Now showing items 1-8 of 8
| Abstract: | Earlier studies5773 in our laboratory showed that when a nucleophile is used along with disulphide or sulphenamide accelerators the vulcanization is accelerated greatly and the reaction mechanism is generally nucleophilic in nature. However it was observed that it also changes with the systems under review. The present study, deals with the use of unsubstituted amidino thiourea i.e. aminoimino methyl thiourea(AMT) V in the vulcanization studies of different elastorners and their blends. One of the aims of this study was to get further proof with regard to the theory of nucleophilic reaction mechanism in such binary systems.Mixes containing thiourea are used as controls. AMT is more nucleophilic than TU and this is clear from the fact that the fonner can condense with isothiocynate even in the absence of alkali while TU cannot". Also the guanidinyl group in AMT can facilitate the polarization of the C=S bond favouring a nucleophilic reaction |
| Description: | Department Of Polymer Science And Rubber Technology Cochin University Of Science And Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/4700 |
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| Dyuthi-T1831.pdf | (2.103Mb) |
| Abstract: | Petroleum, a mixture of organic compounds, comes from underground rock formations ranging in age from ten to several hundred million years. The process by which it is formed and developed is not yet completely known. Studies indicate that petroleum is formed mainly from microscopic-sized marine animals and plants. When these organisms died in water of low oxygen content, they did not decompose. Thus their remains sank to the bottom to be buried under accumulations of sediment. Their conversion to petroleum remains a subject of research even today. |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/3480 |
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| Dyuthi-T1446.pdf | (1.988Mb) |
| Abstract: | Studies on the chemistry of vulcanization” play a central role in the efforts to achieve better product performance from natural and synthetic rubbers. They provide rubber technologists with an increasingly realistic picture of molecular framework of vulcanizates, from which relation between physical properties and chemical constitution may be deduced. Moreover, these studies are also aimed at the understanding of the vulcanization process, in sufficiently advanced chemical mechanistic terms, so that the effect of changes on vulcanizate structure can rationally be predicted.“ The study of accelerator activity ofthe binary system containing ATU with TMTD, and with MBTS in sulphur vulcanization of dry natural rubber using standard procedures for compounding and vulcanization is described in the third chapter. The study of the gum vulcanizates form part I of this chapter The behaviour of the experimental mixes were compared with those of the controls containing thiourea; diphenyl guanidine |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/3460 |
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| Dyuthi-T1438.pdf | (2.142Mb) |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/2200 |
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| Dyuthi-T0556.pdf | (6.323Mb) |
| Abstract: | In the first part of the study we probed the effectiveness of rice bran oil as a multipurpose compounding ingredient for nitrile (NBR) and chloroprene (CR) rubbers. This oil has already been successfully employed in the compounding of NR and SBR in this laboratory.In this context we thought it worthwhile to try this oil in the polar rubbers viz, NBR and CR also. The principle of like dissolves like as applicable to solvents is equally applicable while selecting a plasticiser, elastomer combination. Because of the compatibility considerations polar plasticisers are preferred for polar rubbers like NBR and CR. Although plasticisation is a physical phenomenon and no chemical reaction is involved, the chemical structure of plasticisers determines how much physical attraction there is between the rubber and the plasticiser. In this context it is interesting to note that the various fatty acids present in rice bran oil have a long paraffinic chain, characteristic of waxes, with an acid group at the end of the molecule. The paraffinic end of the molecule contributes lubricating effects and limits compatibility whereas the acid end group contributes some polarity and is also chemically reactive. Because of absorption of acid group on the surface of pigments, these acids will have active pigment wetting characteristics also. These factors justifies the role of rice bran oil as a co-activator and lubricating agent for NBR and CR. In fact in our study we successfully replaced stearic acid as co-activator and aromatic oillDOP as processing aid for CR and NBR with rice bran oil.This part of the study has got special significance in the fact that rubber industry now heavily depends on petroleum industry for process oils. The conventional process oils like aromatic, naphthenic and paraffinic oils are increasingly becoming costlier, as its resources in nature are fast depleting. Moreover aromatic process oils are reported to be carcinogenic because of the presence of higher levels of polycyclic aromatic compounds in these oils.As a result of these factors, a great amount research is going on world over for newer processing aids which are cost effective, nontoxic and performanance wise at par with the conventional ones used in the rubber industry. Trials with vegetable oils in this direction is worth trying.Antioxidants are usually added to the rubber compound to minimise ageing effects from heat, light, oxygen etc. As rice bran oil contains significant amount of tocopherols and oryzanol which are natural antioxidants, we replaced a phenolic antioxidant like styrenated phenol (SP) from the compound recipe of both the rubbers with RBO and ascertained whether this oil could function in the role of antioxidant as well.Preparation and use of epoxidised rice bran oil as plasticiser has already been reported.The crude rice bran oil having an iodine value of 92 was epoxidised in this laboratory using peracetic acid in presence of sulphuric acid as catalyst. The epoxy content of the epoxidised oil was determined volumetrically by treating a known weight of the oil with excess HCI and back titrating the residual HCI with standard alkali solution. The epoxidised oil having an epoxy content of 3.4% was tried in the compounding of NBR and CR as processing aids. And results of these investigations are also included in this chapter. In the second part of the study we tried how RBO/ERBO could perform when used as a processing aid in