Modification of Unsaturated Polyester Resin by Polyurethane Prepolymers

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Modification of Unsaturated Polyester Resin by Polyurethane Prepolymers

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dc.contributor.author Eby Thomas, Thachil
dc.contributor.author Benny Cherian, A
dc.contributor.author Beena, Abraham T
dc.date.accessioned 2014-08-30T05:22:31Z
dc.date.available 2014-08-30T05:22:31Z
dc.date.issued 2006
dc.identifier.uri http://dyuthi.cusat.ac.in/purl/4688
dc.description Journal of Applied Polymer Science, Vol. 100, 449–456 (2006) en_US
dc.description.abstract Unsaturated polyester resins (UPRs) are extensively used by the fiber-reinforced plastic (FRPs) industry. These resins have the disadvantages of brittleness and poor resistance to crack propagation. In this study, UPRs were chemically modified by reactive blending with polyurethane prepolymers having terminal isocyanate groups. Hybrid networks were formed by copolymerisation of unsaturated polyesters with styrene and simultaneous reaction between terminal hydroxyl groups of unsaturated polyester and isocyanate groups of polyurethane prepolymer. The prepolymers were based on toluene diisocyanate (TDI) and each of hydroxy-terminated natural rubber (HTNR), hydroxy- terminated polybutadiene (HTPB), polyethylene glycol (PEG), and castor oil. Properties like tensile strength, toughness, impact resistance, and elongation-at-break of the modified UPRs show considerable improvement by this modification. The thermal stability of the copolymer is also marginally better en_US
dc.description.sponsorship Cochin University of Science and Technology en_US
dc.language.iso en en_US
dc.publisher Wiley Periodicals en_US
dc.subject hybrid polymer networks en_US
dc.subject impact resistance en_US
dc.subject polyurethane prepolymers en_US
dc.subject toughness en_US
dc.subject unsaturated polyester resin en_US
dc.title Modification of Unsaturated Polyester Resin by Polyurethane Prepolymers en_US
dc.type Article en_US


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