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Please use this identifier to cite or link to this item: http://purl.org/purl/2631

Title: Overtone spectra of styrene and polystyrene in the visible and near infrared regions
Authors: Abdul Rasheed, T M
Moosad, K P B
Nampoori, V P N
Sathianandan, K
Technology
Keywords: Overtone spectroscopy
CH bond lengths
thermal lens technique.
Issue Date: Sep-1989
Publisher: Springer
Abstract: Vibrational overtone spectra of styrene (liquid) and polystyrene (solid), studied by the laser-induced thermal lens (for ΔV=6) and the conventional near infrared absorption (for ΔV=3–5) techniques, are reported. For polystyrene, the overtone energy-bond length correlation predicts that the aryl CH bonds are ∼0.0005 Å longer than that in benzene, while no such conclusions could be drawn on styrene. Thesp 3 CH overtones in polystyrene are observed on the low energy side of the aryl CH overtones.
URI: http://dyuthi.cusat.ac.in/purl/2631
Appears in Collections:Dr. V P N Nampoori

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