Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex

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Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex

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dc.contributor.author Rapheal, P F
dc.contributor.author Manoj, E
dc.contributor.author Prathapachandra Kurup, M R
dc.date.accessioned 2011-03-15T05:49:08Z
dc.date.available 2011-03-15T05:49:08Z
dc.date.issued 2007
dc.identifier.issn 0277-5387
dc.identifier.other Polyhedron 26 (2007) 818–828
dc.identifier.uri http://dyuthi.cusat.ac.in/xmlui/purl/2099
dc.description.abstract Ten copper(II) complexes {[CuL1Cl] (1), [CuL1NO3]2 (2), [CuL1N3]2 · 2/3H2O (3), [CuL1]2(ClO4)2 · 2H2O (4), [CuL2Cl]2 (5), [CuL2N3] (6), [Cu(HL2)SO4]2 · 4H2O (7), [Cu(HL2)2] (ClO4)2 · 1/2EtOH (8), [CuL3Cl]2 (9), [CuL3NCS] · 1/2H2O (10)} of three NNS donor thiosemicarbazone ligands {pyridine-2-carbaldehyde-N(4)-p-methoxyphenyl thiosemicarbazone [HL1], pyridine-2-carbaldehyde-N(4)-2-phenethyl thiosemicarbazone [HL2] and pyridine-2-carbaldehyde N(4)-(methyl), N(4)-(phenyl) thiosemicarbazone [HL3]} were synthesized and physico-chemically characterized. The crystal structure of compound 9 has been determined by X-ray diffraction studies and is found that the dimer consists of two square pyramidal Cu(II) centers linked by two chlorine atoms. en_US
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.subject Crystal structure en_US
dc.subject Thiosemicarbazone en_US
dc.subject Pyridine-2-carbaldehyde en_US
dc.subject Cu(II) complex en_US
dc.title Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde: Crystal structure of a binuclear complex en_US
dc.type Working Paper en_US
dc.contributor.faculty Science en_US


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