Self-assembled Transition Metal Coordination Frameworks of Carbohydrazone and Thiocarbohydrazone Ligands: Structural, Spectral, Magnetic and Anticancer Properties

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Self-assembled Transition Metal Coordination Frameworks of Carbohydrazone and Thiocarbohydrazone Ligands: Structural, Spectral, Magnetic and Anticancer Properties

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dc.contributor.author Manoj, E
dc.contributor.author Dr. Prathapachandra Kurup, M.R
dc.date.accessioned 2012-10-03T05:44:29Z
dc.date.available 2012-10-03T05:44:29Z
dc.date.issued 2007-10
dc.identifier.uri http://dyuthi.cusat.ac.in/purl/3016
dc.description.abstract Chemistry occupies a unique middle position in the scientific arena, between physics and mathematics on the one side and biology, ecology, sociology and economics on the other [1]. Chemistry is the science of matter and of its transformations, and life is its highest expression [2]. According to reductionist thinking biology is reducible into chemistry, chemistry into physics, and ultimately physics into mathematics. Reductionism implies the ease of understanding one level in terms of another.The work presented this thesis comprises synthesis and characterization of suitably substituted thiocarbohydrazone and carbohydrazone ligand building blocks, self-assembled metallosupramolecular square grid complexes as well as some di/multinuclear complexes. The primary aim was the deliberate syntheses of some novel transition metal framework complexes, mainly metallosupramolecular coordination square grids by self-assembly and their physico-chemical characterization. The work presented, however, also include synthesis and characterization of four mononuclear Ni(II) complexes of two thiosemicarbazones, which we carried out as a preliminary and supporting study. Based on the present work we would like to conclude that the carbohydrazones, thiocarbohydrazones and their coordination framework complexes of transition metals are promising systems for wide application in science and technology varied from physics to biotechnology. Novel classes of materials and biologically important potential compounds open up further scope of researches and we hopefully welcome any sort of related research to make this work more valuable. en_US
dc.language.iso en en_US
dc.publisher Cochin University of Science and Technology en_US
dc.subject Carbohydrazones en_US
dc.subject Thiocarbohydrazones en_US
dc.subject Metallosupramolecular squares en_US
dc.subject Anticancer drugs en_US
dc.subject NMR spectra en_US
dc.subject Electronic spectra en_US
dc.subject X-ray crystallography en_US
dc.subject MALDI MS spectrometry en_US
dc.subject EPR spectroscopy en_US
dc.subject Magnetochemistry en_US
dc.subject Crystal structure of H213 en_US
dc.subject MALDI MS spectral features en_US
dc.subject Crystal structure of HZL4 en_US
dc.subject EPR spectral studies en_US
dc.title Self-assembled Transition Metal Coordination Frameworks of Carbohydrazone and Thiocarbohydrazone Ligands: Structural, Spectral, Magnetic and Anticancer Properties en_US
dc.type Thesis en_US


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