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Please use this identifier to cite or link to this item: http://purl.org/purl/2790

Title: Transition Metal Complexes with Ring Incorporated Thiosemicarbazones: Syntheses,Structures and Spectral Properties
Authors: Laly, K
Dr.Prathapachandra Kurup,M R
Keywords: Thiosemiocarbazones
Proligands
Mn(II) Complexes
Fe(III) Complexes
Ni(II) Complexes
Copper(II) Complexes
Zinc(II) Complexes
Cd(II)complexes
Chemistry
Applied Chemistry
Issue Date: Jul-2011
Publisher: Cochin University of Science and Technology
Abstract: In the present work,the chelating behaviour of thiosemicarbazones of a heterocyclic diketone, 2,6-diacetylpyridine is studied,with the aim of investigating the influence coordination exerts on their conformation and /or configuration, in connection with the nature of the metal and of the counter ion.The various possibilities like unsubstitution,ring incorporation at terminal nitrogen and condensation of one of the ketone group alone have been tried for ligand selection.Mainly first row transition metals like manganese,iron,nickel,copper,zinc and cadmium are studied.Metals like cobalt also were studied but could not result in fruitful isolation of the compound due to solubility problems.Different spectroscopic and characterization techniques have been utilized to reveal the nature of the metal and the ligands in coordinated metal complex.
Description: Department of Applied Chemistry,Cochin University of Science and Technology
URI: http://dyuthi.cusat.ac.in/purl/2790
Appears in Collections:Faculty of Sciences

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