Anantharaman, M R; Mathew, George; Philip, Kurian(Wiley Subscription Services, Inc., A Wiley Company, September 22, 2010)
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Abstract:
Ultra fine nickel ferrite have been synthesized
by the sol-gel method. By heat treating different portions
of the prepared powder separately at different
temperatures, nano-sized particles of nickel ferrite with
varying particle sizes were obtained. These powders were
characterised by the X-ray diffraction and then incorporated
in the nitrile rubber matrix according to a specific
recipe for various loadings. The cure characteristics and
the mechanical properties of these rubber ferrite composites
(RFCs) were evaluated. The effect of loading and the
grain size of the filler on the cure characteristics and tensile
properties were also evaluated. It is found that the
grain size and porosity of the filler plays a vital role in
determining the mechanical properties of the RFCs
Reena, T A; Dr.Prathapachandra Kurup,M R(Cochin University of Science & Technology, March , 2011)
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Abstract:
The present work is concentrated on the studies of two novel
semicarbazones, di-2-pyridyl ketone-N4-phenyl-3-semicarbazone (HL1) and
quinoline-2-carboxaldehyde-N4-phenyl-3-semicarbazone (HL2). The compositions
of these semicarbazones were determined by the CHN analyses. For the
characterization of these compounds we have used IR, UV and NMR spectral
studies. The molecular structure of quinoline-2-carboxaldehyde-N4-phenyl-3-
semicarbazone (HL2) was obtained by single crystal X-ray diffraction studies.
Also, we have synthesized Zn(II), Cd(II), Cu(II), Ni(II), Co(II) and Mn(II)
complexes of these semicarbazones, HL1 and HL2. These complexes were
characterized by various spectroscopic techniques, magnetic and conductivity
studies. We could isolate single crystals of some Zn(II) and Cd(II) compounds
suitable for X-ray diffraction studies. For other complexes we could not isolate
single crystals of good quality for single crystal X-ray diffraction studies.
Description:
Department of Applied Chemistry,
Cochin University of Science and Technology
Mohammed Yusuff, K K; Varsha, Gopalakrishnan; Arun, Vasudevan; Robinson, P P; Manju, Sebastian; Digna, Varghese; Leeju, P; Jayachandran, V P(Elesvier,Tetrahedron Letters (2010), February 15, 2010)
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Abstract:
An efficient one-pot synthesis of two new heterocyclic perimidines 4-(2,3-dihydro-1H-perimidin-2-yl)-2-methoxyphenol and
2-(quinoxalin-2-yl)-2,3-dihydro-1H-perimidine in good yields is presented. This methodology provides a simple, straightforward synthetic
route to these interesting classes of heterocycles. Crystal structure, solvatochromism and antibacterial activity of these organic compounds
are discussed.