Unnikrishnan, K P; Jayan, Thomas; V P N Nampoori; Vallabhan, C P G(Elsevier, June , 2002)
[+]
[-]
Abstract:
Here we report measurements of third-order susceptibility χ(3), figure of merit F defined as χ(3)/α (where α is the absorption coefficient) and second hyperpolarizability 〈γ〉 of some metal substituted phthalocyanines and a naphthalocyanine in solutions of dimethyl formamide using degenerate four wave mixing at 532 nm under nanosecond excitation. It was found that among samples investigated, bis-naphthalocyanine possessed the highest value of 〈γ〉 followed by the bis-phthalocyanine. This observation is explained on the basis that bis-naphthalocyanine followed by bis-phthalocyanine has higher degree of π electron conjugation.
Achamma, Kurian; Unnikrishnan, K P; Thomas Lee, S; V P N Nampoori; Vallabhan, C P G(Taylor & Francis, 2002)
[+]
[-]
Abstract:
A sensitive method based on the principle of photothermal phenomena to realize optical
logic gates is presented. A dual beam thermal lens method using low power cw lasers in a
dye-doped polymer can be very effectively used as an alternate technique to perform the
logical function such as NAND, AND and OR.
Nibu A, George; Vallabhan, C P G; Nampoori, V P N; Radhakrishnan, P(Society of Photo-Optical Instrumentation Engineers, January , 2002)
[+]
[-]
Abstract:
We discuss an open photoacoustic cell study on sulfer-doped
n-type InP wafer. The thermal diffusivity of the sample is evaluated from
the phase data associated with the photoacoustic signal as a function of
the modulation frequency under heat transmission configuration. Analysis
is made on the basis of the Rosencwaig-Gersho theory and the results
are compared with those from earlier reported photoacoustic studies
of semiconductors. Our investigation clearly indicates that the
instantaneous thermalization process is the major heat diffusion mechanism
responsible for the photoacoustic signal generation in an InP
sample.
Suresh Kumar, P; Thomas Lee, S; Vallabhan, C P G; Nampoori, V P N; Radhakrishnan, P(Elsevier, 2002)
[+]
[-]
Abstract:
The design and development of a cost-effective, simple, sensitive and portable LED based fiber optic evanescent wave sensor for simultaneously detecting trace amounts of chromium and nitrite in water are presented. In order to obtain the desired performance, the middle portions of two multimode plastic clad silica fibers are unclad and are used as the sensing elements in the two arms of the sensor. Each of the sensor arms is sourced by separate super bright green LEDs, which are modulated in a time-sharing manner and a single photo detector is employed for detecting these light signals. The performance and characteristics of this system clearly establish the usefulness of the technique for detecting very low concentrations of the dissolved contaminants.
Girijavallabhan, C P; Radhakrishnan, P; V P N Nampoori; Sivsankara Pillai, V N; Suresh Kumar, P(Journal of Optics A : Pure and Applied Optics, March 8, 2002)
[+]
[-]
Abstract:
A fibre optic technique for detecting trace amounts of nitrite compounds in
water is described. The off-line fibre optic sensor outlined here is based on
evanescent field absorption in a test solution formed by the reaction of nitrite
compounds in water with suitable chemical reagents. A short unclad portion
of a plastic clad silica fibre acts as the sensing region. The experimental
results clearly establish the usefulness of the present technique for detecting
very low concentrations of the order of 1 ppb (parts per billion) of nitrite
compounds with a large dynamic range of 1–1000 ppb. Such a high
sensitivity enables the present device to be used for measuring the nitrite
content in drinking water.
