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Please use this identifier to cite or link to this item: http://purl.org/purl/4359

Title: Investigations on the electrical and structural properties of polyaniline doped with camphor sulphonic acid
Authors: Anantharaman, M R
Saravanan, S
Joseph, Mathai C
Venkitachalam, S
Prabhakaran, P V
Keywords: A. Polymers
C. X-ray diffraction
D. Dielectric properties
D. Electrical conductivity
Issue Date: 11-Jan-2006
Publisher: Elsevier
Abstract: Polyaniline is chemically synthesised and doped with camphor sulphonic acid. FTIR studies carried out on these samples indicate that the aromatic rings are retained after polymerisation. The percentage of crystallinity for polyaniline doped with camphor sulphonic acid has been estimated from the X-ray diffraction studies and is around 56% with respect to polyaniline emeraldine base. The change in dielectric permittivity with respect to temperature and frequency is explained on the basis of interfacial polarisation. AC conductivity is evaluated from the observed dielectric permittivity. The values of AC and DC conductivity and activation energy are calculated. The activation energy values suggested that the hopping conduction is the prominent conduction mechanism in this system.
Description: Journal of Physics and Chemistry of Solids 67 (2006) 1496–1501
URI: http://dyuthi.cusat.ac.in/purl/4359
Appears in Collections:Dr. M R Anantharaman

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