Nirmala, Paul; Dr.Krishna Pillai, M G(Cochin University Of Science And Technology, December 2, 1981)
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Abstract:
The thesis is a report of the attempts made to
prepare semiconducting and dielectric thin films and to
study their electrical properties. It consists of (i)
studies on the preparation and electrical characteristics
of compound semiconductor thin films of silver sulphide
and ferric hydroxide, and (ii) investigations on the electrical
and dielectric properties of plasma polymerized
thin films of para-toluidine element
Description:
Department
of Physics,Cochin University Of Science And Technology
Matlrew, George; Dr.Anantharaman, M R(Cochin University of Science & Technology, February , 2004)
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Abstract:
Magnetism and magnetic materials have been an ever-attractive
subject area for engineers and scientists alike because of its versatility in
finding applications in useful devices. They find applications in a host of
devices ranging from rudimentary devices like loud speakers to sophisticated
gadgets like waveguides and Magnetic Random Access Memories (MRAM).The one and only material in the realm of magnetism that has been at the
centre stage of applications is ferrites and in that spinel ferrites received the
lions share as far as practical applications are concerned.It has been the endeavour of scientists and engineers to remove
obsolescence and improve upon the existing so as to save energy and
integrate in to various other systems. This has been the hallmark of material
scientists and this has led to new materials and new technologies.In the field of ferrites too there has been considerable interest to
devise new materials based on iron oxides and other compounds. This means
synthesising ultra fine particles and tuning its properties to device new
materials. There are various preparation techniques ranging from top- down
to bottom-up approaches. This includes synthesising at molecular level, self
assembling,gas based condensation. Iow temperature eo-precipitation, solgel
process and high energy ball milling. Among these methods sol-gel
process allows good control of the properties of ceramic materials. The
advantage of this method includes processing at low temperature. mixing at
the molecular level and fabrication of novel materials for various devices.Composites are materials. which combine the good qualities of one
or more components. They can be prepared in situ or by mechanical means
by the incorporation of fine particles in appropriate matrixes. The size of the
magnetic powders as well as the nature of matrix affect the processability
and other physical properties of the final product. These plastic/rubber
magnets can in turn be useful for various applications in different devices.
In applications involving ferrites at high frequencies, it is essential that the
material possesses an appropriate dielectric permittivity and suitable
magnetic permeability. This can be achieved by synthesizing rubber ferrite
composites (RFC's). RFCs are very useful materials for microwave
absorptions. Hence the synthesis of ferrites in the nanoregirne.investigations on their size effects on the structural, magnetic, and electrical
properties and the incorporation of these ferrites into polymer matrixes
assume significance.In the present study, nano particles of NiFe204, Li(!5Fe2S04 and
Col-e-O, are prepared by sol gel method. By appropriate heat treatments,
particles of different grain sizes are obtained. The structural, magnetic and
electrical measurements are evaluated as a function of grain size and
temperature. NiFel04 prepared in the ultrafine regime are then incorporated
in nitrile rubber matrix. The incorporation was carried out according to a
specific recipe and for various loadings of magnetic fillers. The cure
characteristics, magnetic properties, electrical properties and mechanical
properties of these elastomer blends are carried out. The electrical
permittivity of all the rubber samples in the X - band are also conducted.
Description:
Department of Physics,
Cochin University of Science & Technology
Mathew, George; Dr.Anantharaman, M R(Cochin University Of Science And Technology, February 16, 2004)
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Abstract:
In the present study, nano particles of NiFe3O4, I_.l()5Feg5O4 and
CoFegO4 are prepared by sol gel method. By appropriate heat treatments,
particles of different grain sizes are obtained. The structural, magnetic and
electrical measurements are evaluated as a function of grain size and
temperature. NiFe3O4 prepared in the ultrafine regime are then incorporated
in nitrile rubber matrix. The incorporation was carried out according to a
specific recipe and for various loadings of magnetic fillers. The cure
characteristics, magnetic properties, electrical properties and mechanical
properties of these elastomer blends are carried out. The electrical
permittivity of all the rubber samples in the X — band are also conducted
Description:
Department of Physics
Cochin University of Science & Technology
Sagar, S; Dr.Anantharaman, M R(Cochin University of Science & Technology, August , 2010)
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Abstract:
This thesis lays importance in the investigation on the multiferroic and
thermooelectric properties of selected representatives of low bandwidth and
intermediate band width manganites. The first candidate, Strontium doped Gd manganite, is prepared by wet solid state reaction method and the second
candidate, Na doped La manganite, by citrate gel method. In addition to the above
mentioned properties, magneto resistance and dielectric properties are
investigated. Using dielectric spectroscopic the dispersion parameters are
correlated to the relaxation mechanisms and an attempt is made to obtain the grain
and grain boundary contribution to the impedance of the sample through
impedance spectroscopy studies.
