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Dyuthi @ CUSAT >
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Dr. Sugunan S >
Please use this identifier to cite or link to this item:
http://purl.org/purl/2223
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| Title: | Second Order Fit for Mercuric Chloride Catalysed Solvolysis of Alkyl Chlorides in Aqueous DMSO Solvents |
| Authors: | Sugunan, S
Anantaraman, R
Science |
| Keywords: | Mercuric Chloride Catalysed Solvolysis
Alkyl Chlorides
Aqueous DMSO Solvent |
| Issue Date: | Dec-1982 |
| Publisher: | Indian Journal of Chemistry |
| Abstract: | Kinetics of mercuric chloride catalysed solvolysis of l-butyl
chloride, benzyl chloride. p-methylbenzyl chloride, l-phenylethyl
chloride and triethylcarbinyl chloride have been studied in aq.
DMSO, aq. acetonitrile and aq. ethanol. The kinetic data fit a second
order rate equation in aq. DMSO. The calculated values of the
second order rate coefficients increase in the case of aq. acetonitrile
and aq. ethanol. The order in catalyst in 95%(v/v) aq. DMSO is less
than unity. |
| URI: | http://dyuthi.cusat.ac.in/purl/2223 |
| Appears in Collections: | Dr. Sugunan S
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