Radhakrishnan, P; V P N Nampoori; Girijavallabhan, C P; Nibu, A George; George, A K(Journal of Physics D : Applied Physics, October 13, 2000)
[+]
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Abstract:
We report on a laser induced photoacoustic study of the nematic-to-isotropic
transition in certain commercial nematic liquid crystal mixtures, namely BL001, BL002,
BL032 and BL035. A simple analysis of the experimental data using the
Rosencwaig–Gersho theory shows that the heat capacities of all these compounds exhibit a
sharp peak as the temperature of the sample is varied across the transition region. Also,
substantial differences in the photoacoustic signal amplitudes in nematic and isotropic phases
have been noticed for all the mixtures. The increased light scattering property of the nematic
phase may be the reason for the enhanced photoacoustic signal amplitude in this phase
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; Nibu, A George; George, A K(Journal of Physics D : Applied Physics, October 13, 2000)
[+]
[-]
Abstract:
We report on a laser induced photoacoustic study of the nematic-to-isotropic
transition in certain commercial nematic liquid crystal mixtures, namely BL001, BL002,
BL032 and BL035. A simple analysis of the experimental data using the
Rosencwaig–Gersho theory shows that the heat capacities of all these compounds exhibit a
sharp peak as the temperature of the sample is varied across the transition region. Also,
substantial differences in the photoacoustic signal amplitudes in nematic and isotropic phases
have been noticed for all the mixtures. The increased light scattering property of the nematic
phase may be the reason for the enhanced photoacoustic signal amplitude in this phase.
Girijavallabhan, C P; Radhakrishnan, P; V P N Nampoori; Nibu, A George; George, A K(Journal of Physica: Condensed Matter, Institute of Physics Publishing, November 28, 2000)
[+]
[-]
Abstract:
The thermal effusivity values in the isotropic phase of certain comb-shaped
polymers have been evaluated for the first time using an open photoacoustic
cell configuration. The compounds investigated have siloxane and acrylate
backbone and they carry mesogenic groups in their side chain. The results
indicate that the polymer chain length as well as the side chain length have
pronounced influence on the thermal effusivity values in liquid crystalline
polymers.
Radhakrishnan, P; V P N Nampoori; Girijavallabhan, C P; Nibu, A George; George, A K(Journal of Physica: Condensed Matter, Institute of Physics Publishing, November 28, 2000)
[+]
[-]
Abstract:
The thermal effusivity values in the isotropic phase of certain comb-shaped
polymers have been evaluated for the first time using an open photoacoustic
cell configuration. The compounds investigated have siloxane and acrylate
backbone and they carry mesogenic groups in their side chain. The results
indicate that the polymer chain length as well as the side chain length have
pronounced influence on the thermal effusivity values in liquid crystalline
polymers
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; Nibu, A George; George, A K(Journal of Physica: Condensed Matter, Institute of Physics Publishing, November 28, 2000)
[+]
[-]
Abstract:
The thermal effusivity values in the isotropic phase of certain comb-shaped
polymers have been evaluated for the first time using an open photoacoustic
cell configuration. The compounds investigated have siloxane and acrylate
backbone and they carry mesogenic groups in their side chain. The results
indicate that the polymer chain length as well as the side chain length have
pronounced influence on the thermal effusivity values in liquid crystalline
polymers
Girijavallabhan, C P; Radhakrishnan, P; V P N Nampoori; George, N A; Paul, T; Sebastian, M T(Journal of Materials Science Letters,Kluwer Academic Publishers, 2000)
Radhakrishnan, P; V P N Nampoori; Girijavallabhan, C P; George, N A; Paul, T; Sebastian, M T(Journal of Materials Science Letters,Kluwer Academic Publishers, 2000)
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; George, N A; Paul, T; Sebastian, M T(Journal of Materials Science Letters,Kluwer Academic Publishers, 2000)
Girijavallabhan, C P; Radhakrishnan, P; V P N Nampoori; Kumar, G A; Thomas, J; Unnikrishnan, N V; George, N(Journal of Materials Science ,Kluwer Academic Publishers, 2000)
[+]
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Abstract:
Physical and optical properties of various free base and metallic phthalocyanine (Pc) doped
glass matrix are reported for the first time. Absorption spectral measurements of H2Pc,
MnPc, NiPc, CoPc, CuPc, MoOPc, ZnPc and FePc doped borate glass matrix have been
made in the 200–1100 nm region and the spectra obtained are analyzed in the 2.1–6.2 eV
region to obtain the optical band gap (Eg) and the width of the band tail (Et). Other
important optical and physical parameters viz. refractive index (n), molar extinction
coefficient ("), density (½), glass transition temperature (Tg), molecular concentration (N ),
polaron radius (rp), intermolecular separation (R), molar refractivity (Rm) are also reported
Radhakrishnan, P; V P N Nampoori; Girijavallabhan, C P; Kumar, G A; Thomas, J; Unnikrishnan, N V; George, N(Journal of Materials Science ,Kluwer Academic Publishers, 2000)
[+]
[-]
Abstract:
Physical and optical properties of various free base and metallic phthalocyanine (Pc) doped
glass matrix are reported for the first time. Absorption spectral measurements of H2Pc,
MnPc, NiPc, CoPc, CuPc, MoOPc, ZnPc and FePc doped borate glass matrix have been
made in the 200–1100 nm region and the spectra obtained are analyzed in the 2.1–6.2 eV
region to obtain the optical band gap (Eg) and the width of the band tail (Et). Other
important optical and physical parameters viz. refractive index (n), molar extinction
coefficient ("), density (½), glass transition temperature (Tg), molecular concentration (N ),
polaron radius (rp), intermolecular separation (R), molar refractivity (Rm) are also reported.