Philip,Mathew; Dr.Ravindranatha Menon,N(Cochin University of Science and Technology, August , 1990)
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Abstract:
The present scientific investigation of the effects of copper, mercury and cadmium has focussed on their effects on two commercially important marine bivalve species, Perna indica (brown mussel) and Donax incarnatus (wedge clam), conspicuous representatives of the tropical intertidal areas. The investigation centred around delineating the cause and effects of heavy metal stress, individually and in combination on these species under laboratory conditions. A clear understanding of the cause and effect can be had only if laboratory experiments are conducted employing sub-lethal concentrations of the above toxicants. Therefore, during the course of the investigation, sub-lethal concentrations of copper, mercury and cadmium were employed to assess the concentration dependent effects on survival, ventilation rate, O:N ratio and tissues. The results obtained are compared with the already available information and partitioned in sections to make a meaningful presentation.The thesis is presented in five chapters comprising INTRODUCTION, ACUTE TOXICITY, VENTILATION RATE, OXYGEN : NITROGEN RATIO and HISTOPATHOLOGY. Each chapter has been divided into various sections such as INTRODUCTION, REVIEW OF LITERATURE, MATERIAL AND METHODS, RESULTS and DISCUSSION
Description:
Head, Division of Marine Biology, Microbiology and
Biochemistry, School of Marine Sciences, Cochin University
of Science and Technology
Resmi, E A; Dr.Mohanakumar,K(Cochin University Of Science And Technology, September , 2012)
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Abstract:
The stratospheric warming events are categorized into major and minor
warming depending on the temperature increase in the polar stratosphere.
The warming is called a ‘major’, when the polar temperature increases
poleward from 60 degree latitude and followed by a reversal in the zonal
wind at 10 hPa (~32 Km). Usually major warming events are associated
with the displacement of polar vortex from high to mid latitudes or the
splitting of vortices in to two. The warming is called a "Minor", when the
polar temperature increases more than 25 degree in a period of a week or
less, at any stratospheric level with less intensified easterly wind anomalies. The stratospheric warmings generated during the transition
period of winter to spring are called final warmings. The warming events
observed in the early winter period (November to early December) over
Canadian region are called Canadian warmings. There is strong
interaction between stratosphere and troposphere during SSW period over
high and low latitudes regions.
The thesis consists of 7 chapters
Description:
Department of Atmospheric Sciences, Cochin
University of Science and Technology
Rosily, A V; Dr.Chandramohanakumar, N(Cochin University of Science & Technology, December , 2002)
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Abstract:
Sulphur is a non conservative major element and is the most active species in the redox processes in nature, especially in aquatic environment . The varying oxidative states from-2 to +6 make it possible to enter into many of the biogeochemical processes. Thus the history, present and future of the chemical composition and behaviour of the natural aquatic systems and sediments have footprints of the sulphur chemistry.Mangroves are considered to be the most productive, fishery supportive ecosystem operating in the intertidal regions. The interlinking of the mangroves with the sulphur chemistry is attempted here.
Description:
Department of Chemical Oceanography, Cochin University of Science and Technology
Kemthose,P Paul; Dr.Bhasi, M(School of Management Studies, Faculty of Social Sciences, 2003)
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Abstract:
Model development for selection of location for refinery in India and identification of characteristics to be looked into when configuring it and to develop models for integrated supply chain planning for a refinery. Locating and removing inbound, internal and outbound logistic problems in an existing refinery and overall design of a logistic information system for a refinery are the main objectives of the study. A brief description of supply chain management (SCM), elements of SCM and their significance, logistics cost in petroleum industry and its impacts, and dynamics of petroleum its logistic practices are also to be presented. Scope of application of SCM in petroleum refinery will also be discussed. A review of the investigations carried out by earlier researches in the area of supply chain management in general and with specific reference to petroleum refining.
Maya, C Pillai; Rajasenan, D(Ccchin University of Science and Technology, 2003)
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Abstract:
The study deals with the short and long term supply response of the natural rubber in India and to analyse the macro economic environment of NR industry and causative factors of the rubber price crash. It determines the minimum cost of production of natural rubber and to forecast the potential production of NR in India. There is positive response of short run and long run supply to prices. Since correlation analysis show close association between international and domestic price level, international price changes will have its domestic echo. Production and consumption will sustain its rising trend. This makes plans for increasing production estimates show that a mid way level i.e. the range between Rs.32-Rs.38 will give a fair enough profit to the grower in the present situation and provide for the viable sustenance of rubber cultivation. Identification of the SWOT of rubber cultivation would help in supporting rubber cultivation if remedial measures are undertaken with the true spirit. This would help Indian rubber to attain global competitiveness. Then the inflow of valuable foreign exchange will overcome the other economic drawbacks of rubber cultivation
Yoosaf, K; Dr. George Thomas, K(Chemical Sciences and Technology Division,CSIR, January , 2008)
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Abstract:
Most of the procedures reported for the synthesis of metal
nanoparticles involve the use of strong reducing agents or elevated
temperatures. This limits the possibility of developing metal nanoparticle
based sensors for the in situ detection of analytes. One of the objectives of
the present investigations is to (i) develop newer methodologies for the
synthesis of metal nanoparticles in aqueous medium at ambient conditions
and (ii) their use in the detection of metal cations by taking advantage of
the unique coordination ability. Ideally, biocompatible molecules which
possess both the reducing and stabilizing groups are desirable for such
applications. Formation of stable supramolecular assembly, by bringing metal nanoparticles close to each other, results in plasmon coupling and
this strategy can be effectively utilized for the development of metal
nanoparticle based sensors.Another objective of the present study is to understand the
supramolecular organization of molecules on surfaces. Various
noncovalent interactions between the molecules and with surface play a
decisive role in their organizations. An in-depth understanding of these
interactions is essential for device fabrications. Recent photophysical
studies have revealed that phenyleneethynylene based molecular systems
are ideal for device application. The second objective of the thesis focuses
on understanding the (i) organization of phenyleneethynylenes on highly
oriented pyrolytic graphite (HOPG) surface with atomic level precision and
(ii) weak intermolecular interactions which drive their organization.
