Rosabella,K Puthur; Sebastian, K L; Sugunan, S(Cochin University of Science and Technology, October , 2001)
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The thesis presents the dynamics of a polymer chain under tension. It includes existing theories of polymer fracture, important theories of reaction rates, the rate using multidimensional transition state theory and apply it to the case of polyethylene etc. The main findings of the study are; the life time of the bond is somewhat sensitive to the potential lead to rather different answers, for a given potential a rough estimate of the rate can be obtained by a simples approximation that considers the dynamics of only the bond that breaks and neglects the coupling to neighboring bonds. Dynamics of neighboring bonds would decrease the rate, but usually not more than by one order of magnitude, for the breaking of polyethylene, quantum effects are important only for temperatures below 150K, the lifetime strongly depends on the strain and as the strain varies over a narrow range, the life varies rapidly from 105 seconds to 10_5 seconds, if we change one unit of the polymer by a foreign atom, say by one sulphure atom, in the main chain itself, by a weaker bond, the rate is found to increase by orders of magnitude etc.
Sunandakumari,V M; Dr.Ramanujam, N(Cochin University of Science And Technology, May , 1988)
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Abstract:
During recent years, the theory of differential inequalities has been extensively used to discuss singular perturbation problems and method of lines to partial differential equations. The present thesis deals with some differential inequality theorems and their applications to singularly perturbed initial value problems, boundary value problems for ordinary differential equations
in Banach space and initial boundary value problems for parabolic differential equations. The method of lines to parabolic and elliptic differential equations are also dealt The thesis is organised into nine chapters
Description:
Department of mathematics, Cochin University of Science And Technology
Challa Ravi Kiran; Dr Sundresan, A(Cochin University of Science and Technology, June , 2015)
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Deep fat frying process is one of the widely followed cooking practices throughout the
world. Cooking oils serve as a medium for frying food for transferring heat and makes fried
food tasty and palatable. Frying process is a most complex process involving numerous
physicochemical changes which are complicated to understand. Frying leads to thermal
degradation of oil through thermo-oxidation, hydrolysis, and polymerization. Hydrolysis
results in formation of free fatty acids whereas oxidation process produces hydroperoxides
and small molecular carbonyl compounds. This whole process leads to the formation of polar
compounds and degradation of antioxidants that further degrades frying oil. Eventually,
through mass transfer process these degradation products accumulate into fried food and
reduce the nutritional quality of both oil and food. Thus, the frying process is of research
interest calls for detailed systematic study which is chosen for the present study. The primary
objective of this study is to understand the mechanism of degradation and characterization ofdegraded products which helps in arriving at the limits for frying oil utilization in terms of
number of frying cycles. The mechanistic studies and the knowledge on the degraded
products help to understand the way to retard the deterioration of oil for stability and
enhancement of frying cycles. The study also explores the formation of the predominant
polar compounds and their structural elucidation through mass spectrometry. Oxidation of oil
is another important factor that ignites the degradation phenomena. One of the best ways to
increase thermal stability of any oil is addition of potent antioxidants. But, most of the natural
and synthetic antioxidants are unstable and ineffective at frying temperatures. Therefore, it is
necessary to screen alternative antioxidants for their activity in the refined oils which are devoid of any added antioxidants. In this context, this study discussed the efficacy of several
natural and synthetic antioxidants to retard the formation of polar compounds and thermooxidation
during prolonged frying conditions. Similarly, the advantage of blending of two
different oils to improve the thermal stability was explored. The present study brings out the
total picture on the type of degradation products formed during frying and the ways of
retarding the determination to improve upon the stability of the oil and enhancement of frying
cycles.
Subin, Joseph P; Dr.Jathavedan, M(Cochin University of Science and Technology, January , 2006)
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Abstract:
In this thesis we are studying possible invariants in hydrodynamics and hydromagnetics.
The concept of flux preservation and line preservation of vector fields, especially
vorticity vector fields, have been studied from the very beginning of the study of fluid
mechanics by Helmholtz and others. In ideal magnetohydrodynamic flows the magnetic
fields satisfy the same conservation laws as that of vorticity field in ideal hydrodynamic
flows. Apart from these there are many other fields also in ideal hydrodynamic and magnetohydrodynamic flows which preserves flux across a surface or whose vector lines
are preserved.
