dc.contributor.author |
Prathapachandra Kurup, M R |
|
dc.contributor.author |
Sithambaresan, M |
|
dc.contributor.author |
Jayakumar, K |
|
dc.date.accessioned |
2014-09-20T06:25:27Z |
|
dc.date.available |
2014-09-20T06:25:27Z |
|
dc.date.issued |
2011-10-31 |
|
dc.identifier.issn |
1600-5368 |
|
dc.identifier.uri |
http://dyuthi.cusat.ac.in/purl/4702 |
|
dc.description |
Acta Cryst. (2011). E67, o3195 |
en_US |
dc.description.abstract |
The title compound, C15H16N4S, exists in the Z conformation
with the thionyl S atom lying cis to the azomethine N atom.
The shortening of the N—N distance [1.3697 (17) A ° ] is due to
extensive delocalization with the pyridine ring. The hydrazine–
carbothioamide unit is almost planar, with a maximum
deviation of 0.013 (2) A ° for the amide N atom. The stability of
this conformation is favoured by the formation of an
intramolecular N—H N hydrogen bond. The packing of
the molecules involves no classical intermolecular hydrogenbonding
interactions; however, a C—H interaction occurs |
en_US |
dc.description.sponsorship |
Cochin University of Science and Technology |
en_US |
dc.language.iso |
en |
en_US |
dc.title |
(Z)-N,N-Dimethyl-2-[phenyl(pyridin-2- yl)methylidene]hydrazinecarbothioamide |
en_US |
dc.type |
Article |
en_US |