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Dyuthi @ CUSAT >
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Dr. M.R.Prathapachandra Kurup >
Please use this identifier to cite or link to this item:
http://purl.org/purl/4702
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| Title: | (Z)-N,N-Dimethyl-2-[phenyl(pyridin-2- yl)methylidene]hydrazinecarbothioamide |
| Authors: | Prathapachandra Kurup, M R
Sithambaresan, M
Jayakumar, K |
| Issue Date: | 31-Oct-2011 |
| Abstract: | The title compound, C15H16N4S, exists in the Z conformation
with the thionyl S atom lying cis to the azomethine N atom.
The shortening of the N—N distance [1.3697 (17) A ° ] is due to
extensive delocalization with the pyridine ring. The hydrazine–
carbothioamide unit is almost planar, with a maximum
deviation of 0.013 (2) A ° for the amide N atom. The stability of
this conformation is favoured by the formation of an
intramolecular N—H N hydrogen bond. The packing of
the molecules involves no classical intermolecular hydrogenbonding
interactions; however, a C—H interaction occurs |
| Description: | Acta Cryst. (2011). E67, o3195 |
| URI: | http://dyuthi.cusat.ac.in/purl/4702 |
| ISSN: | 1600-5368 |
| Appears in Collections: | Dr. M.R.Prathapachandra Kurup
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