Unnikrishnan, K P; Jayan,Thomas; Nampoori, V P N; Vallabhan, C P G(Elsevier, June , 2002)
[+]
[-]
Abstract:
Here we report measurements of third-order susceptibility χ(3), figure of merit F defined as χ(3)/α (where α is the absorption coefficient) and second hyperpolarizability 〈γ〉 of some metal substituted phthalocyanines and a naphthalocyanine in solutions of dimethyl formamide using degenerate four wave mixing at 532 nm under nanosecond excitation. It was found that among samples investigated, bis-naphthalocyanine possessed the highest value of 〈γ〉 followed by the bis-phthalocyanine. This observation is explained on the basis that bis-naphthalocyanine followed by bis-phthalocyanine has higher degree of π electron conjugation.
Rajasree, K; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(IOP, 1993)
[+]
[-]
Abstract:
A pulsed Nd-YAG laser beam is used to produce a transient refractive index gradient in air adjoining the plane surface of the sample material. This refractive index gradient is probed by a continuous He-Ne laser beam propagating parallel to the sample surface. The observed deflection signals produced by the probe beam exhibit drastic variations when the pump laser energy density crosses the damage threshold for the sample. The measurements are used to estimate the damage threshold for a few polymer samples. The present values are found to be in good agreement with those determined by other methods.
Jayaraj, M K; Vallabhan, C P G(Elsevier, October , 1989)
[+]
[-]
Abstract:
The dielectric properties of vacuum-deposited europium oxide films have been investigated in the frequency range from 1 kHz to 1 MHz at various temperatures (300-543 K). The dielectric constant is found to depend on film thickness and it attains a constant value beyond 1000 Å. Films deposited at higher substrate temperatures (above 423 K) exhibit improved dielectric properties owing to the recovery of stoichiometry. The frequency variation of the loss factor exhibits a minimum which increases with rise in temperature. The breakdown field strength (about 106V cm-1) is found to be thickness dependent and it varies in accordance with the Forlani-Minnaja relation. The films exhibit ohmic conduction with an activation energy of 0.86 eV at low electric fields but at higher fields the conductivity becomes space charge limited. X-ray studies show that the films are amorphous in nature. The a.c. conductivity is proportional to ω at low frequency, whereas a square law dependence is observed at higher frequencies. The optical constants n, α and k and optical band gap are calculated from the UV-visible-near-IR spectra.
Jayaraj, M K; Vallabhan, C P G(Thin Solid Films, 1991)
[+]
[-]
Abstract:
The dielectric properties of electron beam evaporated Sm2O3 films have been
investigated in the frequency range from 1 kHz to 1 MHz at various temperatures
(300 K-453 K). The dielectric constant is found to depend on film thickness and it
attains a constant value beyond 1000 A. The present electron beam evaporated
Sm2O3 films have a high dielectric constant of 43. The frequency dependence of
and tan teeta at various temperatures is also studied.
Riju, C Issac; Vasudevan Pillai, K; Harilal, S S; Geetha K, Varier; Bindhu, C V; Pramod, Gopinath; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Elsevier Science, 1998)
[+]
[-]
Abstract:
Laser produced plasma from silver is generated using a Q-switched Nd:YAG laser. Optical emission spectroscopy is used
to carry out time of flight (TOF) analysis of atomic particles. An anomalous double peak profile in the TOF distribution is
observed at low pressure. A collection of slower species emerge at reduced pressure below 4 X lO-3 mbar and this species
has a greater velocity spread. At high pressure the plasma expansion follows the shockwave model with cylindrical
symmetry whereas at reduced pressure it shows unsteady adiabatic expansion (UAE). During UAE the species show a
parabolic increases in the expansion time with radial distance whereas during shock wave expansion the exponent is less
than one. The angular distribution of the ablated species in the plume is obtained from the measurement of optical density of
thin films deposited on to glass substrates kept perpendicular to the plume. There is a sharp variation in the film thickness
away from the film centre due to asymmetries in the plume.
Pillai, S M; Vallabhan, C P G(Solid State Communications, 1983)
[+]
[-]
Abstract:
ZnS: Cu: Cl phosphor prepared under a vacuum firing process is found to
give blue electroluminescence with emission peak at 460 nm which remams
unaltered with the frequency of the excitation voltage. Addition of excess
chlorine in the phosphor gives blue, green and red emission at 460, 520
and 640 run. The intensity of the blue band decreases and It fmally
disappears as chlorine concentration is increased. A scheme involving
three energy levels attributed to Cu2+, Cu+ and Cl- centres in Zns
explains the experimental results completely.
Measurements of dc conductivity and dielectric constant show that deuteration causes an upward shift of the high temperature phase transition point from 186.5 to 191°C and a downward shift of the low temperature transition point from 10 to -1.5°C in LiNH4SO4. Mechanisms of phase transitions and of electrical transport in the crystal are discussed.
