Sreevalsa, V G; Dr.Jayalekshmi, S(Cochin University Of Science And Technology, November , 2012)
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Abstract:
Organic crystals possess extremely large optical nonlinearity compared
to inorganic crystals. Also organic compounds have the amenability for
synthesis and scope for introducing desirable characteristics by inclusions. A
wide variety of organic materials having electron donor and acceptor groups,
generate high order of nonlinearity. In the present work, a new nonlinear optical crystal, L-citrulline oxalate (LCO) based on the aminoacid L-citrulline was grown using slow evaporation technique. Structural characterization was carried out by single crystal XRD. It crystallizes in the noncentrosymmetric, orthorhombic structure with space group P21 P21 P21. Functional groups present in the sample were identified by Fourier transform infra red (FTIR) and FT-Raman spectral analysis. On studying the FTIR and Raman spectra of the precursors L-citrulline and oxalic acid, used for growing L-citrulline oxalate crystal, it is found that the
significant peaks of the precursors are present in the spectra of the L-citrulline
oxalate crystal . This observation along with the presence of NH3
+ group in the spectra of L-citrulline oxalate, confirms the formation of the charge
transfer complex
Description:
Department of Physics, Cochin University of Science and Technology