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Dyuthi @ CUSAT >
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Dr. Sugunan S >
Please use this identifier to cite or link to this item:
http://purl.org/purl/2210
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| Title: | Liquid-phase Friedel-Crafts acylation using NixMn(l-x)Fe2O4 spinel catalysts |
| Authors: | Sugunan, S
Nishamol, K
Science |
| Keywords: | Liquid-phase Friedel-Crafts acylation
Chemistry
catalysts |
| Issue Date: | May-2002 |
| Publisher: | Indian Journal of Chemistry |
| Abstract: | The liquid-phase Friedel-Crafts acylation of toluene using benzoyl chloride as benzoylating agent has heen carried out over Nix, Mn(l-x)Fe2 O4 (x=O, 0.2, 0.4, 0.6, 0.8 and 1.0) type systems under different reaction conditions. It is observed that the systems with high 'x' values are effective for the conversion of BOC and the selective formation of 4-MBP. Selectivity for 4-MBP over MnFe2O4 is more than 90% under the optimized reaction conditions. Sites of moderate acidity is effective in calalyzing the benzoylation reaction. |
| URI: | http://dyuthi.cusat.ac.in/purl/2210 |
| Appears in Collections: | Dr. Sugunan S
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