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Please use this identifier to cite or link to this item: http://purl.org/purl/4014

Title: Synthesis and Properties of Polyurethanes of Hexamethylene Di-Isocyanate with Multifunctional Chromophores in the Main Chain
Authors: Sreekumar, K
Sudheesh Kumar, K
Keywords: bis(azo)
bis(o-nitrobenzyl)
hexamethylene di-isocyanate
polyaddition
polyurethanes
Issue Date: 1-Jun-2007
Publisher: Taylor & Francis
Abstract: Various polyurethanes containing photoactive bis(azo) and bis(o-nitrobenzyl) groups in the main chain were synthesized by polyaddition reactions of diols such as bis(4-hydroxyphenylazo)-2,20-dinitrodiphenylmethane, 4-hydroxy-3-methylphenylazo- 40-hydroxyphenylazo-2,20-dinitrodiphenylmethane and bis(4-hydroxy-3- methylphenylazo)-2,20-dinitrodiphenylmethane with hexamethylene di-isocyanate (HMDI), in dimethyl acetamide (DMAc) in the presence of di-n-butyltin dilaurate (DBTDL) as catalyst. All of them were characterized by IR, UV-vis, 1H NMR and 13C NMR spectra and also by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and gel permeation chromatography (GPC).
Description: International Journal of Polymeric Materials, 58:160–166, 2009
URI: http://dyuthi.cusat.ac.in/purl/4014
ISSN: 0091-4037 print=1563-535X online
Appears in Collections:Dr. Sreekumar K

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