The rheological behavior of a short-polyester-fiber-filled polyurethane
elastomer composite containing different bonding agents
has been studied in the temperature range 120-160°C and in the
shear rate range 63-608 s-'. The composite with and without
bonding agents showed a pseudoplastic behavior which decreased
with the increase of temperature. Composites containing bonding
agents based on polypropyleneglycol and 4,4'-diphenylmethanediisocyanate
showed the lowest viscosity values at a particular
shear rate, whereas composites containing a glycerol- (GL) based
bonding agent showed the highest viscosity. The viscosity of the
composite decreased sharply after a particular temperature (140°C) and the fall was less drastic in the composite containing
a GL-based bonding agent.
Sunil K Narayanankutty(Elsevier Science Limited, May 17, 1997)
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Abstract:
The thermal degradation of short polyester fiber reinforced polyurethane composites
with and without different bonding agents has been studied by thermogravimetric
analysis . It was found that degradation of the polyurethane takes
place in two steps and that of the composites takes place in three steps. With
the incorporation of 30 phr of fiber in the matrix , the onset of degradation was
shifted from 230 to 238 ° C. The presence of bonding agents in the virgin elastomer
and the composite gave an improved thermal stability . Results of kinetic studies
showed that the degradation of polyurethane and the reinforced composites with
and without bonding agents follows first -order reaction kinetics
Rani, Joseph(Gordon and Breach Science Publishers S.A., October 16, 1992)
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Abstract:
Butyl (IIR) tube reclaim (RR) was mixed with carbon black filled natural rubber (NR) compounds at
various percentages. The blend containing a low percentage of RR was found to show improved ageing
resistance and improved processability with out much reduction in the mechanical properties.
Sunil K Narayanankutty(Elsevier Science Publishers Ltd., August 29, 1991)
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Abstract:
The thermal degradation of short kevlar fibre-thermoplastic polyurethane
(TPU) composites has been studied by Thermogravimetric Analysis (TGA)
and Differential Scanning Calorimetry (DSC). TGA showed that the thermal
degradation of TPU takes place in two steps with peak maxima (T1max and
T2ma,) at 383°C and 448°C, respectively. In the presence of 10-40 phr of short
kevlar fibres, T1_ and T2max were shifted to lower temperatures. The
temperature of onset of degradation was increased from 245 to 255°C at 40
parts per hundred rubber (phr) fibre loading. Kinetic studies showed that the
degradation of TPU and kevlar-TPU composite follows first-order reaction
kinetics. The DSC study showed that there is an improvement in thermal
stability of TPU in the presence of 20 phr of short kevlar fibres.
Ethylene-propylene-diene rubber (EPDM) and isobutylene-isoprene rubber (IIR) were
compounded, precured to a low degree, and then were blended with natural rubber (NR).
The compounding ingredients for NR were then added and the final curing was done. NR/
EPDM and NR/IIR blends, prepared using this method, were found to possess much
improved mechanical properties as compared to their conventional counterparts. The optimum
precuring crosslink density that has to be given to the EPDM and IIR phases has
been determined.
Rani, Joseph(OPA (Overseas Publishers Association), May 28, 1995)
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Abstract:
Amine Terminated Liquid Natural Rubber (ATNR) was used as a plasticiser in filled NR and NBR
compounds replacing oil/DOP. The scorch time and cure time were found to be lowered when ATNR
was used as the plasticiser. ATNR was found to improve the mechanical properties like tensile strength,
tear strength and modulus of the vulcanizates . The ageing resistance of the vulcanizates containing ATNR
was superior compared to the vulcanizates containing oil/DOP.
Filled compounds of natural rubber, isobutylene-isoprene rubber
and styrene-butadiene rubber compounds were extruded through a laboratory
extruder by varying the feeding rate at different temperatures and revolutions
per minute. The extruded compounds were vulcanized up to their optimum cure
times and the mechanical properties of the vulcanizates were determined. The
properties suggest that there is a particular feeding rate in the starved fed region
which results in maximum mechanical properties. The study shows that running
the extruder at a slightly starved condition is an attractive means of improving
the physical properties.
Design and development of a new feed -horn antenna
with low sidelobe levels is reported . The E-walls of this
antenna are fabricated with low -loss dielectric substrate ,
periodicallyloaded with thin conducting strips . The antenna
is found to be simulating the radiation characteristics of metallic
Corrugated horns . This can be an ideal substitute for metallic
Corrugated horns with added advantages like light -weight and low
production cost
Jackson,James; Paulose,C S(Department of Biotechnology, November 19, 1998)
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Abstract:
5-Hydroxytryptamine2A (5-HT2A) receptor kinetics was studied in cerebral cortex and brain stem of streptozotocin (STZ) induced
diabetic rats. Scatchard analysis with [3H] (±) 2,3dimethoxyphenyl-l-[2-(4-piperidine)-methanol] ([3H]MDL100907) in cerebral
cortex showed no significant change in maximal binding (Bmax) in diabetic rats compared to controls. Dissociation constant
(K) of diabetic rats showed a significant decrease (p < 0.05) in cerebral cortex, which was reversed to normal by insulin treatment.
Competition studies of [3H]MDL100907 binding in cerebral cortex with ketanserin showed the appearance of an additional
low affinity site for 5-HT2A receptors in diabetic state, which was reversed to control pattern by insulin treatment. In brain stem,
scatchard analysis showed a significant increase (p < 0.05) in Bmax accompanied by a significant increase (p < 0.05) in Kd.
Competition analysis in brain stem also showed a shift in affinity towards a low affinity State for 5-HT2A receptors. All these
parameters were reversed to control level by insulin treatment. These results show that in cerebral cortex there is an increase
in affinity of 5-HT2A receptors without any change in its number and in the case of brain stem there is an increase in number of
5HT2A receptors accompanied by a decrease in its affinity during diabetes. Thus, from the results we suggest that the increase
in affinity of 5-HT2A receptors in cerebral cortex and upregulation of 5-HT2A receptors in brain stem may lead to altered neuronal
function in diabetes.