Description:
Department of Physics,
Cochin University of Science & Technolog
Palson,T I; Dr.Joy, George(Cochin University Of Science And Technology, February 16, 1987)
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Abstract:
The work reported in this thesis is the preparation,
and the structural, electrical and optical properties
of reactively evaporated lead sulphide and tin telluride
thin films. The three temperature method had been used
for the preparation of these semiconductor thin films.
In this preparation technique constituent elements are
evaporated from separate sources with the substrate kept
at a particular temperature. when one of the constituent
element is a gas near room temperature, the method is
often called reactive evaporation. It has been found for
many materials that a stoichiometric interval exists with
a limited range of flux and substrate temperature. Usually
this technique is used for the preparation of thin films of
high melting point compounds or of materials which decompose
during evaporation. Tin telluride and lead sulphide are
neither high melting point materials nor do they decompose
on melting. But even than reactive evaporation offers the
possibility of changing the ratios of the flux of the constituent
elements within a wide range and studying its
effect on the properties of the films
Description:
Department of Physics, Cochin
University of Science and Technology
Vasudevan, K; Dr.Nair, K G(Cochin University of Science and Technology, April 19, 1982)
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Abstract:
Antennas play an important role in determining
the characteristics of any electronic system which depends
on free space as the propagation medium. Basically, an
antenna can be considered as the connecting link between
free space and the transmitter or receiver. For radar and
navigational purposes the directional properties of an
antenna is its most basic requirement as it determines the
distribution of radiated energy. Hence the study of directional properties of antennas has got special significance
and several useful applications.
Description:
Department of Physics, Cochin University of Science and Technology
Dhannia, T; Dr.Jayalekshmi, S(Cochin University of Science and Technology, January 30, 2012)
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Abstract:
This thesis Entitled INVESTIGATIONS ON THE STRUCTURAL, OPTICAL AND MAGNETIC PROPERTIES OF NANOSTRUCTURED CERIUM OXIDE IN PURE AND DOPED FORMS AND ITS POLYMER NANOCOMPOSITES.Synthesis and processing of nanomatelials and nanostmctures are the essential aspects of nanotechnology. Studies on new physical properties and
applications of nanomaterials and nanostructures are possible only when nanostructured materials are made available with desired size, morphology,crystal structure and chemical composition.Recently, several methods have been developed to prepare pure and doped CeO2 powder, including wet chemical synthesis, thermal hydrolysis, flux method, hydrothermal synthesis, gas condensation method, microwave technique etc. In all these, some special reaction conditions, such as high temperature, high pressure, capping agents, expensive or toxic solvents etc. have been involved.Another hi gh-li ght of the present work is room temperature ferromagnetism in cerium oxdie thin films deposited by spray pyrolysis technique.The observation of self trapped exciton mediated PL in ceria nanocrystals is another important outcome of the present study. STE mediated mechanism has been proposed for CeO2 nanocrystals based on the dependence of PL intensity on the annealing temperature. It would be interesting to extent these investigations to the doped forms of cerium oxide and cerium oxide thin
films to get deeper Insight into STE mechanism.Due to time constraints detailed investigations could not be canied out on the preparation and properties of free standing films of polymer/ceria
nanocomposites. It has been observed that good quality free standing films of PVDF/ceria, PS/C61‘l8, PMMA/ceria can be obtained using solution casting technique. These polymer nanocomposite films show high dielectric constant around 20 and offer prospects of applications as gate electrodes in metal-oxide semiconductor devices.
