Nandini Menon, N; Dr. Ravindranatha Menon, N(Cochin University of Science & Technology, April , 1997)
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Abstract:
The thesis deals with different aspects connected with the distribution and toxicity of PHC in crude oils in the aquatic environment and marine molluscs. Information has been gathered and presented on the present status of research in the field based on a thorough review of recent literature. It is seen from the literature that the resident time of PHC becomes lesser and lesser when crude oil is discharged in large quantities into the coastal waters where excess oxygenation light penetration, temperature availability and strong tidal currents persist. This results in the reduction of the onslaught of oil pollution. This probably shows that taxic insult of crude oil in tropical shores will be relatively lesser than that occurring in temperate and boreal waters. However, there is no record of major episodal oil pollution comparable in quantum and extent to that of Torrey Canyon or Amoco Cadiz which prevents a more reliable analysis on the issue. Considerable controversy exists on the method of estimation of PHC in seawater. However, Ultra-violet fluorescence spectroscopy has been widely recommended as an analytical tool for the determination of total hydrocarbons. Similarly representation of values as chrysene equivalents has been recognised as the most reliable method of Quantum representation.
Description:
Division of Marine Biology, Microbiology and Biochemistry, school of Marine Sciences, Cochin University of Science and Technology
Matlrew, George; Dr.Anantharaman, M R(Cochin University of Science & Technology, February , 2004)
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Abstract:
Magnetism and magnetic materials have been an ever-attractive
subject area for engineers and scientists alike because of its versatility in
finding applications in useful devices. They find applications in a host of
devices ranging from rudimentary devices like loud speakers to sophisticated
gadgets like waveguides and Magnetic Random Access Memories (MRAM).The one and only material in the realm of magnetism that has been at the
centre stage of applications is ferrites and in that spinel ferrites received the
lions share as far as practical applications are concerned.It has been the endeavour of scientists and engineers to remove
obsolescence and improve upon the existing so as to save energy and
integrate in to various other systems. This has been the hallmark of material
scientists and this has led to new materials and new technologies.In the field of ferrites too there has been considerable interest to
devise new materials based on iron oxides and other compounds. This means
synthesising ultra fine particles and tuning its properties to device new
materials. There are various preparation techniques ranging from top- down
to bottom-up approaches. This includes synthesising at molecular level, self
assembling,gas based condensation. Iow temperature eo-precipitation, solgel
process and high energy ball milling. Among these methods sol-gel
process allows good control of the properties of ceramic materials. The
advantage of this method includes processing at low temperature. mixing at
the molecular level and fabrication of novel materials for various devices.Composites are materials. which combine the good qualities of one
or more components. They can be prepared in situ or by mechanical means
by the incorporation of fine particles in appropriate matrixes. The size of the
magnetic powders as well as the nature of matrix affect the processability
and other physical properties of the final product. These plastic/rubber
magnets can in turn be useful for various applications in different devices.
In applications involving ferrites at high frequencies, it is essential that the
material possesses an appropriate dielectric permittivity and suitable
magnetic permeability. This can be achieved by synthesizing rubber ferrite
composites (RFC's). RFCs are very useful materials for microwave
absorptions. Hence the synthesis of ferrites in the nanoregirne.investigations on their size effects on the structural, magnetic, and electrical
properties and the incorporation of these ferrites into polymer matrixes
assume significance.In the present study, nano particles of NiFe204, Li(!5Fe2S04 and
Col-e-O, are prepared by sol gel method. By appropriate heat treatments,
particles of different grain sizes are obtained. The structural, magnetic and
electrical measurements are evaluated as a function of grain size and
temperature. NiFel04 prepared in the ultrafine regime are then incorporated
in nitrile rubber matrix. The incorporation was carried out according to a
specific recipe and for various loadings of magnetic fillers. The cure
characteristics, magnetic properties, electrical properties and mechanical
properties of these elastomer blends are carried out. The electrical
permittivity of all the rubber samples in the X - band are also conducted.
Description:
Department of Physics,
Cochin University of Science & Technology
Sagar, S; Dr.Anantharaman, M R(Cochin University of Science & Technology, August , 2010)
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Abstract:
This thesis lays importance in the investigation on the multiferroic and
thermooelectric properties of selected representatives of low bandwidth and
intermediate band width manganites. The first candidate, Strontium doped Gd manganite, is prepared by wet solid state reaction method and the second
candidate, Na doped La manganite, by citrate gel method. In addition to the above
mentioned properties, magneto resistance and dielectric properties are
investigated. Using dielectric spectroscopic the dispersion parameters are
correlated to the relaxation mechanisms and an attempt is made to obtain the grain
and grain boundary contribution to the impedance of the sample through
impedance spectroscopy studies.
