Annieta, Philip K; Lyjo, Joseph K; Litty, Mathew Irimpan; Radhakrishnan, P; Nampoori, V P N(IOP, 2005)
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Abstract:
The photosensitivity of dye mixture-doped polymethyl methacrylate (PMMA) films are investigated as a function of laser power, concentration of the dyes, modulation frequency and the irradiation wavelength. Energy transfer from a donor molecule to an acceptor molecule affects the emission output of the dye mixture system. Photosensitivity is found to change with changes in donor–acceptor concentrations. PMMA samples doped with the dye mixture are found to be more photosensitive when the dyes are mixed in the same proportion.
Sasi Kumar, P R; Nampoori, V P N; Vallabhan, C P G(IOP, 1994)
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Abstract:
Laser-induced photoelectric and photoemission optogalvanic effects in a Ne-Nd hollow cathode discharge have been studied using a continuous wave laser source. The potential barrier for photoinduced electron emission from the cathode decreases as the applied voltage is increased. Owing to secondary electron emission in the plasma, the photocurrent is greater than that without discharge. The multiplication of secondary electrons and the quantum efficiency are also investigated.
Lyjo, Joseph K; Dayas, K R; Soniya, Damodar; Bindu, Krishnan; Krishnankutty, K; Nampoori, V P N; Radhakrishnan, P(Elsevier, December 15, 2008)
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Abstract:
The laser-induced luminescence studies of the rare earth titanates (R2Ti2O7) (R = La, Nd and Gd) using 355 nm radiation from an Nd:YAG laser are presented. These samples with submicron or nanometer size are prepared by the self-propagating high temperature synthesis (SHS) method and there is no known fluorescence shown by these rare earths in the visible region. Hence, the luminescence transitions shown by the La2Ti2O7 near 610 nm and Gd2Ti2O7 near 767 nm are quite interesting. Though La3+ ions with no 4f electrons have no electronic energy levels that can induce excitation and luminescence processes in the visible region, the presence of the Ti3+ ions leads to luminescence in this region.
Annieta, Philip K; Lyjo, Joseph K; Litty, Irimpan; Radhakrishnan, P; Nampoori, V P N(Department of Photonics, 2004)
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Abstract:
Laser induced photoacoustic (PA) technique is used in the study of photostability of polymethyl
methacrylate (PMMA) films doped with Rhodamine 6G -Rhodamine B dye system. Energy transfer from a donor
molecule to an acceptor molecule in a dye mixture affects the output of the dye system. Details of investigations on
the role of laser power, modulation frequency and the irradiation wavelength on the photosensitivity of the dye
mixture doped PMMA films are presented.
We have performed thermal diffusion measurements
of nanofluid containing gold and rhodamine 6G dye
in various ratios. At certain concentrations, gold is nearly
four times more efficient than water in dissipating small
temperature fluctuations in a medium, and therefore it will
find applications as heat transfer fluids. We have employed
dual-beam mode-matched thermal lens technique for the
present investigation. It is a sensitive technique in measuring
photothermal parameters because of the use of a lowpower,
stabilized laser source as the probe. We also present
the results of fluorescence measurements of the dye in the
nanogold environment.
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; Sajan, D George(Physical Review, American Physical Society, 2003)
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Abstract:
In this paper, we report the in-plane and cross-plane measurements of the thermal diffusivity of double
epitaxial layers of n-type GaAs doped with various concentrations of Si and a p-type Be-doped GaAs layer
grown on a GaAs substrate by the molecular beam epitaxial method, using the laser-induced nondestructive
photothermal deflection technique. The thermal diffusivity value is evaluated from the slope of the graph of the
phase of the photothermal deflection signal as a function of pump-probe offset. Analysis of the data shows that
the cross-plane thermal diffusivity is less than that of the in-plane thermal diffusivity. It is also seen that the
doping concentration has a great influence on the thermal diffusivity value. Measurement of p-type Be-doped
samples shows that the nature of the dopant also influences the effective thermal diffusivity value. The results
are interpreted in terms of a phonon-assisted heat transfer mechanism and the various scattering process
involved in the propagation of phonons
Nampoori, V P N; Radhakrishnan, P; Girijavallabhan, C P; Kumar, G A; Thomas, J; Unnikrishnan, N V; George, N(Journal of Materials Science ,Kluwer Academic Publishers, 2000)
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Abstract:
Physical and optical properties of various free base and metallic phthalocyanine (Pc) doped
glass matrix are reported for the first time. Absorption spectral measurements of H2Pc,
MnPc, NiPc, CoPc, CuPc, MoOPc, ZnPc and FePc doped borate glass matrix have been
made in the 200–1100 nm region and the spectra obtained are analyzed in the 2.1–6.2 eV
region to obtain the optical band gap (Eg) and the width of the band tail (Et). Other
important optical and physical parameters viz. refractive index (n), molar extinction
coefficient ("), density (½), glass transition temperature (Tg), molecular concentration (N ),
polaron radius (rp), intermolecular separation (R), molar refractivity (Rm) are also reported.