Description:
Division for Research in Advanced Materials,
Department of Physics,
Cochin University of Science and Technology
Dhannia, T; Dr. S. Jayalekshmi(Cochin University of Science and Technology, January 30, 2012)
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Abstract:
In recent years, nanoscience and nanotechnology has emerged as one of
the most important and exciting frontier areas of research interest in almost all
fields of science and technology. This technology provides the path of many
breakthrough changes in the near future in many areas of advanced technological
applications. Nanotechnology is an interdisciplinary area of research and
development. The advent of nanotechnology in the modern times and the
beginning of its systematic study can be thought of to have begun with a lecture by
the famous physicist Richard Feynman. In 1960 he presented a visionary and
prophetic lecture at the meeting of the American Physical Society entitled “there is
plenty of room at the bottom” where he speculated on the possibility and potential of
nanosized materials.
Synthesis of nanomaterials and nanostructures are the essential aspects of
nanotechnology. Studies on new physical properties and applications of
nanomaterials are possible only when materials are made available with desired
size, morphology, crystal structure and chemical composition. Cerium oxide (ceria)
is one of the important functional materials with high mechanical strength, thermal
stability, excellent optical properties, appreciable oxygen ion conductivity and
oxygen storage capacity. Ceria finds a variety of applications in mechanical
polishing of microelectronic devices, as catalysts for three-way automatic exhaust
systems and as additives in ceramics and phosphors. The doped ceria usually has
enhanced catalytic and electrical properties, which depend on a series of factors
such as the particle size, the structural characteristics, morphology etc. Ceria based
solid solutions have been widely identified as promising electrolytes for
intermediate temperature solid oxide fuel cells (SOFC). The success of many
promising device technologies depends on the suitable powder synthesis
techniques. The challenge for introducing new nanopowder synthesis techniques is to preserve high material quality while attaining the desired composition. The
method adopted should give reproducible powder properties, high yield and must
be time and energy effective. The use of a variety of new materials in many
technological applications has been realized through the use of thin films of these
materials. Thus the development of any new material will have good application
potential if it can be deposited in thin film form with the same properties. The
advantageous properties of thin films include the possibility of tailoring the
properties according to film thickness, small mass of the materials involved and
high surface to volume ratio. The synthesis of polymer nanocomposites is an
integral aspect of polymer nanotechnology. By inserting the nanometric inorganic
compounds, the properties of polymers can be improved and this has a lot of
applications depending upon the inorganic filler material present in the polymer.
Vijayan, K K; Dr.Abdul Rasheed, T M(Cochin University Of Science And Technology, October 8, 2003)
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Abstract:
The central theme of this research concerns the study of vibrationally excited
molecules. We have used the local mode description of such vibrational states, and this
-model has now gained general acceptance. A central feature of the model is the
Wloealizafion of vibrational energy. A study of these high—energy localized states provides
example, becauseof this localization, overtone spectra, which measure the absorption of
T vibrational energy, are extremely sensitive to the properties of X-H bonds. We also use
-overtone spectra to study the conformation of molecules, i.e., the relative internal
orientation of their bonds. The thesis comprises six chapters
Description:
Department of Physics Cochin
University of Science and Technology
The present study is an attempt to find out the ralation between RNA/DNA ratio, protein,percentage growth rate and specific growth rate of prawn,Penaeus indicus with respect to Nervous system, Eyestalk and Muscle tissues during ontogenesis. We have isolated and purified a natural agglutinin in the hemolymph of P.indicus with antigenecity, agglutinating, hemolytic and antibacterial properties. The influence of growth and environmental parameters on the level of agglutinin in the hemolymph was studied. Agglutinin concentration during normal growth process was compared. The agglutinin concentration in the hemolymph was quantified through developing ELISA, which is useful in health monitoring studies of individual species. Complete amino acid composition of both the subunits of P.indicus agglutinin were analysed. P.indicus agglutinin showed similarity to those proteins having antigenecity,hemolytic and agglutinating properties.Hence, agglutinin was considered as a natural defence protein in the hemolymph of P.indicus responsible for immune surveillance. The humoral defence mechanism of agglutinin was a co-operative effort with hemocytes and complement system. The composition of isolated agglutinin of P.indicus amino acids will be helpful in the synthesis of new antibacterial analogues which can be used against disease causing organisms.
Description:
Dept. of Biotechnology, Cochin University of Science and Technology