Now showing items 1-13 of 13
Abstract: | Titania is a versatile metal oxide with multiple applications. Titania supported catalysts are reported to be much more active compared to conventional silica or alumina supported ones in some reactions. TiO2 (anatase) having high surface area, with better crystallinity and high onset temperature of rutilation can be prepared by thermal hydrolysis of titanyl sulfate solution under controlled conditions. Calcinations at 350oC for 6 hrs were necessary to crystallize anatase. Method of preparation and percentage of the loaded metal oxides have greater influence on surface area. Drastic decrease in surface area was observed upon rutilation. Rutilation started at different temperatures depending on the metal oxide and the method of preparation. TiO2 should be characterized with high surface area, phase purity and high onset temperature of rutilation.Which should be well above the optimum temperature of a designated reaction in which it is employed as a catalyst. Variation in physical properties, depending upon the method of preparation is greater in TiO2 supported catalysts. Methanation activity was found to be highly dependent on nickel concentration present on the surface of the pellets. The methanation activity is strongly influenced by support material. The rate and turn over frequency of methanation and toluene oxidation activity of these catalysts are also equally important from an industrial point of view. |
URI: | http://dyuthi.cusat.ac.in/purl/38 |
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Dyuthi-T0159.pdf | (3.111Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1741 |
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Dyuthi-T0246.pdf | (2.637Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1840 |
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Dyuthi-T0248.pdf | (1.979Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1728 |
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Dyuthi-T0360.pdf | (5.006Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1745 |
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Dyuthi-T0247.pdf | (2.771Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1740 |
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Dyuthi-T0245.pdf | (1.598Mb) |
Abstract: | The thesis deals with the synthesis, characterization and catalytic activity studies of some new Fe (III), Co (II), Ni (II) and Cu (II) complexes of hydrazones and their zeolite encapsulated analogues. Hydrazones have diverse applications in biological, non-biological and biochemical front. During the present study three hydrazone types of ligands namely, acetylacetone- 2-hydroxyphenylhydrazone (APAcAc), acetoacetanilide- 2-hydroxyphenylhydrazone (APAcAcA) and acetoacetanilide-3,5-dihydro-2,4-dione pyrimidylhydrazone (AUAcAcA) were synthesized by diazotization of primary amine and coupling with compounds containing active methylene group. First part of the thesis deals with the synthesis of Fe, Co, Ni and Cu complexes using three hydrazone types of ligands are given. Details regarding the characterization of these complexes with a view to establishing the molecular structures are presented in this part. The other part contains the method of encapsulation of these complexes in zeolite cavities and their characterizations of the encapsulated metal species are described. A comparitive account of the catalytic activities of the pure and encapsulated complexes for cyclohexanol oxidation was also carried out. |
URI: | http://dyuthi.cusat.ac.in/purl/59 |
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Dyuthi-T0234.pdf | (2.715Mb) |
Abstract: | In the present study an attempt has been made to synthesize some simple complexes of multidentate ligands. Analogous zeolite encapsulated complexes were also synthesized and characterized. Immobilization on to polymer supports through covalent attachment is expected to solve the problem of decomposition of many complexes during catalytic reaction. Hence the work is also extended to the synthesis and characterization of some polymer supported complexes of Schiff base Iigands. All the three types of synthesized complexes, simple, zeolite encapsulated and polystyrene anchored, were subjected to catalytic activity study towards catechol-oxidation reaction. A selected group of complexes were also screened for their catalytic activity towards phenol-oxidation reaction. Biological screening of the synthesized ligands and neat complexes were done with a view to establish the effect of complexation on biological systems. |
Description: | Department of Applied Chemistry, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/2754 |
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Dyuthi-T0779.pdf | (4.480Mb) |
Abstract: | In this regard Schiff base complexes have attracted wide attention. Furthermore, such complexes are found to play important role in analytical chemistry, organic synthesis, metallurgy, refining of metals, electroplating and photography. Many Schiff base complexes are reported in literature. Their properties depend on the nature of the metal ion as well as on the nature of the ligand. By altering the ligands it is possible to obtain desired electronic environment around the metal ion. Thus there is a continuing interest in the synthesis of simple and zeolite encapsulated Schiff base complexes of metal ions. Zeolites have a number of striking structural similarities to the protein portion of natural enzymes. Zeolite based catalysts are known for their remarkable ability of mimicking the chemistry of biological systems. In view of the importance of catalysts in all the areas of modern chemical industries, an