Sosamma,Cherian; Dr.George, Philip(Cochin University of Science And Technology, May , 1984)
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Abstract:
Alpha glucan phosphorylase plays a very
significant role in glycolysis. The inhibition and
activation of this enzyme have significant effect on
the rate of glycolysis. The rate of glycolysis is
also determined by the interconversion between the
active 3 and inactive Q forms of phosphorylase by
two specific enzymes called phosphorylase phosphatase
and phosphorylase kinase. The allosteric properties
and interconversion mechanism reported for
well—studied animal muscle phosphorylases do not
fall under a general pattern. Studies using
purified phosphorylase from marine sources are scanty.
Detailed studies using specialised tissues from more
marine animals are necessary to find the factors that
control the properties and activities of the enzyme.
This thesis is an attempt in this direction. The
thesis deals with a detailed study of the control of
the phosphorylase by both allosterism and
interconversion between the g and b forms from four
different aquatic animals of different habitat. Phosphorylase frm the four different animal muscles were purified either partially or completely and the kinetic and control properties were studied.
Description:
School of marine sciences, Cochin University of Science And Technology
Suresh, M; Dr.Pillai, U T S(Cochin University of Science and Technology, April , 2012)
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Abstract:
Demand on magnesium and its alloys is increased significantly in the automotive industry because of their great potential in reducing the weight of components, thus resulting in improvement in fuel efficiency of the vehicle. To date, most of Mg products have been fabricated by casting, especially, by die-casting because of its high productivity, suitable strength, acceptable quality & dimensional accuracy and the components produced through sand, gravity and low pressure die casting are small extent. In fact, higher solidification rate is possible only in high pressure die casting, which results in finer grain size. However, achieving high cooling rate in gravity casting using sand and permanent moulds is a difficult task, which ends with a coarser grain nature and exhibit poor mechanical properties, which is an important aspect of the performance in industrial applications. Grain refinement is technologically attractive because it generally does not adversely affect ductility and toughness, contrary to most other strengthening methods. Therefore formation of fine grain structure in these castings is crucial, in order to improve the mechanical properties of these cast components.
Therefore, the present investigation is “GRAIN REFINEMENT STUDIES ON Mg AND Mg-Al BASED ALLOYS”. The primary objective of this present investigation is to study the effect of various grain refining inoculants (Al-4B, Al- 5TiB2 master alloys, Al4C3, Charcoal particles) on Pure Mg and Mg-Al alloys such as AZ31, AZ91 and study their grain refining mechanisms. The second objective of this work is to study the effect of superheating process on the grain size of AZ31, AZ91 Mg alloys with and without inoculants addition. In addition, to study the effect of grain refinement on the mechanical properties of Mg and Mg-Al alloys. The thesis is well organized with seven chapters and the details of the studies are given below in detail.
Description:
Materials Science and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST), CSIR
John Kurian,P; Radhakrishna,M(Department of Marine Geology and Geophysics, School of Marine Sciences, 2000)
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Abstract:
The primary aim of the present study is to acquire a large amount of gravity data, to prepare gravity maps and interpret the data in terms of crustal structure below the Bavali shear zone and adjacent regions of northern Kerala. The gravity modeling is basically a tool to obtain knowledge of the subsurface extension of the exposed geological units and their structural relationship with the surroundings. The study is expected to throw light on the nature of the shear zone, crustal configuration below the high-grade granulite terrain and the tectonics operating during geological times in the region. The Bavali shear is manifested in the gravity profiles by a steep gravity gradient. The gravity models indicate that the Bavali shear coincides with steep plane that separates two contrasting crustal densities extending beyond a depth of 30 km possibly down to Moho, justifying it to be a Mantle fault. It is difficult to construct a generalized model of crustal evolution in terms of its varied manifestations using only the gravity data. However, the data constrains several aspects of crustal evolution and provides insights into some of the major events.
