optical emission spectroscopy is employed to study the expansion
dynamics of C2 species in a graphite plasma produced during the Nd : YAG ablation. At low laser
fluences a single peak distribution with low kinetic energy is observed. At higher fluences a twin
peak distribution is found. It has been noted that these double peak time of flight distribution splits
into a triple peak structure at distances >_ 17mm from the target surface. The reason for the
occurrence of multiple peak is due to different formation mechanisms of C2 species
Harilal, S S; Bindhu, C V; Issac, Riju C; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, September 1, 1997)
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Abstract:
Plasma generated by fundamental radiation from a Nd:YAG laser focused onto a graphite target is studied spectroscopically. Measured line profiles of several ionic species were used to infer electron temperature and density at several sections located in front of the target surface. Line intensities of successive ionization states of carbon were used for electron temperature calculations. Stark broadened profiles of singly ionized species have been utilized for electron density measurements. Electron density as well as electron temperature were studied as functions of laser irradiance and time elapsed after the incidence of laser pulse. The validity of the assumption of local thermodynamic equilibrium is discussed in light of the results obtained.
Bindhu, C V; Harilal, S S; Nampoori, V P N; Vallabhan, C P G(Society of Photo-Optical Instrumentation Engineers, 1998)
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Abstract:
Thermal diffusivity measurements are carried out in certain organic liquids using the pulsed dual beam thermal lens technique. The 532 nm pulses from a frequency doubled Q-switched Nd:YAG laser are used as the heating source and an intensity stabilized He-Ne laser serves as the probe beam. Experimental determination of the characteristic time constant of the transient thermal lens signal is verified theoretically. Measured thermal diffusivity values are in excellent agreement with literature values.
Issac, R C; Varier, G K; Harilal, S S; Nampoori, V P N; Vallabhan, C P G(Springer, 1998)
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Abstract:
The dynamics of diffusion of electrons and ions from the laser-produced plasma from a multielement superconducting material, namely YBa2Cu3O7, using a Q-switched Nd:YAG laser is investigated by time-resolved emission-spectroscopic techniques at various laser irradiances. It is observed that beyond a laser irradiance of 2.6 \xC3\x97 1011 W cm-2, the ejected plume collectively drifts away from the target with a sharp increase in velocity to 1.25 \xC3\x97 106 cm s-1, which is twice its velocity observed at lower laser irradiances. This sudden drift apparently occurs as a result of the formation of a charged double layer at the external plume boundary. This diffusion is collective, that is, the electrons and ions inside the plume diffuse together simultaneously and hence it is similar to the ambipolar diffusion of charged particles in a discharge plasma
Harilal, S S; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, 1998)
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Abstract:
The effect of ambient gas on the dynamics of the plasma generated by laser ablation of a carbon target using 1.06 μm radiation from a Q-switched Nd:YAG laser has been investigated using a spectroscopic technique. The emission characteristics of the carbon plasma produced in argon, helium and air atmospheres are found to depend strongly on the nature and pressure of the surrounding gas. It has been observed that hotter and denser plasmas are formed in an argon atmosphere rather than in helium or air as an ambient.
Issac, R C; Varier, G K; Gopinath, P; Harilal, S S; Nampoori, V P N; Vallabhan, C P G(Springer Berlin / Heidelberg, 1998)
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Abstract:
A silver target kept under partial vacuum conditions
was irradiated with focused nanosecond pulses at
1:06 mm from a Nd:YAG laser. The electron emission monitored
with a Langmuir probe shows a clear twin-peak distribution.
The first peak which is very sharp has only a small delay
and it indicates prompt electron emission with energy as
much as 60 5 eV. Also the prompt electron emission shows
a temporal profile with a width that is same as that for the
laser pulse whereas the second peak is broader, covers several
microseconds, and represents the low-energy electrons
(2 0:5 eV) associated with the laser-induced silver plasma
as revealed by time-of-flight measurements. It has been found
that prompt electrons ejected from the target collisionally
excite and ionize ambient gas molecules. Clearly resolved
rotational structure is observed in the emission spectra of
ambient nitrogen molecules. Combined with time-resolved
spectroscopy, the prompt electrons can be used as excitation
sources for various collisional excitation–relaxation experiments.