Description:
Department of Physics,
Cochin University of Science & Technolog
Gopikrishna, M; Dr.Aanandan, C K(Cochin University of Science & Technology, July , 2010)
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Abstract:
A major challenge in the transmission of narrow pulses is the radiation characteristics
of the antenna. Designing the front ends for UWB systems pose challenges
compared to their narrow and wide band counterparts because in addition to
having electrically small size, high efficiency and band width, the antenna has
to have excellent transient response. The present work deals with the design
of four novel antenna designs- Square Monopole, Semi-Elliptic Slot, Step and
Linear Tapered slot - and an assay on their suitability in UWB Systems. Multiple
resonances in the geometry are matched to UWB by redesigning the ground-patch
interfaces. Techniques to avoid narrow band interference is proposed in the
antenna level and their effect on a nano second pulse have also been investigated.
The thesis proposes design guidelines to design the antenna on laminates of any
permittivity and the analyzes are complete with results in the frequency and time
domains.
Description:
Department of Electronics,
Cochin University of Science and Technology
Jesty, Thomas; Surender, G D; Reddy, M L P(RRL (CSIR), 2000)
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Abstract:
The thesis entitled INVESTIDGATIONS ON THE RECOVERY OF TITANIUM VANADIUM AND IRON VALUES FROM THE WASTE CHILORIDE LIQUORS OF TITANIA INDUSTRY embodies the results of the investigations carried out on the solvent extraction separation of iron (III) vanadium(V) and titanium (IV) chlorides from the waste chloride liquors of titanium minerals processing industry by employing tributylphosphate (TBT) as an extractant. The objective of this study is to generate the knowledge base to achieve the recovery of iron, vanadium and titanium cvalues from multi- metal waste chloride liquors originating from ilmenite mineral beneficiation industries through selective separation and value added material development
Rani, Pavithran; Reddy, M L P(Chemical Science Division RRL (CSIR), March , 2005)
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Abstract:
The thesis entitled “ Investigations on the solvent extraction and luminescence of lanthanoids with mixtures of heterocyclic β-diketone S and various neutral oxo-donors” embodies the results of investigations carried out on the solvent extraction of trivalent lanthanoids with various heterocyclic β-diketones in the presence and absence of neutral oxo-donors and also on the luminescent studies of Eu3+-heterocyclic β-diketonate complexes with Lewis bases. The primary objective of the present work is to generate the knowledge base, especially to understand the interactions of lanthanoid-heterocyclic β-diketonates with various macrocyclic ligands such as crown ethers and neutral organophosphorus extractants , with a view to achieve better selectivity. The secondary objective of this thesis is to develop novel lanthanoid luminescent materials based on 3-phenyl-4-aroyl-5-isoxazolones and organophosphorus ligands, for use in electroluminescent devices.
In the beginning it describes the need for the development of new mixed-ligand systems for the separation of lanthanoids and the development and importance of novel luminescent lanthanoid- β-diketonate complexes for display devices. The syntheses of various para substituted derivatives of 4-aroyl-5-isoxazolones and their characterization by various spectroscopic techniques are described. It also investigate the solvent extraction behaviour of trivalent lanthanoids with 4-aroyl-5-isoxazolones in the presence and absence of various crown ethers such as 18C6, DC18C6, DB18C6 and B18C6. Elemental analysis, IR and H NMR spectral studies are used to understand the interactions of crown ethers with 4-aroyl-5-isoxazolonate complexes of lanthanoids.
The synergistic extraction of trivalent lanthanoids with sterically hindered 1-phenyl-3-methyl-4-pivaloyl-5-pyrazolone in the presence of various structurally related crown ethers are studied. The syntheses, characterization and photyphysical properties of Eu3+-4-aroyl-5-isoxazolonate complexes in the presence of Lewis bases like trictylphosphine oxide or triphenylphosphine oxide were studied.
Paul, Miriam; Dr. Ravindranatha Menon, N(Cochin University of Science & Technology, 2001)
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Abstract:
The present investigation has addressed the effects of PHC contaminated culture medium on the morphology, physiology and behaviour of shrimps. The shrimp Metapenaeus dobsoni is an important member of the crustacean animal community abounding the oil contaminated benthic regions of Cochin backwater system. Since it is known that true pollutants can disrupt the sustainability of ecosystems by its effect on species, populations and communities,a representative species was used for the study. The results discussed in this work is bound to help in understanding the ecotoxicant resistance that the animal may display under toxic conditions compared to dynamic steady-state systems in nature.
