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Please use this identifier to cite or link to this item: http://purl.org/purl/2543

Title: Transition Metal Complexes of Schiff Bases with Azide and Thiocyanate as Coligands:Spectral and Structural Investigations
Authors: Sreesha, Sasi
Dr.Prathapachandra Kurup,M R
Science
Keywords: Copper(ll) complexes
manganese(II) complexes
nickel(II) complexes
cobalt complexes
cadmium(II) complexes
Pseudohalogens
Azide
Thiocyanate
Schiff bases
Issue Date: Oct-2008
Publisher: Cochin University of Science & Technology
Abstract: Metallo-organic chemistry,incorporating the frontiers of both inorganic and organic chemical aspects,is a topic of utility concern.The first exploration of coordinated metal complexes dates back to the ninettenth century,during the days of Alfred Werner.Thereafter,inorganic chemistry witnessed a great outflow of coordination compounds,with unique structural characteristics and diverse applicatons.The diversity in structures exhibited by the coordination complexes of multidentate ligands have led to their usage as sensors,models for enzyme mimetic centers,medicines etc.The liganda chosen are of prime importance in determining the properties of coordination compounds.Schiff bases are compounds obtained by the condensation of an aidehyde or ketone with an amine.The chemical properties of Schiff bases and their complexes are widely explored in recent years owing to their pharmacological activity,their catalytic activities and so on.On the other hand pseudohalides like azide and thiocyanate are versatile candidates for the construction of dimeric or polymeric complexes having excellent properties and diverse applications.So a combination of the Schiff bases and the pseudohalogens for the synthesis of metal complexes can bring about interesting results.An attempt into this area is the besis of this Ph.D theis.
Description: Department of Applied Chemistry, Cochln University of Science and Technology
URI: http://dyuthi.cusat.ac.in/purl/2543
Appears in Collections:Faculty of Sciences

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