place of aromatic oil in the compounding of black filled NRCR blends. Elastomers cannot have all the properties required for a particular applications, so it is common practice in rubber industry to blend two elastomers to have desired property for the resulting blend.In this RBO/ERBO was tried as a processing aid for plasticisation, dispersion of fillers, and vulcanisation of black filled NR-CR blends.Aromatic oil was used as a control. The results of our study indicate that these oils could function as a processing aid and when added together with carbon black function as a cure accelerator also.PVC is compatible with nitrile rubber in all proportions, provided NBR has an acrylonitrile content of 25 to 40%. Lower or higher ACN content in NBR makes it incompatible with PVC.PVC is usually blended with NBR at high temperatures. In order to reduce torque during mixing, additional amounts of plasticisers like DOP are added. The plasticiser should be compatible both with PVC and NBR so as to get a homogeneous blend. Epoxidised soyaben oil is reported to have been used in the compounding of PVC as it can perfonn both as an efficient plasticiser and heat stabilizer.At present DOP constitute the largest consumed plasticiser in the PVC compounding. The migration of this plasticiser from food packaging materials made of PVC poses great health hazards as this is harmful to human body. In such a scenario we also thought it worthwhile to see whether DOP could be replaced by rice bran oil in the compounding of NBR-PVC blends Different blends of NBR-PVC were prepared with RBO and were vulcanized using sulphur and conventional accelerators. The various physical and mechanical properties of the vulcanisates were evaluated and compared with those prepared with DOP as the control plasticiser. Epoxidised rice bran oil was also tried as plasticiser for the preparation of NBR-PVC blends. A comparison of the processability and cure characteristics of the different blends prepared with DOP and ERBO showed that ERBO based blends have better processability and lower cure time values. However the elastographic maximum torque values are higher for the DOP based blends. Almost all of the physical properties evaluated are found to be slightly better for the DOP based blends over the ERBO based ones. However a notable feature of the ERBO based blends is the better percentage retention of elongation at break values after ageing over the DOP based blends. The results of these studies using rice bran oil and its epoxidised variety indicated that they could be used as efficient plasticisers in place of DOP and justifies their role as novel, nontoxic, and cheap plasticisers for NBR-PVC blends. |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/2648 |
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| Dyuthi-T0708.pdf | (9.727Mb) |
| Abstract: | In the present work, studies on vulcanization, rheology and reinforcement of natural rubber latex with special reference to accelerator combinations, surface active agents and gamma irradiation have been undertaken. In vulcanization, the choice of vulcanization system, the extent and mc-zie of vulcanization and network structure of the vulcanizate are important factors contributing to the overall quality of the product. The vulcanization system may be conventional type using elemental sulfur or a system involving sulfur donors. The latter type is used mainly in the manufacture of heat resistant products. For improving the technical properties of the products such as modulus and tensile strength, different accelerator combinations are used. It is known that accelerators have a strong effect on the physical properties of rubber vulcanizates. A perusal of the literature indicates that fundamental studies on the above aspects of latex technology are very limited. Thereforea systematic study on vulcanization, rheology and reinforcement of natural rubber latex with reference to the effect of accelerator combinations, surface active agents and gamma irradiation has been undertaken. The preparation and evaluation of some products like latex thread was also undertaken as a part of the study. The thesis consists of six chapter |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/3662 |
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| Dyuthi-T1582.pdf | (3.586Mb) |
| Abstract: | The thesis entitled Study on Accelerators in Rubber Vulcanization with Special Reference to the Binary Systems Containing Substituted Dithiobiurets. It includes a detailed study on the binary accelerator systems containing substituted dithiobiurets in natural rubber and NR latex and dithiobiurets in SBR and NR-SBR blends vulcanization systems. It deals with the experimental procedure adopted for the preparation of DTB-II and DTB-III; the procedure for compounding and vulcanization and determination of physical properties like modulus, tensile strength, elongation at break, hardness, compression set, heat build up etc. The results indicate that there is efficient acceleration activity of the dithiobiurets in the vulcanization of natural rubber latex containing TMT. The study of dithiobiurets in natural rubber and NR latex reveal that they are having definite accelerating effect in SBR vulcanization systems. |
| Description: | Department of Polymer Science and Rubber Technology Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/3252 |
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| Dyuthi-T1226.pdf | (6.157Mb) |
| Abstract: | The thesis consists of seven chapters. The first chapter is a general introduction on rice by-products, their composition and utilization at present. The different milling processes adopted in paddy and the major by-products obtained from these processes viz. rice husk, rice bran, rice bran oil and rice husk ash are described. The physical properties and chemical composition of the rice husk and its general uses are given in detail. The chemical composition of the rice bran and its separation from paddy is also included. The details of solvent extraction process used for obtaining rice bran oil and also its chemical constitution is discussed in this chapter. Also described is the preparation and the different uses of rice husk ash. A literature survey is also done on the utilization of rice by-products in rubber and plastics as on today. The scope and objectives of the present study is also included at the end of this chapter. |
| Description: | Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology |
| URI: | http://dyuthi.cusat.ac.in/purl/3462 |
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| Dyuthi-T1439.pdf | (1.974Mb) |
Now showing items 1-8 of 8
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