Synthesis and Properties of Polyurethanes of Hexamethylene Di-Isocyanate with Multifunctional Chromophores in the Main Chain

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Synthesis and Properties of Polyurethanes of Hexamethylene Di-Isocyanate with Multifunctional Chromophores in the Main Chain

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dc.contributor.author Sreekumar, K
dc.contributor.author Sudheesh Kumar, K
dc.date.accessioned 2014-07-14T09:29:27Z
dc.date.available 2014-07-14T09:29:27Z
dc.date.issued 2007-06-01
dc.identifier.issn 0091-4037 print=1563-535X online
dc.identifier.uri http://dyuthi.cusat.ac.in/purl/4014
dc.description International Journal of Polymeric Materials, 58:160–166, 2009 en_US
dc.description.abstract Various polyurethanes containing photoactive bis(azo) and bis(o-nitrobenzyl) groups in the main chain were synthesized by polyaddition reactions of diols such as bis(4-hydroxyphenylazo)-2,20-dinitrodiphenylmethane, 4-hydroxy-3-methylphenylazo- 40-hydroxyphenylazo-2,20-dinitrodiphenylmethane and bis(4-hydroxy-3- methylphenylazo)-2,20-dinitrodiphenylmethane with hexamethylene di-isocyanate (HMDI), in dimethyl acetamide (DMAc) in the presence of di-n-butyltin dilaurate (DBTDL) as catalyst. All of them were characterized by IR, UV-vis, 1H NMR and 13C NMR spectra and also by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and gel permeation chromatography (GPC). en_US
dc.description.sponsorship Cochin University of Science and Technology en_US
dc.language.iso en en_US
dc.publisher Taylor & Francis en_US
dc.subject bis(azo) en_US
dc.subject bis(o-nitrobenzyl) en_US
dc.subject hexamethylene di-isocyanate en_US
dc.subject polyaddition en_US
dc.subject polyurethanes en_US
dc.title Synthesis and Properties of Polyurethanes of Hexamethylene Di-Isocyanate with Multifunctional Chromophores in the Main Chain en_US
dc.type Article en_US


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