Bindu, Krishnan; Deepthy, A; Litty, Irimpan; Dann, V J; Nampoori, V P N(Elsevier, 2006)
[+]
[-]
Abstract:
We report enhanced back scattering in nanometer-sized ZnO colloids prepared in two different media, by different methods. The FWHM of the back scattered cone and hence the mean free path varied with concentration of ZnO as well as particle size. The Lorentzian profile of backscattered cone indicates the presence of coherence.
Nampoori, V P N; Radhakrishnan, P; Litty, Irimpan; Bindu, Krishnan; Deepthy, A(Journal of Physics D : Applied Physics, August 30, 2007)
[+]
[-]
Abstract:
In this paper, the fluorescence behaviour of nano colloids of ZnO has been
studied as a function of the excitation wavelength. We have found that
excitation at the tail of the absorption band gives rise to an emission that
shifts with the change of the excitation wavelength. The excitation
wavelength dependent shift of the fluorescence maximum is measured to be
between 60 and 100 nm. This kind of excitation wavelength dependent
fluorescence behaviour, which may appear to be in violation of Kasha’s rule
of excitation wavelength independence of the emission spectrum, has been
observed for nano ZnO colloids prepared by two different chemical routes
and different capping agents. It is shown that the existence of a distribution
of energetically different molecules in the ground state coupled with a low
rate of the excited state relaxation processes, namely, solvation and energy
transfer, are responsible for the excitation wavelength dependent
fluorescence behaviour of the systems.
Litty, Irimpan; Deepthy, A; Bindu, Krishnan; Nampoori, V P N; Radhakrishnan, P(Springer, 2008)
[+]
[-]
Abstract:
In the present work, we have investigated the nonlinear
optical properties of self-assembled films formed from
ZnO colloidal spheres by z-scan technique. The sign of the nonlinear
component of refractive index of the material remains
the same; however, a switching from reverse saturable absorption
to saturable absorption has been observed as the material
changes from colloid to self-assembled film. These different
nonlinear characteristics can be mainly attributed to ZnO defect
states and electronic effects when the colloidal solution is
transformed into self-assembled monolayers. We investigated
the intensity, wavelength and size dependence of saturable and
reverse saturable absorption of ZnO self-assembled films and
colloids. Values of the imaginary part of third-order susceptibility
are calculated for particles of size in the range 20–300 nm
at different intensity levels ranging from 40 to 325MW/cm2
within the wavelength range of 450–650 nm.
Bindu, Krishnan; Nampoori, V P N(Indian Academy of Sciences, June , 2005)
[+]
[-]
Abstract:
Nanosized ZnO was prepared by polyol synthesis. Fluorescence spectrum of the ZnO colloid at varying pump intensities was studied. The powder was extracted and characterized by XRD and BET. The extracted powder was screen printed on glass substrates using ethyl cellulose as binder and turpinol as solvent. Coherent back scattering studies were performed on the screen printed sample which showed evidence of weak localization. The screen printed pattern showed strong UV emission.