The electron density corresponding to the first peak is
estimated to be of the order of 1017 cm?--3 and it is found that
the density increases as a function of distance away from the
target. Dependence of probe current on laser intensity shows
plasma shielding at high laser intensities.
Bindhu, C V; Harilal, S S; Achamma, Kurian; Nampoori, V P N; Vallabhan, C P G(World Scientific Publishing Company, 1998)
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Abstract:
Dual beam transient thermal lens studies were carried out in rhodamine 6G methanol solutions using 532 nm pulses from a frequency doubled Nd:YAG laser. Analysis of thermal lens signal shows the existence of different nonlinear processes like two photon absorption and three photon absorption phenomena along with one photon absorption. Concentration of the dye in the solution has been found to influence the occurrence of the different processes in a significant way.
Riju, C Issac; Vasudevan Pillai, K; Harilal, S S; Geetha K, Varier; Bindhu, C V; Pramod, Gopinath; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Elsevier Science, 1998)
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Abstract:
Laser produced plasma from silver is generated using a Q-switched Nd:YAG laser. Optical emission spectroscopy is used
to carry out time of flight (TOF) analysis of atomic particles. An anomalous double peak profile in the TOF distribution is
observed at low pressure. A collection of slower species emerge at reduced pressure below 4 X lO-3 mbar and this species
has a greater velocity spread. At high pressure the plasma expansion follows the shockwave model with cylindrical
symmetry whereas at reduced pressure it shows unsteady adiabatic expansion (UAE). During UAE the species show a
parabolic increases in the expansion time with radial distance whereas during shock wave expansion the exponent is less
than one. The angular distribution of the ablated species in the plume is obtained from the measurement of optical density of
thin films deposited on to glass substrates kept perpendicular to the plume. There is a sharp variation in the film thickness
away from the film centre due to asymmetries in the plume.
Harilal, S S; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(Applied Spectroscopy, 1998)
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Abstract:
Spectroscopic studies of laser -induced plasma from a high-temperature
superconducting material, viz., YBa2Cu3O7 (YBCO), have
been carried out. Electron temperature and electron density measurements
were made from spectral data. The Stark broad ening of
emission lines was used to determine the electron density, and the
ratio of line in tensities was exploited for the determination of electron
temperature. An initial electron temperature of 2.35 eV and
electron density of 2.5 3 1017 cm2 3 were observed. The dependence
on electron temperature and density on different experimental parameters
such as distance from the target, delay time after the in itiation
of the plasm a, and laser irradiance is also discussed in detail.
Index Headings: Laser -plasma spectroscopy; Plasma diagnostics;
Emission spectroscop y; YBa2Cu3O7.
Harilal, S S; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(Springer Berlin / Heidelberg, 1998)
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Abstract:
Laser radiation at 1.06 µm from a pulsed Nd:YAG
laser was focused onto a multielement YBa2Cu3O7 target in
vacuum and the plasma thus generated was studied using
time-resolved spectroscopic techniques. Line broadening of
the Ba I emission line at 553.5 nm was monitored as a function
of time elapsed after the incidence of a laser pulse on the
target. Measured line profiles of barium species were used to
infer the electron density and temperature, and the time evolution
of these important plasma parameters has been worked out.
Nampoori, V P N; Vallabhan, C P G; George, A K; Radhakrishnan, P; Rajasree, K; Vidyalal, V(Elsevier, July , 1998)
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Abstract:
he phenomenon of single beam mirage effect, otherwise known as photothermal deflection (PTD) effect using a He–Ne laser beam has been employed to detect phase transitions in some liquid crystals. It has been observed that anomalous changes in amplitude occur in the PTD signal level near the transition temperature. The experimental details and the results of measurements made in liquid crystals E8, M21 and M24 are given in this paper.
