Abstract: | Development of molecular probes for the selective and sensitive detection of analytes has been an active area of research because such effective molecules can have biological and medicinal applications. Of the various probes reported, the fluorescence based systems have attracted much attention owing to their high sensitivity, fast response time, non–invasiveness and technical simplicity. However, the quantification of a target analyte using the fluorescent probe that acts through a single emission response (either increase or decrease in the fluorescence intensity) can have disadvantages, when compared to the systems that show either dual emission or ratiometric changes. In the case of the systems that exhibit ratiometric changes, the ratio of the fluorescence intensity of the two different wavelengths can be utilized for the quantification of the analyte of interest. Such an observation will have an effective internal referencing that greatly increases the sensitivity of the detection. In this context, it was our objective to develop functional organic systems and to explore their potential as sensitive fluorescent probes for the recognition of anions, cations and biomolecules. The present thesis has been divided into four chapters and of which the first chapter gives an overview on the organic fluorescent probes, with a particular emphasis on their mechanism of molecular recognition. In addition, the specific objectives of the present thesis were also briefly described at the end of this chapter. |
URI: | http://dyuthi.cusat.ac.in/purl/5150 |
Files | Size |
---|---|
Dyuthi-T2184.pdf | (10.85Mb) |
Abstract: | Multimodal imaging agents that combine magnetic and fluorescent imaging capabilities are desirable for the high spatial and temporal resolution. In the present work, we report the synthesis of multifunctional fluorescent ferrofluids using iron oxide as the magnetic core and rhodamine B as fluorochrome shell. The core–shell structure was designed in such a way that fluorescence quenching due to the inner magnetic core was minimized by an intermediate layer of silica. The intermediate passive layer of silica was realized by a novel method which involves the esterification reaction between the epoxy group of prehydrolysed 3-Glyidoxypropyltrimethoxysilane and the surfactant over iron oxide. The as-synthesized ferrofluids have a high saturation magnetization in the range of 62–65 emu/g and were found to emit light of wavelength 640 nm ( excitation = 446 nm). Time resolved life time decay analysis showed a bi-exponential decay pattern with an increase in the decay life time in the presence of intermediate silica layer. Cytotoxicity studies confirmed the cell viability of these materials. The in vitro MRI imaging illustrated a high contrast when these multimodal nano probes were employed and the R2 relaxivity of these ∗Author to whom correspondence should be addressed. Email: smissmis@gmail.com sample was found to be 334 mM−1s−1 which reveals its high potential as a T2 contrast enhancing agent |
Description: | Material Express, Vol. 2, No. 4, 2012 |
URI: | http://dyuthi.cusat.ac.in/purl/4400 |
Files | Size |
---|---|
Fluorescent Sup ... imodalCellular Imaging.pdf | (7.439Mb) |
Abstract: | The paper presents a maximally flat compact planar filter employing folded Stepped Impedance Resonators (SIR) and Complementary Split Ring Resonators (CSRR), for Ultra Wide Band (UWB) applications. An interdigital quarter wavelength coupled line is used for achieving the band pass characteristics. The filter has low insertion loss in its pass band and steep roll off rate and good attenuation in its lower and upper stop bands. The measured microwave characteristics of the fabricated filter show good agreement with the simulated response |
Description: | Electronic System Design (ISED), 2013 International Symposium on |
URI: | http://dyuthi.cusat.ac.in/purl/4341 |
Files | Size |
---|---|
Folded SIR with ... Wide Band Applications.pdf | (385.5Kb) |