Sajan, D George; Augustine, S; Mathai, E; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(WILEY-VCH Verlag GmbH&Co, 2003)
[+]
[-]
Abstract:
An open cell configuration has been employed for the photoacoustic measurement of the thermal diffusivity of undoped Bi2Se3 crystals and Bi2Se3 crystals doped with various concentrations of Te. The amplitude of the photoacoustic signal obtained under heat transmission configuration as a function of chopping frequency is used to evaluate the numerical value of thermal diffusivity, α. Doped samples show a substantial reduction in the value of α compared to undoped samples. The variations in the thermal diffusivity of the doped samples are explained in terms of the phonon assisted heat transfer mechanism. It is seen that α is very sensitive to structural variations arising from doping. The experimentally observed results are correlated with X-ray diffraction studies.
Syamaprasad, U; Vallabhan, C P G(Elsevier, May , 1981)
[+]
[-]
Abstract:
Anomalous variations of d.c. electrical conductivity with temperature are observed in ammonium sulphate single crystals, suggesting a possible phase transition at 150°C. Measurements of thermally stimulated current also support these results. The mechanism of electrical conduction is explained on the basis of studies made on doped and quenched crystals.
Navil Kumar, R; Vallabhan, C P G(IOP Publishing, 1989)
[+]
[-]
Abstract:
DC and AC electrical conductivity measurements in single crystals of diammonium hydrogen phosphate along the c axis show anomalous variations at 174, 246 and 416 K. The low-frequency dielectric constant also exhibits peaks exactly at these temperatures with a thermal hysteresis of 13 degrees C for the peak at 416 K. These specific features of the electrical properties are in agreement with earlier NMR second-moment data and can be identified with three distinct phase transitions that occur in the crystal. The electrical conductivity values have been found to increase linearly with impurity concentration in specimens doped with a specific amount of SO42- ions. The mechanisms of the phase transition and of the electrical conduction process are discussed in detail.
Santhakumari, N C; Vallabhan, C P G(Elsevier, May , 1992)
[+]
[-]
Abstract:
D.C. and a.c. electrical conductivities, dielectric constant and dielectric loss factor in single crystals of ethylenediammonium sulphate, (H3NCH2CH2NH3)(SO4), have been measured axiswise as a function of temperature. Anomalous variations in all the above properties at 480 K indicate the occurrence of a phase transition in the above material at this temperature. The existence of such a phase transition is also confirmed by DSC measurements. Electrical conductivity results are analysed and the activation energies of conduction at different temperature regions have been evaluated from the logσ vs 103T−1 plot. Possible mechanisms for the electrical conduction process are discussed, the available results being in favour of a proton transport model.
Santhakumari, N C; Vallabhan, C P G(Elsevier, April , 1991)
[+]
[-]
Abstract:
dc and ac electrical conductivities, dielectric constant and dielectric loss factor in single crystals of ethylenediammonium dinitrate (EDN) have been measured axiswise as a function of temperature. All the above properties exhibit anomalous variations at 404 K thereby confirming the occurence of a phase transition in EDN at this temperature. Electrical conductivity parameters have been evaluated and possible conduction mechanisms are discussed. The role of protons in electrical trasport phenomenon is established by chemical analysis.
Harilal, S S; Bindhu, C V; Issac, Riju C; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, September 1, 1997)
[+]
[-]
Abstract:
Plasma generated by fundamental radiation from a Nd:YAG laser focused onto a graphite target is studied spectroscopically. Measured line profiles of several ionic species were used to infer electron temperature and density at several sections located in front of the target surface. Line intensities of successive ionization states of carbon were used for electron temperature calculations. Stark broadened profiles of singly ionized species have been utilized for electron density measurements. Electron density as well as electron temperature were studied as functions of laser irradiance and time elapsed after the incidence of laser pulse. The validity of the assumption of local thermodynamic equilibrium is discussed in light of the results obtained.
Harilal, S S; Issac, Riju C; Bindhu, C V; Nampoori, V P N; Vallabhan, C P G(American Institute of Physics, April , 1997)
[+]
[-]
Abstract:
The emission features of laser ablated graphite plume generated in a helium ambient atmosphere have been investigated with time and space resolved plasma diagnostic technique. Time resolved optical emission spectroscopy is employed to reveal the velocity distribution of different species ejected during ablation. At lower values of laser fluences only a slowly propagating component of C2 is seen. At high fluences emission from C2 shows a twin peak distribution in time. The formation of an emission peak with diminished time delay giving an energetic peak at higher laser fluences is attributed to many body recombination. It is also observed that these double peaks get modified into triple peak time of flight distribution at distances greater than 16 mm from the target. The occurrence of multiple peaks in the C2 emission is mainly due to the delays caused from the different formation mechanism of C2 species. The velocity distribution of the faster peak exhibits an oscillating character with distance from the target surface.
