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Please use this identifier to cite or link to this item: http://purl.org/purl/1993

Title: Photophysical and Electrochemical Investigations on Photoconducting Poly(6-tert-butyl-3,4-dihydro-2H- 1,3-benzoxazine)
Authors: Sreekumar, K
Kishore,V C
Sudha Kartha, C
Rani, Joseph
Keywords: conducting polymers
glass transition
UV-vis spectroscopy
Issue Date: 2009
Publisher: Wiley InterScience
Abstract: Poly(6-tert-butyl-3,4-dihydro-2H-1,3-benzoxazine) was synthesized by thermally activated cationic ring opening polymerization. The structure of the polymer was confirmed by spectral and thermal studies. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) were estimated using cyclic voltammetry and optical absorption. Modulated photocurrent measurement technique was employed to study the spectral and field dependence of photocurrent. Photocurrent of the order of 1.5 micro A/m2 was obtained for polymer at a biasing electric field of 40 V/mico m.
URI: http://dyuthi.cusat.ac.in/xmlui/purl/1993
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