Joyes, Jacob; Dr.Sugunan, S(Cochin University of Science and Technology, December 14, 2009)
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Abstract:
Scientists throughout the world are in search of a better methodology to reduce the use of environmentally hazardous chemicals common in industries .A significant contribution in this field is given by different redox catalysts in oxidation reactions. The oxidation of organic substrates represents one of the most important industrial chemical reactions, explaining the significant efforts invested in the research and development of new heterogeneous catalysts with increased activities and selectivities in these type reactions[l-4|. Hence liquid phase reactions like epoxidation of cylcohexene and hydroxylation of phenol were carried out with a new outlook in the challenge using CeO2/TiO;; and CuO/TiO2 catalysts denoted as TiO2-Ce as TiO2-Cu respectively in this work. Also different wt% of metals incorporated titania catalysts like 3, 6, 9 wt% CeO2/TiO; and CuO/TiO;were subjected to the present study .The interaction between metal oxides and the oxide supports have attracted much attention because of the wide applications of supported metal oxide systems[7,8]. It is well known that supported oxides of transition metals are widely used as catalysts for various reactions. Titania as well its metal modified catalysts systems afford high activity and selectivity in the liquid phase epoxidation of cyclohexene[9]. Cyclohexene epoxide is obtained as the major product during the reaction with small amounts of allylic substitution products.This chapter gives an idea about the liquid phase oxidation reactions like epoxidation of cylcohexene and hydroxylation of phenol in which many industrially important products are formed. Here discusses about the redox properties of the ceria and copper incorporated titania catalysts.The epoxidation of cyclohcxene is carried out efficiently over the prepared systems with the selective formation of cyclohexane epoxide. This reaction hints that it might be possible to create cleaner nylon chemistry. The total acidity of the prepared systems plays an important role in determining the catalytic activity in the dehydrogenation of cyclohexane and cyclohexene. The total acidity of the prepared systems plays an important role in determining the catalytic activity in the dehydrogenation of cyclohexane and cyclohexene.
Description:
Department of Applied Chemistry, Cochin University of Science and Technology