V P N Nampoori; Radhakrishnan, P; Girijavallabhan, C P; Sivsankara Pillai, V N; Suresh Kumar, P(Journal of Optics : A Pure and Applied Optics, March 8, 2002)
[+]
[-]
Abstract:
A fibre optic technique for detecting trace amounts of nitrite compounds in
water is described. The off-line fibre optic sensor outlined here is based on
evanescent field absorption in a test solution formed by the reaction of nitrite
compounds in water with suitable chemical reagents. A short unclad portion
of a plastic clad silica fibre acts as the sensing region. The experimental
results clearly establish the usefulness of the present technique for detecting
very low concentrations of the order of 1 ppb (parts per billion) of nitrite
compounds with a large dynamic range of 1–1000 ppb. Such a high
sensitivity enables the present device to be used for measuring the nitrite
content in drinking water.
Radhakrishnan, P; Girijavallabhan, C P; V P N Nampoori; Sivsankara Pillai, V N; Suresh Kumar, P(Journal of Optics : A Pure and Applied Optics, March 8, 2002)
[+]
[-]
Abstract:
A fibre optic technique for detecting trace amounts of nitrite compounds in
water is described. The off-line fibre optic sensor outlined here is based on
evanescent field absorption in a test solution formed by the reaction of nitrite
compounds in water with suitable chemical reagents. A short unclad portion
of a plastic clad silica fibre acts as the sensing region. The experimental
results clearly establish the usefulness of the present technique for detecting
very low concentrations of the order of 1 ppb (parts per billion) of nitrite
compounds with a large dynamic range of 1–1000 ppb. Such a high
sensitivity enables the present device to be used for measuring the nitrite
content in drinking water.
Kumar, G A; Vinoy, Thomas; Gin, Jose; Unnikrishnan, N V; Nampoori, V P N(Elsevier, 2002)
[+]
[-]
Abstract:
Optical properties of free and substituted porphyrins (PP) doped borate glass matrix are reported for the first time. Absorption spectral measurements of H2TPP, CdTPP, MgTPP and ZnTPP doped borate glass matrix have been made in the 200–1100 nm region and the spectra obtained are analyzed to obtain the optical bandgap (Eg) and other important spectral parameters viz. oscillator strength (f), molar extinction coefficient (ε), electric dipole strength (q2), absorption cross-section (σa) and molecular concentration (N). Intense fluorescence was observed in the region 668–685 nm for CdTPP, ZnTPP and MgTPP doped matrices, whereas no such fluorescence was observed in H2TPP doped matrix. Fluorescence intensity was observed to be almost similar in all the metallated porphyrine matrices. Fluorescence bandwidth (Δλ), decay time (τ), stimulated emission cross-section (σ) and optical gain (G) of the principal fluorescence transitions corresponding to the Q-band excitation were also evaluated and discussed.
Achamma, Kurian; Nibu A, George; Binoy, Paul; Nampoori, V P N; Vallabhan, C P G(Taylor & Francis, 2002)
[+]
[-]
Abstract:
In this paper we report the use of the dual beam thermal lens technique as a quantitative
method to determine absolute fluorescence quantum efficiency and concentration
quenching of fluorescence emission from rhodamine 6G doped Poly(methyl
methacrylate) (PMMA), prepared with different concentrations of the dye. A
comparison of the present data with that reported in the literature indicates that the
observed variation of fluorescence quantum yield with respect to the dye
concentration follows a similar profile as in the earlier reported observations on
rhodamine 6G in solution. The photodegradation of the dye molecules under cw laser
excitation is also studied using the present method.
Sajan D, George; Vallabhan, C P G; Heck, M; Radhakrishnan, P; Nampoori, V P N(Taylor & Francis, 2002)
[+]
[-]
Abstract:
An open cell photoacoustic (PA) configuration has been employed to evaluate the thermal diffusivity of intrinsic InP as well as InP doped with tin and iron. Thermal diffusivity data have been evaluated from variation of phase of PA signal as a function of modulation frequency. In doped samples, we observe a reduced value for thermal diffusivity in comparison with intrinsic InP. We also observed that, while the phase of the PA signal varies linearly with the square root of chopping frequency for doped samples, the intrinsic material does not exhibit such behaviour in the experimental frequency range. These results have been interpreted in terms of the heat generation and phonon assisted heat diffusion mechanisms in semiconductors.