Kannan, Balakrishnan; Unnikrishnan, A; Bino, Sebastian V(April , 2012)
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Abstract:
Grey Level Co-occurrence Matrices (GLCM) are one of the earliest techniques used for image texture
analysis. In this paper we defined a new feature called trace extracted from the GLCM and its implications
in texture analysis are discussed in the context of Content Based Image Retrieval (CBIR). The theoretical
extension of GLCM to n-dimensional gray scale images are also discussed. The results indicate that trace
features outperform Haralick features when applied to CBIR.
Description:
International Journal of Computer Science, Engineering and Information Technology (IJCSEIT), Vol.2, No.2, April 2012
Jomon Jacob, P; Dr.Prathapan, S(Cochin University of Science And Technology, January 30, 2013)
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Abstract:
the thesis entitled “Ground and Excited
State Electron Transfer Reaction Between a few Anthracene
Appended Tertiary Amines and Suitable Electron Acceptors”
portrays our attempts to explore the solvent, concentration and
temperature effect of the reaction between a few (anthracen-9-
yl)methanamines with electron acceptors like DMAD, DBA and
DBE. We have also studied the effect of solvent and percentage
fluorescence quenching in the photoinduced electron transfer
reactions of these ‘donor-spacer-acceptor’ systems. Finally we
look in to the intramolecular electron transfer reactions of a few
tertiary amine appended dibenzobarrelenes and
bisdibenzobarrelenes
Description:
Department
of Applied Chemistry, Cochin University of Science and Technology
Premachandran,S K; Dr.Joy, George(Cochin University of Science And Technology, January , 1981)
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Abstract:
The thesis presents the results of the investigations on the crystallisation ‘behaviour, detect
structure end electrical properties of certain organic crystals---phthslic snhydride end potsssiun scid phthalate Hollow crystals of phthalic snhydride were grown from vapour. the norpholog of these hollow crystals were studied in detail and s. mechanism for their growth has been proposed. A closed crystal—vapour system was used to study the basal plane growth of the
whiskers and the sequential growth, observed, confirmed the mechanism suggested for hollow crystals. The dendritic crystals of phthslic enhydride were grown, both iron
the melt and solution. The observed morphologies of these dendrites ere described. Bpherulites of phthalic anhydride have been grown by the artificial initiation of nucleation, from melt and solution. The variation of the substructure oi’ these spherulites with the growth tenperature wee
investigated. The spherulitic filll having ribbon substructure were etched to reveal dislocations. A mechanism for the formation of the observed etch pattern has been suggested. the slip occurring in these ribbons were studied and the results are presented
Description:
Department of physics, Cochin University of Science And Technology
Vanaja, K A; Dr.Jayalekshmi, S(Cochin University of Science and Technology, May , 2011)
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Abstract:
In the present studies, various copper delafossite materials viz; CuAlO2,
CuGaO2, CuFeO2 , CuGa1-xFexO2, CuYO2 and CuCaxY1-xO2 were synthesised by
solid state reaction technique. These copper delafossite materials were grown in
thin film form by rf magnetron sputtering technique. In general copper
delafossites exhibit good optical transparency. The conductivity of the CuYO2
could be improved by Ca doping or by oxygen intercalation by annealing the film in oxygen atmosphere. It has so far been impossible to improve the p-type
conductivity of CuGaO2 significantly by doping Mg or Ca on the Ga site. The ptype
conductivity is presumed to be due to oxygen doping or Cu Vacancies [6].
Reports in literature show, oxygen intercalation or divalent ion doping on Ga
site is not possible for CuGaO2 thin films to improve the p-type conductivity.