Bindhu, C V; Harilal, S S; Riju, C Issac; Nampoori, V P N; Vallabhan, C P G(World Scientific Puhlishing Company, 1996)
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Abstract:
Pulsed photoacoustic technique which is found to be a very convenient and accurate method, is used for the determination of absolute fluorescence quantum yield of laser dye rhodamine B. Concentration and power dependence of quantum yield of rhodamine B in methanol for excitation at 532 nm is reported here. Results show that a rapid decrease in quantum yield as the concentration is increased and finally it reaches the limit corresponding to fluorescence quenching.
Nampoori, V P N; Girijavallabhan, C P; Radhakrishnan, P; Thomas, K J; Sheeba, M(Journal of Optics A: Pure and Applied Optics, March 27, 2008)
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Abstract:
Polymethyl methacrylate (PMMA) optical fibres are fabricated by a preform drawing process.
The Raman spectra of PMMA fibres are recorded using a diode pumped solid state laser
emitting at 532 nm and a CCD-spectrograph in the 400–3800 cm−1 range. The variation of the
Raman intensity with the length of the optical fibre is studied. Investigations are carried out on
the variation of FWHM of the Raman peak at 2957 cm−1 with the length of the optical fibre and
pump power. The differential scattering cross section and gain coefficient of the Raman peak at
2957 cm−1 in PMMA are calculated in relation to that of toluene
Nampoori, V P N; Kamalasanan, M N; Patel, M M(IOP, 1975)
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Indium monofluoride was excited in a high-frequency discharge and the C-X system was photographed at a reciprocal dispersion of 0.3 AA mm-1 using a plane-grating spectrograph. Rotational analyses of the 0,0 1,0 2,2 3,3 4,4 2,4 3,5 4,6 and 5,7 bands have been carried out and the following molecular constants have been evaluated. Be'=0.2670(+or-3) cm-1, Be"=0.2628(+or-4) cm-1, alpha e'=0.0050(+or-4) cm-1, alpha e"=0.0020(+or-1) cm-1, De'=3.65(+or-5)*10-7 cm-1, De"=2.5(+or-3)*10-7 cm-1, beta e'=0.5(+or-2)*10-7 cm-1, beta e"=0.2(+or-1)*10-7 cm-1, re'=1.9672(+or-3) AA, re"=1.9853(+or-2) AA. The re" value agrees with the microwave absorption value 1.9854 AA.
Bindu, Krishnan; Nampoori, V P N(Indian Academy of Sciences, June , 2005)
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Nanosized ZnO was prepared by polyol synthesis. Fluorescence spectrum of the ZnO colloid at varying pump intensities was studied. The powder was extracted and characterized by XRD and BET. The extracted powder was screen printed on glass substrates using ethyl cellulose as binder and turpinol as solvent. Coherent back scattering studies were performed on the screen printed sample which showed evidence of weak localization. The screen printed pattern showed strong UV emission.
Nithyaja, Balan; Misha, Hari; Nampoori, Vadakkedathu P N(Optical Society of America, July 1, 2009)
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A solid-state laser based on a dye-doped deoxyribonucleic acid (DNA) matrix is described. A thin solid film of DNA has been fabricated by treating with polyvinyl alcohol (PVA) and used as a host for the laser dye Rhodamine 6G. The edge emitted spectrum clearly indicated the existence of laser modes and amplified spontaneous emission. Lasing was obtained by pumping with a frequency-doubled Nd:YAG laser at 532 nm. For a pump energy of 10 mJ/pulse, an intense line with FWHM ≈0.2 nm was observed at 566 nm due to selective mode excitation.
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; Thomas Lee, S; Jose, Gin; Unnikrishnan, N V(Journal of Optics A: Pure and Applied Optics, July 12, 2001)
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Abstract:
The fabrication and characterization of a fibre optic pH sensor based on
evanescent wave absorption is presented. The unclad portion of a
multi-mode optical fibre is coated with a pH sensitive dye, which is
immobilized by the sol–gel route. The sensitivity of the device has been
found to increase when multiple sol–gel coatings are used as the sensing
region. The dynamic range and the temporal response of the sensor are
investigated for two different dyes, namely bromocresol purple and
bromocresol green. The performance of the device is evaluated in terms of
the results obtained during actual measurements.
Indic, P; Pratap, R; Nampoori, V P N; Pradhan, N(International Journal of Neuroscience, 1999)
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Abstract:
We propose to show in this paper, that the time series obtained from biological systems such as human brain are invariably nonstationary because of different time scales involved in the dynamical process. This makes the invariant parameters time dependent. We made a global analysis of the EEG data obtained from the eight locations on the skull space and studied simultaneously the dynamical characteristics from various parts of the brain. We have proved that the dynamical parameters are sensitive to the time scales and hence in the study of brain one must identify all relevant time scales involved in the process to get an insight in the working of brain.