Krishna Kumar,P A; Chandramohanakumar, N(Cochin University of Science and Technology, October , 1999)
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Abstract:
This study focuses on the fractionation and quantification of chlorophenols, the most important and potential pollutant in this category, the distribution and seasonal dynamics of MBAS, phenols and clorophenols and development of a model to describe the chemical reactivity of the estuary are utilizing the dynamics of boron. The CES is highly influenced by various anthropogenic activities like discharge of agricultural, industrial and urban wastes operation of shipyard, oil and other transporting activities, fishing, dredging etc. Seasonal values of MBAS showed high values in the surface water during monsoon compared to premonsoon and postmonsoon. In the Cochin estuary o-chlorophenol and p-chlorophenol showed low values in the surface water compared to bottom water in the northern part of the estuary and higher values in the surface water in the southern part
Akula Raghunadha, Rao; Basil, Mathew(Naval Physical & Oceanographic Laboratory,Defence Research and Development Organisation, 2008)
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Abstract:
In the present study the availability of satellite altimeter sea level data with good spatial and temporal resolution is explored to describe and understand circulation of the tropical Indian Ocean. The derived geostrophic circulations showed large variability in all scales. The seasonal cycle described using monthly climatology generated using 12 years SSH data from 1993 to 2004 revealed several new aspects of tropical Indian Ocean circulation. The interannual variability presented in this study using monthly means of SSH data for 12 years have shown large year-to-year variability. The EOF analysis has shown the influence of several periodic signals in the annual and interannual scales where the relative strengths of the signals also varied from year to year. Since one of the reasons for this kind of variability in circulation is the presence of planetary waves. This study discussed the influence of such waves on circulation by presenting two cases one in the Arabian Sea and other in the Bay of Bengal.
Jalaja, Malayan J; Dr.Sugunan, S(Cochin University of Science and Technology, December , 1994)
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Abstract:
The rare earths have provided fascinating field
for chemists confronted with problems of their separation
and purification. The rare earths become available in
relatively pure form in recent years due to the development
of efficient separation methods, largely as a byproduct of
the atomic energy programmes of various countries. The
rare earths often called lanthanides from La (Z=57) to Lu
(Z=7l) display subtle variation of properties through the
series, while the differences become appreciable for the
elements that are farther apart.
Description:
Department of
Applied Chemistry, Cochin University of Science and
Technology
Ramankutty, C G; Dr.Sugunan, S(Cochin University of Science & Technology, November , 2000)
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Abstract:
The present study describes the surface properties and catalytic activities of
ferrospinels containing Co, Ni and Cu prepared by the low temperature route. Various
physico-chemical methods have been adopted to characterise the systems. The reactions
carried out are the Friedel-Crafts benzoylation of aromatics and the cyclohexanol
decomposition. We have attempted the sulphate modification of the ferrites and have
studied the surface and catalytic properties of the sulphated analogues.The work is presented in six chapters, the last chapter giving the summary and
conclusions of the results presented earlier. Our samples prove as potential catalysts for
the benzoylation of aromatics , for which truly heterogeneous catalysts are rare. Again ,
the materials show remarkable dehydration/dehydrogenation activities during
cyclohexanol decomposition. There is plenty of scope for research in this field, especially
in the development of environmentally benign catalysts for acylation reactions.
Description:
Department of Applied Chemistry,
Cochin University of Science and Technology
Nishamol,Kanat; Sugunan, S(Department of applied chemistry, 2002)
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Abstract:
In recent years considerable advances have been achieved in the study of the surface structure and mechanism of action of environmentally benign heterogeneous catalysts. The study entitled as surface properties and catalytic activity of manganese ferrospinels. In the present study we have prepared manganese ferrospinels of general formula Mn(1-x)BxFe2O4 via low temperature controlled co-precipation method. The study employed low temperature co-precipitation method for the preparation ofMn(1-x)BxFe2O4 specimens, where B is a metal cation such as Cr,Co, Ni,Cu and Zn. The catalytic activities of the systems were investigated for liquid-phase benzoylation of aromatic compounds and phenol hydroxylation and for vapour-phase reactions such as aniline alkylation, phenol methylation and ODH of ethylbenzene. The different series of manganese ferrites are proved to be excellent catalysts for various industrially important reactions such as Friedel-crafts benzoylation of aromatic compounds, methylation of aniline and phenol, hydroxylation of phenol and oxidative dehydrogenation of ethylbenzene. Due to the tightening of the environmental regulations, production of diphenols from phenol hydroxylation and reduction of phenolic pollutants in waste waters using these catalysts can be a promising approach because it demands only simple techniques and produce little environmental pollution.