Sintered powder and crystals of CuFeO2 have been reported as the materials
having the highest p-type conductivity [14, 15] among the copper and silver
delafossites. However the CuFeO2 films are found to be less transparent in the
visible region compared to CuGaO2. Hence in the present work, the solid
solution between the CuGaO2 and CuFeO2 was effected by solid state reaction,
varying the Fe content. The CuGa1-xFexO2 with Fe content, x=0.5 shows an
increase in conductivity by two orders, compared to CuGaO2 but the
transparency is only about 50% in the visible region which is less than that of
CuGaO2 The synthesis of α−AgGaO2 was carried out by two step process which
involves the synthesis of β-AgGaO2 by ion exchange reaction followed by the
hydrothermal conversion of the β-AgGaO2 into α-AgGaO2. The trace amount of
Ag has been reduced substantially in the two step synthesis compared to the
direct hydrothermal synthesis. Thin films of α-AgGaO2 were prepared on silicon
and Al2O3 substrates by pulsed laser deposition. These studies indicate the
possibility of using this material as p-type material in thin film form for
transparent electronics. The room temperature conductivity of α-AgGaO2 was
measured as 3.17 x 10-4 Scm-1and the optical band gap was estimated as 4.12 eV.
A transparent p-n junction thin film diode on glass substrate was fabricated
using p-type α-AgGaO2 and n-ZnO.AgCoO2 thin films with 50% transparency in the visible region were deposited
on single crystalline Al2O3 and amorphous silica substrates by RF magnetron
sputtering and p type conductivity of AgCoO2 was demonstrated by fabricating
transparent p-n junction diode with AgCoO2 as p-side and ZnO: Al as n-side
using sputtering. The junction thus obtained was found to be rectifying with a
forward to reverse current of about 10 at an applied voltage of 3 V.The present
study shows that silver delafossite thin films with p-type conductivity can be
used for the fabrication of active devices for transparent electronics applications.
Description:
Department of Physics,
Cochin University of Science and Technology
Nisha, M; Jayaraj, M K(Department of Physics, December , 2006)
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Abstract:
The increasing interest in the interaction of light with electricity and
electronically active materials made the materials and techniques for producing
semitransparent electrically conducting films particularly attractive. Transparent
conductors have found major applications in a number of electronic and
optoelectronic devices including resistors, transparent heating elements,
antistatic and electromagnetic shield coatings, transparent electrode for solar
cells, antireflection coatings, heat reflecting mirrors in glass windows and many
other. Tin doped indium oxide (indium tin oxide or ITO) is one of the most
commonly used transparent conducting oxides. At present and likely well into
the future this material offers best available performance in terms of
conductivity and transmittivity combined with excellent environmental stability,
reproducibility and good surface morphology.
Although partial transparency, with a reduction in conductivity, can be obtained
for very thin metallic films, high transparency and simultaneously high
conductivity cannot be attained in intrinsic stoichiometric materials. The only
way this can be achieved is by creating electron degeneracy in a wide bandgap
(Eg > 3eV or more for visible radiation) material by controllably introducing
non-stoichiometry and/or appropriate dopants. These conditions can be
conveniently met for ITO as well as a number of other materials like Zinc oxide,
Cadmium oxide etc.
ITO shows interesting and technologically important combination of properties
viz high luminous transmittance, high IR reflectance, good electrical
conductivity, excellent substrate adherence and chemical inertness. ITO is a key
part of solar cells, window coatings, energy efficient buildings, and flat panel
displays. In solar cells, ITO can be the transparent, conducting top layer that lets
light into the cell to shine the junction and lets electricity flow out. Improving
the ITO layer can help improve the solar cell efficiency. A transparent
ii
conducting oxide is a material with high transparency in a derived part of the
spectrum and high electrical conductivity. Beyond these key properties of
transparent conducting oxides (TCOs), ITO has a number of other key
characteristics. The structure of ITO can be amorphous, crystalline, or mixed,
depending on the deposition temperature and atmosphere. The electro-optical
properties are a function of the crystallinity of the material. In general, ITO
deposited at room temperature is amorphous, and ITO deposited at higher
temperatures is crystalline. Depositing at high temperatures is more expensive
than at room temperature, and this method may not be compatible with the
underlying devices.
