Sunil,K Narayanankutty(John Wiley & Sons. Inc., June 21, 2001)
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Abstract:
The effect of diphenylmethane diisocyanate
(MDI) -polyethyleneglycol (PEG) resin on the cure characteristics and mechanical
properties of nitrile rubber/whole tyre eclaim-short nylon fiber
composite-was studied. At a constant loading of 5 phr, the resin composition
was varied. The minimum torque .,id (maximum - minimum) torque increased
with isocyanate concentration. Scorch time and cure time showed a reduction on
introduction of bonding agent. Properties like tensile strength, tear strength, and
abrasion resistance increased with increase in MDI/PEG ratio, and these
properties are higher in the longitudinal direction of fiber orientation.
Compression set increased with isocyanate concentration and the resilience
remain unchanged.
Blends of nitrile rubber and reclaimed rubber containing different levels of a
coupling agent, Si 69 (bis(3- triethoxysilyl propyl)(tetrasulphide) were prepared
and the cure characteristic's and mechanical properties were studied. Optimum
loading of Si-69 was found to be a function of blend ratio. 3 phi- of Si 69 in a
70:30. Blend was found to be the optimum combination with respect to the
mechanical properties. The rate and state of cure were also affected bv the
conp/ing agent. Tensile strength, tear strength and abrasion resistance were
improved in the presence of coupling agent. While the state of cure improved,
the cure rate and scorch time decreased with increasing silane content. Ageing
studies showed that the blends containing the coupling agent were inferior to
the unmodified blends.