Abstract: | In the present investigation, an attempt is made to study late Quaternary foraminiferal and pteropod records of the shelf of northern Kerala and to evaluate their potentiality in paleocenographic and paleoclimatic reconstruction. The study gives details of sediment cores, general characteristics of foraminifera and pteropod species recorded from the examined samples and their systematic classification, spatial distribution of Recent foraminifera and pteropods and their response to varying bathymetry, nature of substrate, organic matter content in sediment and hydrography across the shelf. An attempt is also made to establish an integrated chronostratigraphy for the examined core sections. An effort is also made to identify microfaunal criteria useful in biostratigraphic division in shallow marine core sections. An attempt is made to infer various factors responsible for the change in microfaunal assemblage. Reconstruction of sea level changes during the last 36,000 years was attempted based on the pteropod record. The study reveals a bathymetric control on benthic/planktic (BF/PF) foraminiferal and pteropods/planktic foraminiferal (Pt/PF) abundance ratio. Bathymetric distribution pattern of BF/PF ratio is opposite to the (Pt/PF) ratio with decreasing trend of former from the shore across the shelf. Quantitative benthic foraminiferal record in the surficial sediments reveals a positive correlation between the diversity and bathymetry. R-mode cluster analysis performed on 30n significant Recent benthic foraminiferal, determines three major assemblage. |
URI: | http://dyuthi.cusat.ac.in/purl/74 |
Files | Size |
---|---|
Dyuthi-T0552.pdf | (7.582Mb) |
Abstract: | Professor Irma Glicman Adelman, an Irish Economist working in California University at Berkely, in her research work on ‘Development Over Two Centuries’, which is published in the Journal of Evolutionary Economics, 1995, has identified that India, along with China, would be one of the largest economies in this 21st Century. She has stated that the period 1700 - 1820 is the period of Netherlands, the period 1820 - 1890 is the period of England the period 1890 - 2000 is the period of America and this 21st Century is the century of China and India. World Bank has also identified India as one of the leading players of this century after China. India will be third largest economy after USA and China. India will challenge the Global Economic Order in the next 15 years. India will overtake Italian economy in 2015, England economy in 2020, Japan economy in 2025 and USA economy in 2050 (China will overtake Japan economy in 2016 and USA economy in 2027). India has the following advantages compared with other economies. India is 4th largest GDP in the world in terms of Purchasing Power. India is third fastest growing economy in the world after China and Vietnam. Service sector contributes around 57% of GDP. The share of agriculture is around 17% and Manufacture is 16% in 2005 - 2006. This is a character of a developed country. Expected GDP growth rate is 10% shortly (It has come down from 9.2% in 2006 - 2007 to 6.2% during 2008 - 2009 due to recession. It is only a temporary phenomenon). India has $284 billion as Foreign Exchange Reserve as on today. India had just $1 billion as Foreign Exchange Reserve when it opened its economy in the year 1991. In this research paper an attempt has been made to study the two booming economies of the globe with respect to their foreign exchange reserves. This study mainly based on secondary data published by respective governments and various studies done on this area |
Description: | African Journal of Marketing Management Vol. 2(4) pp. 69-79, April 2010 |
URI: | http://dyuthi.cusat.ac.in/purl/4298 |
Files | Size |
---|---|
Foreign exchange reserves in India and China.pdf | (265.1Kb) |
URI: | http://dyuthi.cusat.ac.in/purl/5336 |
Files | Size |
---|---|
Dyuthi T-2403.pdf | (12.35Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/5323 |
Files | Size |
---|---|
Dyuthi T-2359.pdf | (9.406Mb) |
Abstract: | Forest is essential for the healthy subsistence of human being on earth. Law has been framed to regulate exploitation of forest.This study is an analysis of the law relating to forest from an environmental perspective.Practical suggestions are also made for the better protection of forest .Forest is a valuable component of human environment.For healthy subsistence of human beings on earth it is essential that at least one third of the land area on earth should be under forest cover. Forest helps in keeping air and water fresh and climate good.The Indian Forest Act 1927 and State legislation relating to forest impose Governmental control over forests by classifying them into reserved forests. Protected forests and village forests.Effective environmental impact studies facilitate adoption of the practice of sustainable development.Permission should not be granted for a project before examination of its impact on the flora and fauna in forest.Kerala, much of the vested forest remains under the control of the State Government and are managed like reserved forests.Infrastructural facilities require improvement in almost all States for protecting forest.Inter-State problems can be minimised if a central forest legislation is applied uniformly throughout India.Voluntary organisations should be encouraged to taxe part actively