Vallabhan, C P G; Thomas, J; Pillai, V N S; Nampoori, V P N(Springer, 1999)
[+]
[-]
Abstract:
The electrical conductivity and thermal diffusivity of pristine and iodine doped vanadyl naphthalocyanine (VONc) were studied. In the pristine sample, the temperature dependence was very weak below 300 K. The increase in conductivity at higher temperature must be due to an enhancement in carrier density with increase in thermal energy. The electrical conductivity of VONc increased when doped with iodine. The behavior of VONcI indicated that considerable changes have occurred in the electronic environment of the molecule as a result of doping. Iodine doping enhanced the thermal diffusivity of VONc. The increase in thermal diffusivity of the iodine doped sample may be due to the disorder of iodine atoms occupying the channels in one dimensional lattices.
Ravi Kumar, A V; Padmaja, G; Radhakrishnan, P; Nampoori, V P N; Vallabhan, C P G(Springer, October , 1991)
[+]
[-]
Abstract:
The acoustic signals generated in solids due to interaction with pulsed laser beam is used to determine the ablation threshold of bulk polymer samples of teflon (polytetrafluoroethylene) and nylon under the irradiation from a Q-switched Nd:YAG laser at 1.06µm wavelength. A suitably designed piezoelectric transducer is employed for the detection of photoacoustic (PA) signals generated in this process. It has been observed that an abrupt increase in the amplitude of the PA signal occurs at the ablation threshold. Also there exist distinct values for the threshold corresponding to different mechanisms operative in producing damages like surface morphology, bond breaking and melting processes at different laser energy densities.
Girijavallabhan, C P; Nampoori, V P N; Radhakrishnan, P; Thomas Lee, S; Suresh, Kumar P; Unnikrishnan, K P; Sugunan, S(INSTITUTE OF PHYSICS PUBLISHING, April 24, 2003)
[+]
[-]
Abstract:
In this communication, we discuss the details of fabricating an off-line fibre
optic sensor (FOS) based on evanescent wave absorption for detecting trace
amounts of Fe3+ in water. Two types of FOS are developed; one type uses
the unclad portion of a multimode silica fibre as the sensing region whereas
the other employs the microbent portion of a multimode plastic fibre as the
sensing region. Sensing is performed by measuring the absorption of the
evanescent wave in a reagent medium surrounding the sensing region. To
evaluate the relative merits of the two types of FOS in Fe3+ sensing, a
comparative study of the sensors is made, which reveals the superiority of
the latter in many respects, such as smaller sensing length, use of a double
detection scheme (for detecting both core and cladding modes) and higher
sensitivity of cladding mode detection at an intermediate range of
concentration along with the added advantage that plastic fibres are
inexpensive. A detection limit of 1 ppb is observed in both types of fibre and
the range of detection can be as large as 1 ppb–50 ppm. All the
measurements are carried out using a LabVIEW set-up.
Kailasnath, M; Nishant, Kumar; Nampoori, V P N; Vallabhan, C P G; Radhakrishnan, P(Elsevier, 2008)
[+]
[-]
Abstract:
Dependence of energy transfer parameters on excitation wavelength has been investigated in poly (methyl methacrylate) (PMMA) optical fibre preforms doped with C 540:Rh B dye mixture by studying the fluorescence intensity and the lifetime variations. A fluorescence spectrophotometer was used to record the excitation spectra of the samples for the emission wavelengths 495 and 580 nm. The fluorescence emission from the polymer rods was studied at four specific excitation wavelengths viz; 445, 465, 488 and 532 nm. The fluorescence lifetime of the donor molecule was experimentally measured in polymer matrix by time correlated single photon counting technique. The energy transfer rate constants and transfer efficiencies were calculated and their dependence on the acceptor concentration was analysed for three excitation wavelengths. It was found that any change in the excitation wavelength leads to significant variations in the quenching characteristics, which in turn affect the calculated energy transfer parameters.
Bindhu, C V; Harilal, S S; Nampoori, V P N; Vallabhan, C P G(Springer-Verlag, 2000)
[+]
[-]
Abstract:
Optical limiting and thermal lensing studies are
carried out in C70–toluene solutions. The measurements are
performed using 9-ns pulses generated from a frequencydoubled
Nd:YAG laser at 532 nm. Optical limiting studies in
fullerene molecules lead to the conclusion that reverse saturable
absorption is the major mechanism for limiting. Analysis
of thermal lensing measurements showed a quadratic
dependence of thermal lens signal on incident laser energy,
which also supports the view that optical limiting in C70 arises
due to sequential two-photon absorption via excited triplet
state (reverse saturable absorption).