effort has been made to synthesize some simple Schiff base complexes, heterogenize them by encapsulating within the supercages of zeoliteY cavities and to study their applications. The thesis deals with studies on the synthesis and characterization of some simple and zeoliteY encapsulated Mn(II), Fe(III), Co(II), Ni(II) and Cu(II) complexes and on the catalytic activity of these complexes on some oxidation reactions. Simple complexes were prepared from the Schiff base ligands SBT derived from 2-aminobenzothiazole and salicylaldehyde and the ligand VBT derived from 2-aminobenzothiazole and vanillin (4-hydroxy-3- methoxybenzaldehyde). ZeoliteY encapsulated Mn(II), Fe(III), Co(II), Ni(II) and Cu(II) complexes of Schiff base ligands SBT and VBT and also of 2-aminobenzothiazole were synthesized. All the prepared complexes were characterized using the physico-chemical techniques such as chemical analysis (employing AAS and CHN analyses), magnetic moment studies, conductance measurements and electronic and FTIR spectra. EPR spectra of the Cu(II) complexes were also carried out to know the probable structures and nature of Cu(II) complexes. Thermogravimetric analyses were carried out to obtain the information regarding the thermal stability of various complexes. The successful encapsulations of the complexes within the cavities of zeoliteY were ascertained by XRD, surface area and pore volume analysis. Assignments of geometries of simple and zeoliteY encapsulated complexes are given in all the cases. Both simple and zeoliteY encapsulated complexes were screened for catalytic activity towards oxidation reactions such as decomposition of hydrogen peroxide, oxidation of benzaldehyde, benzyl alcohol, 1-propanol, 2-propanol and cyclohexanol. |
URI: | http://dyuthi.cusat.ac.in/purl/925 |
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Dyuthi-T0241.pdf | (4.270Mb) |
URI: | http://dyuthi.cusat.ac.in/jspui/handle/dyuthi/1732 |
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Dyuthi-T0230.pdf | (2.903Mb) |
Abstract: | The thesis deals with the synthesis, characterization and catalytic activity studies of supported cobalt(ii), nickel(II) and copper(II) complexes of O-phenylenediamine and Schiff bases derived from 3-hydroxyquinoxaline -2-carboxaldehyde. Zeolite encapsulation and polymer anchoring was employed for supporting the complexes. The characterization techniques proved that the encapsulation as well as polymer supporting has been successfully achieved. The catalytic activity studies revealed that the activities of the simple complexes are improved upon encapsulation. Various characterization techniques are used such as, chemical analysis, EPR, magnetic measurements, FTIR studies, thermal analysis, electronic spectra, XRD, SEM, surface area, and GC.The present study indicated that the that the mechanism of oxidation of catechol and DTBC by hydrogen peroxide is not altered by the change in the coordination sphere around the metal ion due to encapsulation. This fact suggests outer sphere mechanism for the reactions. The catalytic activity by zeolite encapsulated complex was found to be slower than that by the neat complex. The slowing down of the reaction in the zeolite case is probably due to the constraint imposed by the zeolite framework. The rate of DTBC ( 3,5-di-tert-butylchatechol)oxidation was found to be greater than the rate of catechol oxidation. This is obviously due to the presence of electron donating tertiary butyl groups. |
URI: | http://dyuthi.cusat.ac.in/purl/19 |
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Dyuthi-T0232.pdf | (4.670Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1735 |
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Dyuthi-T0300.pdf | (4.571Mb) |
Abstract: | This thesis deals with the synthesis, characterization and catalysis activity studies of some zeolite encapsulated complexes. Encapsulation inside the zeolite cages makes the catalysts more stable. Further, the framework prevents the complexes from dimerising. Catalysis by metal complexes encapsulated in the cavities of zeolites and other molecular sieves has many features of homogeneous, heterogenous and enzymatic catalysis. Serious attempts has been made to gain product selectivity in catalysis .The catalytic activity shown by the encapsulated complexes can be correlated to the structure of the active site inside the zeolite pore. It deals with the studies on the partial oxidation of benzyl alcohol to benzaldehyde. The oxidatio was carried out using hydrogen peroxide as oxidant in presence of PdYDMG and CuYSPP as catalysts. The product (benzaldehyde) was detected using TLC and confirmed using GC.The catalytic activity of the complexes was tested for oxidation under various conditions. The operating conditions like the amount of the catalyst, reaction time, oxidant to substrate ratio, reaction temprature, and solvents have been optimized. No further oxidation products were obtained on continuing the reaction for four hours beyond the optimum time. Maximum conversion was obtained at room temperature and the percentage conversion decreased with increase in temperature. Activity was found to be dependent on the solvent used. With increasing awareness about the dangers of environmental degradation, research in chemistry is getting increasing geared to the development of “green chemistry,” by designing environmentally friendly products and processes that bring down the generation and use of hazardous substances. |
URI: | http://dyuthi.cusat.ac.in/purl/7 |
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Dyuthi-T0348.pdf | (8.523Mb) |
Now showing items 1-13 of 13
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