The effect of glass additives on the densification , phase evolution, microstructure and microwave dielectric properties of Ba(Mg1;3
Ta2i3)03 (BMT) was investigated . Different weight percentages of quenched glass such as B203 , Si02, B203-SiO2, ZnO-B203,
5ZnO-2B2O3, Al203-SiO2, Na20-2B203.10H20, BaO-B203-SiO2, MgO-B203-SiO2, PbO-B203-SiO2 , ZnO-B203-SiO2 and
2MgO-Al203-5SiO2 were added to calcined BMT precursor . The sintering temperature of the glass -added BMT samples were
lowered down to 1300 °C compared to solid-state sintering where the temperature was 1650 °C. The formation of high temperature
satellite phases such as Ba5Ta4O15 and Ba7Ta6O22 were found to be suppressed by the glass addition . Addition of glass systems such
as B203, ZnO-B203, 5ZnO-2B203 and ZnO-B203-SiO2 improved the densification and microwave dielectric properties. Other
glasses were found to react with BMT to form low-Q phases which prevented densification . The microwave dielectric properties of
undoped BMT with a densification of 93 . 1 % of the theoretical density were Cr = 24 . 8, Tr = 8 ppm/°C and Q„ x f= 80,000 GHz. The
BMT doped with 1.0 wt% of B203 has Q„ x f = 124,700GHz, Cr = 24.2, and T f = -1.3 ppm /°C. The unloaded Q factor of 0.2 wt%
ZnO-B203-doped BMT was 136,500 GHz while that of 1.0 wt% of 5ZnO-2B203 added ceramic was Q„ x f= 141,800 GHz . The best
microwave quality factor was observed for ZnO -B203-SiO2 (ZBS) glass-added ceramics which can act as a perfect liquid-phase
medium for the sintering of BMT. The microwave dielectric properties of 0.2wt% ZBS-added BMT dielectric was
Q„ x f= 152,800 GHz, F,= 25.5, and Tr = - 1.5 ppm/°C
Abdul Khalam,L; Sreemoolanadhan,H; Ratheesh, R; Mohanan, P; Sebastian,M T(ELSEVIER, 2003)
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Abstract:
Microwave dielectric resonators (DRs) based on Ba(B1,2Nbi/2)03 [B' = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Yb, and In] complex
perovskites have been prepared by conventional solid state ceramic route. The dielectric properties (relative permittivity, Er; quality factor, Q;
and resonant frequency, rr) of the ceramics have been measured in the frequency range 4-6 GHz using resonance methods. The resonators
have relatively high dielectric constant in the range 36-45, high quality factor and small temperature variation of resonant frequency. The
dielectric properties are found to depend on the tolerance factor (t), ionic radius (r), and lattice parameter (ap)
The BaO-2CeO2-nTiO2 ceramics with n = 3, 4 and 5 have been prepared with CeO2 as starting material . The ceramics have been
characterized using scanning electron microscopy , X-ray diffraction , Raman and X-ray photoelectron spectroscopy techniques. The
microwave dielectric properties have been measured using standard dielectric resonator techniques . BaO-2CeO2-3TiO2 (123),
BaO-2CeO2-4TiO2 ( 124) and BaO-2CeO2-5TiO2 ( 125) ceramics showed dielectric constants of 38, 27 and 32, respectively . All the
ceramics showed fairly good unloaded Q - factors . 124 and 125 compounds exhibited low tf values, while 123 showed a high rf value
The microwave dielectric properties of ZnAl2O4 spinels were investigated and their properties
were tailored by adding different mole fractions of Ti02. The samples were synthesized using the mixed
oxide rout.e. The phase purity and crystal structure were identified using X-ray diffraction technique.
The sintered specimens were characterized in the microwave frequency range (3-13 GHz). The ZnA12O4
ceramics exhibited interesting dielectric properties (dielectric constant (e,.) = 8.5, unloaded quality factor
(Q.) = 4590 at 12.27 GHz and temperature coefficient of resonant frequency (Tf) = -79 ppm/°C).
Addition of Ti02 into the spinel improved its properties and the Tf approached zero for 0.83ZnAl2O4-
0.17TiO2• This temperature compensated composition has excellent microwave dielectric properties (Cr _
12.67, Q, = 9950 at 10.075 GHz) which can be exploited for microwave substrate applications