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Please use this identifier to cite or link to this item: http://purl.org/purl/2223

Title: Second Order Fit for Mercuric Chloride Catalysed Solvolysis of Alkyl Chlorides in Aqueous DMSO Solvents
Authors: Sugunan, S
Anantaraman, R
Keywords: Mercuric Chloride Catalysed Solvolysis
Alkyl Chlorides
Aqueous DMSO Solvent
Issue Date: Dec-1982
Publisher: Indian Journal of Chemistry
Abstract: Kinetics of mercuric chloride catalysed solvolysis of l-butyl chloride, benzyl chloride. p-methylbenzyl chloride, l-phenylethyl chloride and triethylcarbinyl chloride have been studied in aq. DMSO, aq. acetonitrile and aq. ethanol. The kinetic data fit a second order rate equation in aq. DMSO. The calculated values of the second order rate coefficients increase in the case of aq. acetonitrile and aq. ethanol. The order in catalyst in 95%(v/v) aq. DMSO is less than unity.
URI: http://dyuthi.cusat.ac.in/purl/2223
Appears in Collections:Dr. Sugunan S

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