Now showing items 1-4 of 4
| Abstract: | Vibrational overtone spectra of acetophenone and benzaldehyde in the visible and near-infrared regions are studied by the dual beam thermal lens and the conventional near-infrared absorption techniques. The observed increase in the mechanical frequency of the aryl CH bond from that of benzene is attributed to the decrease in the aryl CH bond length caused by the electron-withdrawing property of the substituents. Overtone spectra also demonstrate that acetophenone contains two types of methyl CH bonds arising from the anisotropic environments created by oxygen lone pair and carbonyl P electrons. The local-mode parameters of the two types of CH bonds are compared with those of acetone and acetaldehyde. The possible factors influencing the methyl CH bonds in acetophenone are discussed. |
| URI: | http://dyuthi.cusat.ac.in/purl/2601 |
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| Dyuthi-P0161.pdf | (916.4Kb) |
| Abstract: | Low power optical phase conjugation in polyvinyl alcohol films embedded with saturable dyes is reported. Phase conjugate reflectivity achieved is higher than that obtained in the case of similar gelatin films. |
| URI: | http://dyuthi.cusat.ac.in/purl/2645 |
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| Dyuthi-P0332.pdf | (209.8Kb) |
| Abstract: | The vibrational overtone spectra 0f the liquid phase 1,2-dichloroethane and 1,2-dibromoethane in the spectral regions of CH stretching local mode overtones corresponding to delta v CH= = 2 to delta v CH=5 are reported. The observed spectral features are assigned using the local mode model. LocaI mode frequencies WCH and diagonal local mode anharmonicities XCH are obtained from an analysis of the spectra. The local-local combinations observed are interpreted on the basis of a coupled CH oscillator model hamiltonian. Local-normal combinations show complex structures and their possible assignments are given. |
| URI: | http://dyuthi.cusat.ac.in/purl/2606 |
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| Dyuthi-P0166.pdf | (472.3Kb) |
| Abstract: | Vibrational overtone spectra of styrene (liquid) and polystyrene (solid), studied by the laser-induced thermal lens (for ΔV=6) and the conventional near infrared absorption (for ΔV=3–5) techniques, are reported. For polystyrene, the overtone energy-bond length correlation predicts that the aryl CH bonds are ∼0.0005 Å longer than that in benzene, while no such conclusions could be drawn on styrene. Thesp 3 CH overtones in polystyrene are observed on the low energy side of the aryl CH overtones. |
| URI: | http://dyuthi.cusat.ac.in/purl/2631 |
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| Dyuthi-P0190.pdf | (256.9Kb) |
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