Santhi, A; Vinu V, Namboodiri; Radhakrishnan, P; Nampoori, V P N(American Institute of Physics, 2006)
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Abstract:
The authors apply the theory of photothermal lens formation and also that of pure optical nonlinearity to account for the phase modulation in a beam as it traverses a nonlinear medium. It is used to simultaneously determine the nonlinear optical refraction and the thermo-optic coefficient. They demonstrate this technique using some metal phthalocyanines dissolved in dimethyl sulfoxide, irradiated by a Q-switched Nd:YAG laser with 10 Hz repetition rate and a pulse width of 8 ns. The mechanism for reverse saturable absorption in these materials is also discussed.
Litty, Irimpan; Nampoori, V P N; Radhakrishnan, P; Bindu, Krishnan; Deepthy, A(American Institute of Physics, 2008)
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We have investigated the third-order nonlinearity in ZnO nanocolloids with particle sizes in the range 6-18 nm by the z-scan technique. The third-order optical susceptibility χ(3) increases with increasing particle size (R) within the range of our investigations. In the weak confinement regime, an R2 dependence of χ(3) is obtained for ZnO nanocolloids. The optical limiting response is also studied against particle size.
Litty, Irimpan; Nampoori, V P N; Radhakrishnan, P; Deepthy, A; Bindu, Krishnan(American Institute of Physics, 2007)
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Abstract:
In this article we present size dependent spectroscopic observations of nanocolloids of ZnO. ZnO is reported to show two emission bands, an ultraviolet (UV) emission band and another in the green region. Apart from the known band gap 380 nm and impurity 530 nm emissions, we have found some peculiar features in the fluorescence spectra that are consistent with the nanoparticle size distribution. Results show that additional emissions at 420 and 490 nm are developed with particle size. The origin of the visible band emission is discussed. The mechanism of the luminescence suggests that UV luminescence of ZnO colloid is related to the transition from conduction band edge to valence band, and visible luminescence is caused by the transition from deep donor level to valence band due to oxygen vacancies and by the transition from conduction band to deep acceptor level due to impurities and defect states. A correlation analysis between the particle size and spectroscopic observations is also discussed.
Harilal, S S; Riju, C Issac; Bindhu, C V; Geetha K, Varier; Nampoori, V P N; Vallabhan, C P G(Pramana, February , 1996)
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Abstract:
Analysis of the emission bands of the CN molecules in the plasma generated from
a graphite target irradiated with 1-06/~m radiation pulses from a Q-switched Nd:YAG laser has
been done. Depending on the position of the sampled volume of the plasma plume, the intensity
distribution in the emission spectra is found to change drastically. The vibrational temperature
and population distribution in the different vibrational levels have been studied as function of
distance from the target for different time delays with respect to the incidence of the laser pulse.
The translational temperature calculated from time of flight is found to be higher than the
observed vibrational temperature for CN molecules and the reason for this is explained.
Litty, Irimpan; Nampoori, V P N; Radhakrishnan, P(Elsevier, 2008)
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In this Letter we present the spectral and nonlinear optical properties of ZnO–Ag nanocomposites prepared by colloidal chemical synthesis. Obvious enhancement of ultraviolet (UV) emission of the samples is observed and the strongest UV emission is over three times than that of pure ZnO. These nanocomposites show self-defocusing nonlinearity and good nonlinear absorption behaviour which increases with increasing Ag volume fraction. The observed nonlinear absorption is explained through two photon absorption followed by free carrier absorption. ZnO–Ag is a potential nanocomposite material for the UV light emission and for the development of nonlinear optical devices with a relatively small limiting threshold.
V P N Nampoori; Litty, Irimpan; Radhakrishnan, P(Journal of Applied Physics, American Institute of Physics,, 2008)
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In this article, we present the spectral and nonlinear optical properties of ZnO–CdS nanocomposites
prepared by colloidal chemical synthesis. The optical band gap (Eg) of the material is tunable
between 2.62 and 3.84 eV. The emission peaks of ZnO–CdS nanocomposites change from 385 to
520 nm almost in proportion to changes in Eg. It is possible to obtain a desired luminescence color
from UV to green by simply adjusting the composition. The nonlinear optical response of these
samples is studied by using nanosecond laser pulses from a tunable laser at the excitonic resonance
and off-resonance wavelengths. The nonlinear response is wavelength dependent, and switching
from saturable absorption (SA) to reverse SA (RSA) has been observed for samples as the excitation
wavelength changes from the excitonic resonance to off-resonance wavelengths. Such a changeover
in the sign of the nonlinearity of ZnO–CdS nanocomposites is related to the interplay of exciton
bleach and optical limiting mechanisms. The ZnO–CdS nanocomposites show self-defocusing
nonlinearity and good nonlinear absorption behavior at off-resonant wavelengths. The nonlinear
refractive index and the nonlinear absorption increase with increasing CdS volume fraction at 532
nm. The observed nonlinear absorption is attributed to two photon absorption followed by weak free
carrier absorption. The enhancement of the third-order nonlinearity in the composites can be
attributed to the concentration of exciton oscillator strength. This study is important in identifying
the spectral range and composition over which the nonlinear material acts as a RSA based optical
limiter. ZnO–CdS is a potential nanocomposite material for the tunable light emission and for the
development of nonlinear optical devices with a relatively small limiting threshold.