A general study using this analogy had not been made for a long time. Moreover
there are other physical quantities which are also invariant under the flow, such as
Ertel invariant. Using the calculus of differential forms Tur and Yanovsky classified
the possible invariants in hydrodynamics. This mathematical abstraction of physical
quantities to topological objects is needed for an elegant and complete analysis of
invariants.Many authors used a four dimensional space-time manifold for analysing fluid flows.
We have also used such a space-time manifold in obtaining invariants in the usual three
dimensional flows.In chapter one we have discussed the invariants related to vorticity field using
vorticity field two form w2 in E4. Corresponding to the invariance of four form w2 ^ w2
we have got the invariance of the quantity E. w. We have shown that in an isentropic
flow this quantity is an invariant over an arbitrary volume.In chapter three we have extended this method to any divergence-free frozen-in
field. In a four dimensional space-time manifold we have defined a closed differential
two form and its potential one from corresponding to such a frozen-in field. Using this
potential one form w1
, it is possible to define the forms dw1 , w1 ^ dw1 and dw1 ^ dw1
.
Corresponding to the invariance of the four form we have got an additional invariant
in the usual hydrodynamic flows, which can not be obtained by considering three
dimensional space.In chapter four we have classified the possible integral invariants associated with
the physical quantities which can be expressed using one form or two form in a three
dimensional flow. After deriving some general results which hold for an arbitrary dimensional
manifold we have illustrated them in the context of flows in three dimensional
Euclidean space JR3. If the Lie derivative of a differential p-form w is not vanishing,then the surface integral of w over all p-surfaces need not be constant of flow. Even
then there exist some special p-surfaces over which the integral is a constant of motion,
if the Lie derivative of w satisfies certain conditions. Such surfaces can be utilised
for investigating the qualitative properties of a flow in the absence of invariance over
all p-surfaces. We have also discussed the conditions for line preservation and surface
preservation of vector fields. We see that the surface preservation need not imply the
line preservation. We have given some examples which illustrate the above results.
The study given in this thesis is a continuation of that started by Vedan et.el. As
mentioned earlier, they have used a four dimensional space-time manifold to obtain
invariants of flow from variational formulation and application of Noether's theorem.
This was from the point of view of hydrodynamic stability studies using Arnold's
method.
The use of a four dimensional manifold has great significance in the study of knots
and links. In the context of hydrodynamics, helicity is a measure of knottedness of
vortex lines. We are interested in the use of differential forms in E4 in the study of
vortex knots and links. The knowledge of surface invariants given in chapter 4 may
also be utilised for the analysis of vortex and magnetic reconnections.
Description:
Department of Mathematics,
Cochin University of Science and Technology
Sethulakshmi, N; Dr. Anantharaman, M. R.(Cochin University of Science and Technology, September , 2014)
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Abstract:
The present thesis work focuses on hole doped lanthanum manganites and their thin film forms. Hole doped lanthanum manganites with higher substitutions of sodium are seldom reported in literature. Such high sodium substituted lanthanum manganites are synthesized and a detailed investigation on their structural and magnetic properties is carried out. Magnetic nature of these materials near room
temperature is investigated explicitly. Magneto caloric application potential of these materials are also investigated. After a thorough investigation of the bulk samples, thin films of the bulk counterparts are also investigated. A magnetoelectric composite with ferroelectric and ferromagnetic components is developed using pulsed laser deposition and the variation in the magnetic and electric properties are investigated. It is established that such a composite could be realized as a potential field effect device. The central theme of this thesis is also on manganites and is with the twin objectives of a material study leading to the demonstration of a device. This is taken up for investigation. Sincere efforts are made to synthesize phase pure compounds. Their structural evaluation, compositional verification and evaluation of ferroelectric and ferromagnetic properties are also taken up. Thus the focus of this investigation is related to the investigation of a magnetoelectric and magnetocaloric application potentials of doped lanthanum manganites with sodium substitution. Bulk samples of sodium substituted lanthanum manganites. Bulk samples of sodium substituted lanthanum manganites with Na substitution ranging from 50 percent to 90 percent were synthesized using a modified citrate gel method and were found to be orthorhombic in structure belonging to a pbnm spacegroup. The variation in lattice parameters and unit cell volume with sodium concentration were also dealt with. Magnetic measurements revealed that magnetization decreased with increase in sodium concentrations.