The main objective of this thesis work is to optimise the growth conditions of
Indium tin oxide thin films at low processing temperatures. The films are
prepared by radio frequency magnetron sputtering under various deposition
conditions. The films are also deposited on to flexible substrates by employing
bias sputtering technique. The films thus grown were characterised using
different tools. A powder x-ray diffractometer was used to analyse the
crystalline nature of the films. The energy dispersive x-ray analysis (EDX) and
scanning electron microscopy (SEM) were used for evaluating the composition
and morphology of the films. Optical properties were investigated using the UVVIS-
NIR spectrophotometer by recording the transmission/absorption spectra.
The electrical properties were studied using vander Pauw four probe technique.
The plasma generated during the sputtering of the ITO target was analysed using
Langmuir probe and optical emission spectral studies.
Valsala Kumari, C K; Dr.Joy, George(Cochin University of Science and Technology, 1984)
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Abstract:
During the past few decades, a wide spread interest in the structural, optical, electrical and other physical properties of the transition metal dichalcogenide
layer compounds has evolved. The members of this family of compounds can be regarded as stronglybonded two dimensional chalcogen-metal-chalcogen layers
which are loosely coupled to one another by the weak van der Waal's forces. Because of this type of bonding, the crystals are easily cleavable along the basal plane and show highly anisotropic properties. This thesis contains the growth and the study of the physical properties of certain tin dichalcogenide
crystals (SnS2 and Snsea). Tin disulphide and tin diselenide crystallize in the hexagonal CdI2 type crystalstructure. This structure consists of layers of tin
atoms sandwiched between two layers of chalcogen atoms. Aitin atom is surrounded by six chalcogen atoms octahedrally. In the layers the atoms are held together by covalent bonding and in between the layers there is
van der Waal's bonding.
Description:
Department of Physics, Cochin University of Science and Technology
Valsala Kumari, C K; Dr.Joy, George(Cochin University of Science and Technology, September 20, 1984)
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Abstract:
During the past few decades, a wide spread interest in the structural, optical, electrical and
other physical properties of the transition metal dichalcogenide layer compounds has evolved. The members of this family of compounds can be regarded as strongly bonded two dimensional chalcogen-metal~chalcogen layers which are loosely coupled to one another by the weak ven
der Waal's forces. Because of this type of bonding, the crystals are easily cleavable along the basal plane and show highly anisotropic properties. This thesis contains the growth and the study
of the physical properties of certain tin dichalcogenide crystals (SnS2 and SnSe2). Tin disulphide and tin diselenide crystallize in the hexagonal CdI2 type crystal structure. This structure consists of layers of tin atoms sandwiched between two layers of chalcogen atoms. A tin atom is surrounded by six chalcogen atoms octahedrally.In the layers the atoms are held together by
covalent bonding and in between the layers there is van der Waal's bonding.
Description:
Department of Physics, Cochin University of Science and Technology
George, Peter; Dr.Joy, George(Cochin University Of Science And Technology, July 11, 1986)
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Abstract:
Over the past years there has been considerable interest in the
growth of single crystals both from the point of view of basic research
and technological application. With the revolutionary emergence
of solid state electronics which is based on single crystal technolo8Ys
basic and applied studies on crystal growth and characterization
_have gained a-more significant role in material science. These studies
are being carried out for single crystals not only of semiconductor
and other electronic materials but also of metals and insulators.
Many organic crystals belonging to the orthorhombic class exhibit
ferroelectric, electrooptic, triboluminescent and piezoelectric properties.
Diammonium Hydrogen Citrate (DAHC) crystals are reported to
be piezoelectric and triboluminescent /1/. Koptsik et al. /2/ have
reported the piezoelectric nature of Citric Acid Monohydrate (CA)
crystals. And since not much work has been done on these crystals,
it has been thought useful to grow and characterize these crystals.
This thesis presents a study of the growth of these crystals
from solution and their defect structures. The results of the microindentation and thermal analysis are presented. Dielectric, fractographic, infrared (IR) and ultraviolet (UV) studies of DAHC crystals are also reported
Description:
Department of Physics, Cochin University
of Science and Technology