in the programmes for conserving forest and wildlife.The new Forest Act should provide for effective environmental impact study before development projects are undertaken in forest areas. The guidelines for this should be clearly laid down in the Act.The law relating to forest should also clearly lay down the guidelines for implementing social forestry programmes. The Forest Department should be authorised to lease lands for planting useful trees. The new forest legislation should also recognise the traditional tribal rights in forest. The Indian Forest Act 1927 and the State legislation relating to forest with their outdated revenue policy and scheme should be replaced by such a new forest legislation framed with an environmental peres-pective. The new law should be uniformly applied throughout India . |
Description: | Department of Law, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3093 |
Files | Size |
---|---|
Dyuthi-T1067.pdf | (18.32Mb) |
Abstract: | This thesis deals with preparing stoichiometric crystalline thin films of InSe and In2Se3 by elemental evapouration and their property investigation.In the present study three temperature( or Elemental evapouration) method is utilized for the deposition of crystalline thin films . The deposition mechanism using three temperature method deals’ with condensation of solids on heated surfaces when the critical supersaturation of the vapour phase exceeds a certain limit. The critical values of the incident flux are related to substrate temperature and the interfacial energies of the involved vapours. At a favorable presence of component atoms in the vapour phase these can react and condense onto a substrate even at a elevated temperature. In the studies conducted the most significant factor is the formation of single compositional film namely indium mono selenide in the In –se system of compounds .Further this work shows the feasibility of thin film photovoltaic junctions of the schottky barrier type |
Description: | Department of Physics, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3158 |
Files | Size |
---|---|
Dyuthi-T1132.pdf | (8.537Mb) |
Abstract: | Due to the great versatility of the properties of polymer thin films, special interest has been taken in recent years on their preparation and electrical properties. The present thesis is entirely devoted to the study of the formation, structure and electrical properties of plasma» polymerised polyacrylonitrile (PAN) thin films. Eventhough the studies are confined to a single polymer film, the results in general are applicable to similar polar polymer films. |
Description: | Department of Physics,Cochin University Of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3616 |
Files | Size |
---|---|
Dyuthi-T1574.pdf | (8.616Mb) |
Abstract: | Hydrographic characteristics of the southwest coast of India and its adjoining Cochin backwaters (CBW) were studied during the summer monsoon period. Anomalous formation of anoxia and denitrification were observed in the bottom layers of CBW, which 5 have not been previously reported elsewhere in any tropical estuarine systems. The prevalent upwelling in the Arabian Sea (AS) brought cool, high saline, oxygen deficient and nutrient-rich waters towards the coastal zone and bottom layers of CBW during the high tide. High freshwater discharge in the surface layers brought high amount of nutrients and makes the CBW system highly productive. Intrusion of AS waters seems 10 to be stronger towards the upstream end ( 15 km), than had been previously reported, as a consequence of the lowering of river discharges and deepening of channels in the estuary. Time series measurements in the lower reaches of CBW indicated a low mixing zone with increased stratification, 3 h after the high tide (highest high tide) and high variation in vertical mixing during the spring and neap phases. The upwelled waters 15 (O2 40 μM) intruded into the estuary was found to lose more oxygen during the neap phase (suboxic O2 4 μM) than spring phase (hypoxic O2 10 μM). Increased stratification coupled with low ventilation and presence of high organic matter have resulted in an anoxic condition (O2 = 0), 2–6 km away from barmouth of the estuary and leads to the formation of hydrogen sulphide. The reduction of nitrate and formation of nitrite 20 within the oxygen deficient waters indicated strong denitrification intensity in the estuary. The expansion of oxygen deficient zone, denitrification and formation of hydrogen sulphide may lead to a destruction of biodiversity and an increase of green house gas emissions from this region |
Description: | Biogeosciences Discuss., 7, 1751–1782, 2010 |
URI: | http://dyuthi.cusat.ac.in/purl/4598 |