Rekha,A; Krishnamoorthy,A(Department of Mathematics, Faculty of Science, 2000)
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In this thesis T-policy is implemented to the inventory system with random lead time and also repair in the reliability of k-out-of-n system. Inventory system may be considered as the system of keeping records of the amounts of commodities in stock. Reliability is defined as the ability of an entity to perform a required function under given conditions for a given time interval. It is measured by the probability that an entity E can perform a required function under given conditions for the time interval. In this thesis considered k-out-of-n system with repair and two modes of service under T-policy. In this case first server is available always and second server is activated on elapse of T time units. The lead time is exponentially distributed with parameter and T is exponentially distributed with parameter from the epoch at which it was inactivated after completion of repair of all failed units in the previous cycle, or the moment n-k failed units accumulate. The repaired units are assumed to be as good as new. In this study , three different situations, ie; cold system, warm system and hot system. A k-out-of-n system is called cold, warm or hot according as the functional units do not fail, fail at a lower rate or fail at the same rate when system is shown as that when it is up.
Shali, N B; Dr.Sugunan, S(Cochin University of Science and Technology, April , 2006)
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Catalysis is a mature field with extensive practical applications in today's society.indeed,the catalysis of petroleum refining,fine chemical synthesis and emission control demands the production of catalysts in bulk quantities.Future improvement of these well established processes is likely to be incremental.On the other hand,the continuous demand for new products will require additional novel and innovative processes.The need for pollution abatement and prevention also imposes new demands on catalysis, and new processes are periodically advanced for the control of emission of gases as well as for remediation processes such as the cleaning of underground waters. The number of problems where catalysis can have a big impact is constantly growing.In general,science stimulated by the technology has enriched the field of catalysis in a way that has had broad and lasting value.The thesis"Transition metal and rare earth metal modified sol-gel titania: a versatile catalyst for organic transformations" accounts the preparation and characterization studies of both transition metals and rare earth metals modified sol-gel titania and its applications in industrially useful organic reactions.
Description:
Department of Applied Chemistry,
Cochin University of Science and Technology
Renjusha, S; Dr.Prathapachandra Kurup,M R(Cochin University of Science and Technology, April , 2012)
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Thiosemicarbazones have recently attracted considerable attention due to
their ability to form tridentate chelates with transition metal ions through either
two nitrogen and sulfur atoms, N–N–S or oxygen, nitrogen and sulfur atoms,
O–N–S. Considerable interest in thiosemicarbazones and their transition metal
complexes has also grown in the areas of biology and chemistry due to
biological activities such as antitumoral, fungicidal, bactericidal, antiviral and
nonlinear optical properties. They have been used for metal analyses, for
device applications related to telecommunications, optical computing, storage
and information processing.The versatile applications of metal complexes of thiosemicarbazones in various fields prompted us to synthesize the tridentate NNS-donor
thiosemicarbazones and their metal complexes. As a part of our studies on
transition metal complexes with these ligands, the researcher undertook the current work
with the following objectives.
1. To synthesize and physico-chemically characterize the following
thiosemicarbazone ligands:
a. Di-2-pyridyl ketone-N(4)-methyl thiosemicarbazone (HDpyMeTsc)
b. Di-2-pyridyl ketone-N(4)-ethyl thiosemicarbazone (HDpyETsc)
2. To synthesize oxovanadium(IV), manganese(II), nickel(II), copper(II),
zinc(II) and cadmium(II) complexes using the synthesized
thiosemicarbazones as principal ligands and some anionic coligands.
3. To study the coordination modes of the ligands in metal complexes by
using different physicochemical methods like partial elemental analysis,
thermogravimetry and by different spectroscopic techniques.
4. To establish the structure of compounds by single crystal XRD studies
Description:
Department of Applied Chemistry, Cochin University of Science and Technology
Manju, Sebastian; Dr.Mohammed Yusuff,K K(Cochin University of Science & Technology, July , 2010)
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Abstract:
Schiff base complexes of transition metal ions have played a significant role in coordination chemistry.The convenient route of synthesis and thermal stability of Schiff base complexes have contributed significantly for their possible applications in catalysis,biology,medicine and photonics.Significant variations in cataltytic activity with structure and type are observed for these complexes.The thesis deals with synthsis and characterization of transition metal complexes of quinoxaline based Schiff base ligands and their catalytic activity study.The Schiff bases synthesized in the present study are quinoxaline-2-carboxalidine-2-amino-5-methylphenol,3-hydroxyquinoxaline-2-carboxalidine-2-amino-5-methylphenol,quinoxaline-2-aminothiophenol.They provide great structural diversity during complexation.To the best of our knowledge, the transition metal complexes of quinoxaline based Schiff bases are poorly utilised in academic and industrial research.
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Dept.of Applied Chemistry,Cochin University of Science and Technology