Riju, C Issac; Pramod, Gopinath; Geetha K, Varier; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, July 13, 1998)
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Abstract:
Laser-induced plasma generated from a silver target under partial vacuum conditions using the
fundamental output of nanosecond duration from a pulsed Nd:yttrium aluminum garnet laser is
studied using a Langmuir probe. The time of flight measurements show a clear twin peak
distribution in the temporal profile of electron emission. The first peak has almost the same duration
as the laser pulse while the second lasts for several microseconds. The prompt electrons are
energetic enough ('60 eV) to ionize the ambient gas molecules or atoms. The use of prompt
electron pulses as sources for electron impact excitation is demonstrated by taking nitrogen, carbon
dioxide, and argon as ambient gases.
Deepa, Jose; Shelly John, M; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Elsevier, July 18, 1998)
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Abstract:
A novel fibre optic sensor for the in situ measurement of the rate of deposition of thin films has been developed. Evanescent wave in the uncladded portion of a multimode fibre is utilised for this sensor development. In the present paper we demonstrate how this sensor is useful for the monitoring of the deposition rate of polypyrrole thin films, deposited by an AC plasma polymerisation method. This technique is simple, accurate and highly sensitive compared with existing techniques.
Krishnan Nair, P R; Nandakumaran, V M(Springer, October , 1998)
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Abstract:
We present the analytical investigations on a logistic map with a discontinuity at the
centre. An explanation for the bifurcation phenomenon in discontinuous systems is presented. We
establish that whenever the elements of an n-cycle (n > 1) approach the discontinuities of the nth
iterate of the map, a bifurcation other than the usual period-doubling one takes place. The periods of
the cycles decrease in an arithmetic progression, as the control parameter is varied. The system also
shows the presence of multiple attractors. Our results are verified by numerical experiments as well.
Radhakrishnan, P; Nampoori, V P N; Girijavallabhan, C P; Shelly John, M(Measurement Science and Technology, UK, November 12, 1998)
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Abstract:
A novel sensing technique for the in situ monitoring of the rate of pulsed laser
deposition (PLD) of metal thin films has been developed. This optical fibre based sensor
works on the principle of the evanescent wave penetration of waveguide modes into the
uncladded portion of a multimode fibre. The utility of this optical fibre sensor is
demonstrated in the case of PLD of silver thin films obtained by a Q-switched Nd:YAG laser
which is used to irradiate a silver target at the required conditions for the preparation of thin
films. This paper describes the performance and characteristics of the sensor and shows how
the device can be used as an effective tool for the monitoring of the deposition rate of silver
thin films. The fibre optic sensor is very simple, inexpensive and highly sensitive compared
with existing techniques for thin film deposition rate measurements
Nampoori, V P N; Radhakrishnan, P; Girijavallabhan, C P; Shelly John, M(Measurement Science and Technology, UK, November 12, 1998)
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Abstract:
A novel sensing technique for the in situ monitoring of the rate of pulsed laser
deposition (PLD) of metal thin films has been developed. This optical fibre based sensor
works on the principle of the evanescent wave penetration of waveguide modes into the
uncladded portion of a multimode fibre. The utility of this optical fibre sensor is
demonstrated in the case of PLD of silver thin films obtained by a Q-switched Nd:YAG laser
which is used to irradiate a silver target at the required conditions for the preparation of thin
films. This paper describes the performance and characteristics of the sensor and shows how
the device can be used as an effective tool for the monitoring of the deposition rate of silver
thin films. The fibre optic sensor is very simple, inexpensive and highly sensitive compared
with existing techniques for thin film deposition rate measurements.
Indic, P; Pratap, R; Nampoori, V P N; Pradhan, N(International Journal of Neuroscience, 1999)
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Abstract:
We propose to show in this paper, that the time series obtained from biological systems such as human brain are invariably nonstationary because of different time scales involved in the dynamical process. This makes the invariant parameters time dependent. We made a global analysis of the EEG data obtained from the eight locations on the skull space and studied simultaneously the dynamical characteristics from various parts of the brain. We have proved that the dynamical parameters are sensitive to the time scales and hence in the study of brain one must identify all relevant time scales involved in the process to get an insight in the working of brain.