Files | Size |
---|---|
Formation of an ... uthwest coast of India.pdf | (6.957Mb) |
Abstract: | An unusual copper(II) complex [Cu(L1a)2Cl2] CH3OH H2O H3O+Cl (1a) was isolated from a solution of a novel tricopper(II) complex [Cu3(HL1)Cl2]Cl3 2H2O (1) in methanol, where L1a is 3-(2-pyridyl)triazolo [1,5-a]-pyridine, and characterized with single crystal X-ray diffraction study. The tricopper(II) complex of potential ligand 1,5-bis(di-2-pyridyl ketone) carbohydrazone (H2L1) was synthesized and physicochemically characterized, while the formation of the complex 1a was followed by time-dependant monitoring of the UV–visible spectra, which reveals degradation of ligand backbone as intensity loss of bands corresponding to O?Cu(II) charge transfer |
Description: | Inorganic Chemistry Communications 12 (2009) 952–955 |
URI: | http://dyuthi.cusat.ac.in/purl/4006 |
Files | Size |
---|---|
Formation of an ... carbohydrazone complex.pdf | (330.3Kb) |
Abstract: | Transition metal acetylides, MC2 (M=Fe, Co and Ni), exhibit ferromagnetic behavior of which TC is characteristic of their size and structure. CoC2 synthesized in anhydrous condition exhibited cubic structure with disordered C2− 2 orientation. Once being exposed to water (or air), the particles behave ferromagnetically due to the lengthening of the Co–Co distance by the coordination of water molecules to Co2+ cations. Heating of these particles induces segregation of metallic cores with carbon mantles. Electron beam or 193 nm laser beam can produce nanoparticles with metallic cores covered with carbon mantles |
Description: | Eur. Phys. J. D 34, 219–222 (2005) |
URI: | http://dyuthi.cusat.ac.in/purl/4550 |
Files | Size |
---|---|
Formation of ca ... ctron beam irradiation.pdf | (272.6Kb) |
Abstract: | The flange technique, suggested by Reynolds72 is simple technique to improve antenna characteristics. Using flange technique we can trim the antenna characteristic by suitably adjusting the flange parameters75. Later corrugated flanges87 are used for beam shaping. The important parameters of the corrugated flanges are (a) flange angle, (b) flange width, (c) flange position, (d) conductivity of the flange, (e) amplitude excitation of the flange elements, (f) period of corrugation etc. Compared to a compound horn the flange technique offers great convenience in trimming antenna characteristics. Horns are commonly used as a feed in radar and satellite communications. A large number of work had been done to improve the characteristics of horn antennas. It is an established fact that grooved walls on the inner surface of a horn can improve the antenna characteristics44. Corrugated comb surface can be used for the circular polarization98, tilt of polarization99 etc. This suggests the possibility to combine these two phenomena and to obtain a resultant beam. This thesis presents the result of an investigation to study the possibility of controlling different antenna characteristics like polarization, beam shaping, matching etc, using corrugated flange techniques. |
Description: | Department of physics, Cochin University of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3476 |
Files | Size |
---|---|
Dyuthi-T1473.pdf | (8.996Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1103 |
Files | Size |
---|---|
Mohanan P 1985.pdf | (1.825Mb) |
URI: | http://dyuthi.cusat.ac.in/purl/1096 |
Files | Size |
---|---|
Mohanachandran K 1983.pdf | (555.8Kb) |
Abstract: | In this paper the class of continuous bivariate distributions that has form-invariant weighted distribution with weight function w(x1, x2) ¼ xa1 1 xa2 2 is identified. It is shown that the class includes some well known bivariate models. Bayesian inference on the parameters of the class is considered and it is shown that there exist natural conjugate priors for the parameters |
Description: | Statistics, 2003, Vol. 37(3), pp. 259–269 |
URI: | http://dyuthi.cusat.ac.in/purl/4278 |
Files | Size |
---|---|
Form-invariant bivariate weighted.pdf | (165.5Kb) |
Abstract: | The distribution of three important dissolved forms of nitrogen, viz. nitrate, nitrite and urea in the surface and bottom water samples collected from 27 selected hydrographic profiles, in the Arabian Sea, along the west coast of India is described. Of the three forms, nitrate concentrations were the highest and comparatively higher concentrations were observed in the bottom water. Decomposition of organic matter resulting in the release of the thermodynamically stable nitrogen species, i.e. nitrate, may be the major factor resulting in higher nitrate concentrations at these depths, where the water is also characterized by low values of dissolved oxygen and temperature. The significant positive correlation between A.O.U. and nitrate of the bottom water samples emphasizes the role of oxidative decomposition of organic matter which plays an active role in reducing the oxygen concentrations below the theoretical values since at this depth ( 200 m) the net production is taken to be zero. This is also evidenced by the negative correlation of nitrate with dissolved oxygen and temperature, for the bottom samples |
