| dc.contributor.author |
Prathapachandra Kurup, M R |
|
| dc.contributor.author |
Manoj, E |
|
| dc.contributor.author |
Rohith, John P |
|
| dc.contributor.author |
Nethaji, M |
|
| dc.contributor.author |
Alex, Punnoose |
|
| dc.date.accessioned |
2014-07-14T06:43:17Z |
|
| dc.date.available |
2014-07-14T06:43:17Z |
|
| dc.date.issued |
2009-07-16 |
|
| dc.identifier.uri |
http://dyuthi.cusat.ac.in/purl/4006 |
|
| dc.description |
Inorganic Chemistry Communications 12 (2009) 952–955 |
en_US |
| dc.description.abstract |
An unusual copper(II) complex [Cu(L1a)2Cl2] CH3OH H2O H3O+Cl (1a) was isolated from a solution of a
novel tricopper(II) complex [Cu3(HL1)Cl2]Cl3 2H2O (1) in methanol, where L1a is 3-(2-pyridyl)triazolo
[1,5-a]-pyridine, and characterized with single crystal X-ray diffraction study. The tricopper(II) complex
of potential ligand 1,5-bis(di-2-pyridyl ketone) carbohydrazone (H2L1) was synthesized and physicochemically
characterized, while the formation of the complex 1a was followed by time-dependant monitoring
of the UV–visible spectra, which reveals degradation of ligand backbone as intensity loss of bands
corresponding to O?Cu(II) charge transfer |
en_US |
| dc.description.sponsorship |
Cochin University of Science and Technology |
en_US |
| dc.language.iso |
en |
en_US |
| dc.publisher |
Elsevier |
en_US |
| dc.subject |
Carbohydrazone |
en_US |
| dc.subject |
Cu(II) complex |
en_US |
| dc.subject |
Synthesis |
en_US |
| dc.subject |
Dipyridyl ketone |
en_US |
| dc.subject |
Antiferromagnetism |
en_US |
| dc.subject |
EPR |
en_US |
| dc.subject |
Crystal structure |
en_US |
| dc.title |
Formation of an unusual copper(II) complex from the degradation of a novel tricopper(II) carbohydrazone complex |
en_US |
| dc.type |
Article |
en_US |