Saji, John K; Dr.Girish Kumar, K(Cochin University of Science and Technology, May 3, 2004)
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Abstract:
As the application of polymeric complexes is enormous, there
exists a continuing interest in the synthesis and characterization of
these complexes. The synthetic and characterization parts are very
important in an academic point of view. Further in an application
point of view also polymeric ligands/complexes are gaining
attention.The thesis is divided in to six chapters, in which the first
chapter gives an introduction along with a brief review on polymeric ligands/ complexes. The second chapter explains the different
procedure adopted for the whole work along with the details of the
reagents/ instruments used. The third chapter gives a report of the
detailed study regarding the synthesis and characterization of
eighteen complexes. While the fourth chapter is a report of the ion
removal studies using three polymeric ligands, the fifth chapter
explains the development of a polymeric complex as ion selective
electrode material for the fabrication of a CC ion selective electrode.
The sixth chapter presents the summary and tables, figures and
references are given separately at the end.
Description:
Department of Applied Chemistry, Cochin University of Science
and Technology
Jose, Kalloopparambil P; Dr.Girish Kumar, K(Cochin University of Science and Technology, November , 2006)
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Abstract:
Polymer supports and polymeric complexes are highly versatile and
they are successfully employed as efficient reagents, substrates and
catalysts. Recently there observed a growing interest in the synthesis of
tailor-made polymer supports and functionalized polymers for the
preparation of metal complexes for various applications. They have the
combination of properties due to the macromolecular structure as well as
due to the reactivity of the functional group. An interesting feature of
functional polymers is their affinity towards metal ions. Therefore the
synthesis, characterization and application of such polymeric complexes
have great scientific and analytical importance.
In this investigation three series of polymeric complexes of transition
metal ions are prepared from three schiff bases. All the complexes and
polymeric schiff bases were characterized by analytical, spectral and
thermal methods The thesis consist of six chapters. The first chapter contains an
introduction and a brief review on application of polymer supports, polymer
supported ligands and complexes. The second chapter gives the details of
reagents and instruments used and the procedure adopted for the
preparation of ligands and complexes. The third chapter explains the
methods employed for characterization and the results are also discussed.
The fourth chapter gives a detailed study of metal ion removal using
ligands whereas the fifth chapter describes the development of the Cu” ion
sensor electrode. The sixth chapter is the summary of the thesis and
references are presented at the end.
Description:
Department of Applied Chemistry, Cochin University of Science and Technology