Description: | Chemistry and Ecology, 2002, Vol. 18(3–4), pp. 233–244 |
URI: | http://dyuthi.cusat.ac.in/purl/4613 |
Files | Size |
---|---|
Forms Of Nitrog ... Waters Of Arabian Sea.pdf | (187.6Kb) |
Abstract: | After skin cancer, breast cancer accounts for the second greatest number of cancer diagnoses in women. Currently the etiologies of breast cancer are unknown, and there is no generally accepted therapy for preventing it. Therefore, the best way to improve the prognosis for breast cancer is early detection and treatment. Computer aided detection systems (CAD) for detecting masses or micro-calcifications in mammograms have already been used and proven to be a potentially powerful tool , so the radiologists are attracted by the effectiveness of clinical application of CAD systems. Fractal geometry is well suited for describing the complex physiological structures that defy the traditional Euclidean geometry, which is based on smooth shapes. The major contribution of this research include the development of • A new fractal feature to accurately classify mammograms into normal and normal (i)With masses (benign or malignant) (ii) with microcalcifications (benign or malignant) • A novel fast fractal modeling method to identify the presence of microcalcifications by fractal modeling of mammograms and then subtracting the modeled image from the original mammogram. The performances of these methods were evaluated using different standard statistical analysis methods. The results obtained indicate that the developed methods are highly beneficial for assisting radiologists in making diagnostic decisions. The mammograms for the study were obtained from the two online databases namely, MIAS (Mammographic Image Analysis Society) and DDSM (Digital Database for Screening Mammography. |
Description: | Department of Electronics, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3047 |
Files | Size |
---|---|
Dyuthi-T1021.pdf | (24.09Mb) |
Abstract: | Phosphorus fractionation was employed to find the bioavailability of phosphorus and its seasonal variations in the Panangad region of Cochin estuary, the largest estuarine system in the southwest coast of India. Sequential extraction of the surficial sediments using chelating agents was taken as a tool for this. Phosphate in the water column showed seasonal variations, with high values during the monsoon months, suggesting external runoff. Sediment texture was found to be the main factor influencing the spatial distribution of the geochemical parameters in the study region. Similarly, total phosphorus also showed granulometric dependence and it ranged between 319.54 and 2,938.83 μg/g. Calcium-bound fraction was the main phosphorus pool in the estuary. Significant spatial variations were observed for all bioavailable fractions; iron-bound inorganic phosphorus (5.04–474.24 μg/g), calcium-bound inorganic phosphorus (11.16–826.09 μg/g), and acidsoluble organic phosphorus (22.22–365.86 μg/g). Among the non-bioavailable phosphorus, alkalisoluble organic fraction was the major one (51.92– 1,002.45 μg/g). Residual organic phosphorus was K. R. Renjith (B) · N. Chandramohanakumar · M. M. Joseph Department of Chemical Oceanography, School of Marine Sciences, Cochin University of Science and Technology, Kochi 682016, Kerala, India e-mail: renjithaqua@gmail.com comparatively smaller fraction (3.25–14.64% of total). The sandy and muddy stations showed distinct fractional composition and the speciation study could endorse the overall geochemical character. There could be buffering of phosphorus, suggested by the increase in the percentage of bioavailable fractions during the lean premonsoon period, counteracting the decreases in the external loads. Principal component analysis was employed to find the possible processes influencing the speciation of phosphorus in the study region |
Description: | Environ Monit Assess (2011) 174:299–312 |
URI: | http://dyuthi.cusat.ac.in/purl/4601 |
Files | Size |
---|---|
Fractionation a ... tuary, Southwest India.pdf | (437.1Kb) |
Dyuthi Digital Repository Copyright © 2007-2011 Cochin University of Science and Technology. Items in Dyuthi are protected by copyright, with all rights reserved, unless otherwise indicated.