Thermochemistry of Charge-Transfer Complexes of 7,7,8,8-Tetracyanoquinodimethane with Benzene and Its Chloro Derivatives

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Thermochemistry of Charge-Transfer Complexes of 7,7,8,8-Tetracyanoquinodimethane with Benzene and Its Chloro Derivatives

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dc.contributor.author Sugunan, S
dc.contributor.author Ramankutty, C G
dc.date.accessioned 2011-09-16T06:55:53Z
dc.date.available 2011-09-16T06:55:53Z
dc.date.issued 1995
dc.identifier.other J. Chem. Eng. Data, 1995, 40 (2), pp 417–418
dc.identifier.uri http://dyuthi.cusat.ac.in/purl/2286
dc.description.abstract The enthalpies of formation of charge-transfer complexes of benzene, chlorobenzene, and 1,3-dichlorobenzene as donors with 7,7,8,8-tetracyanoquinodimethane as acceptor were determined. The thermochemical data show an increased stability of charge-transfer complexes of donors with permanent dipole moment. The results confirm the importance of electrostatic forces in bonding and stabilizing weak complexes. The approximate formation constants of the complexes are also reported. en_US
dc.description.sponsorship Cochin University of Science and Technology en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject 7,7,8,8-Tetracyanoquinodimethane en_US
dc.subject Benzene en_US
dc.subject Chloro Derivatives en_US
dc.title Thermochemistry of Charge-Transfer Complexes of 7,7,8,8-Tetracyanoquinodimethane with Benzene and Its Chloro Derivatives en_US
dc.type Working Paper en_US
dc.contributor.faculty Science en_US
dc.identifier.url DOI:10.1021/je00018a011 en_US


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