Description:
Division of Marine Biology, Microbiology and Biochemistry, Cochin University of Science and Technology
Sumangala,R; Saseendran Pillai,P R(Cochin University OF Science and Technology, December , 1996)
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Abstract:
The main objective of carrying out this investigation is to develop suitable transducer array systems so that underwater pipeline inspection could be carried out in a much better way, a focused beam and electronic steering can reduce inspection time as well. Better results are obtained by optimizing the array parameters. The spacing between the elements is assumed to be half the wavelength so that the interelement interaction is minimum. For NDT applications these arrays are operated at MHz range. The wavelengths become very small in these frequency ranges. Then the size of the array elements becomes very small, requiring hybrid construction techniques for their fabrication. Transducer elements have been fabricated using PVDF as the active, mild steel as the backing and conducting silver preparation as the bonding materials. The transducer is operated in the (3,3) mode. The construction of a high frequency array is comparatively complicated. The interelement spacing between the transducer elements becomes considerably small when high frequencies are considered. It becomes very difficult to construct the transducer manually. The electrode connections to the elements can produce significant loading effect. The array has to be fabricated using hybrid construction techniques. The active materials has to be deposited on a proper substrate and etching techniques are required to fabricate the array. The annular ring, annular cylindrical or other similar structural forms of arrays may also find applications in the near future in treatments were curved contours of the human body are affected.
The present study is an attempt to find out the ralation between RNA/DNA ratio, protein,percentage growth rate and specific growth rate of prawn,Penaeus indicus with respect to Nervous system, Eyestalk and Muscle tissues during ontogenesis. We have isolated and purified a natural agglutinin in the hemolymph of P.indicus with antigenecity, agglutinating, hemolytic and antibacterial properties. The influence of growth and environmental parameters on the level of agglutinin in the hemolymph was studied. Agglutinin concentration during normal growth process was compared. The agglutinin concentration in the hemolymph was quantified through developing ELISA, which is useful in health monitoring studies of individual species. Complete amino acid composition of both the subunits of P.indicus agglutinin were analysed. P.indicus agglutinin showed similarity to those proteins having antigenecity,hemolytic and agglutinating properties.Hence, agglutinin was considered as a natural defence protein in the hemolymph of P.indicus responsible for immune surveillance. The humoral defence mechanism of agglutinin was a co-operative effort with hemocytes and complement system. The composition of isolated agglutinin of P.indicus amino acids will be helpful in the synthesis of new antibacterial analogues which can be used against disease causing organisms.
Description:
Dept. of Biotechnology, Cochin University of Science and Technology
Manjusha, K P; Dr.Saleena, Mathew(Cochin University of Science and Technology, April , 2011)
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Abstract:
The present study is aimed at the isolation and characterization of glycosaminoglycans from selected tissues of two commercially important species of cephalopods;squid,Loligo duvauceli and cuttlefish,Sepia pharaonis,keeping in view of the aforementioned benefits on the utilization of waste generated during processing.The cephalopod GAGs may also be expected to have an effect on various physiological functions based on the results obtained from GAGs from other sources.In addition,knowledge of the chemical structure of macromolecules that constitute major components of extracellular matrix(ECM) will be helpful in understanding their interactions with other matrix components.
Description:
School of Industrial Fisheries,
Cochin University of Science and Technology
Bijina, B; Dr. Chandrasekaran, M(Cochin University of Science & Technology, May , 2006)
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Abstract:
Protease inhibitors are one of the most important tools of nature for
regulating the proteolytic activity of their target proteases. They are
synthesized in biological systems and they play a critical role in controlling
a number of diverse physiological functions. The current investigation
focused on the isolation, purification and characterization of a novel
protease inhibitor from Moringa oleifera. The results obtained during the
course of study opens new perspectives for the utilization of protease
inhibitor from Moringa oleifera for various pharmaceutical, agricultural and
food industries. The biological and physicochemical properties exhibited by
the novel protease inhibitor from Moringa oleifera clearly testify its
suitability for the development as a drug for application in pharmaceutical
industries such as anticoagulant agent or biocontrol agent in agriculture and
even as a food preservant. There is a scope for further research on the
structure elucidation and protein engineering towards a wide range of
further applications. Detailed structure/function analysis of these proteins is
important to facilitate their use in genetic engineering for various
applications.
Description:
Department of Biotechnology,
Cocbin University of Science and Technology
Joshy, M K; Dr. Rani, Joseph(Cochin University of Science and Technology, October , 2007)
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Abstract:
The aim of this
investigation is to study the effectiveness of isora fibre as reinforcement material
in short and long forms, for unsaturated polyester and epoxy resins.Studies on the optimization of fibre length and fibre loading of
randomly oriented isora-polyester composite are described.The
salient features of the alkali treatment of short isora fibre on the properties of
randomly oriented isora-polyester composite are outlined in this thesis.The
effect of surface modification of the hydrophilic isora fibre by different chemical
treatments on the properties of randomly oriented isora-polyester composite is
outlined.The properties of oriented and
randomly oriented isora fibre reinforced epoxy composites with special reference
to the effect of fibre loading are reported and also the dynamic mechanical
properties ofthe oriented and randomly oriented isora-polyester and isora-epoxy
composites are presented and the water absorption kinetics
of oriented and randomly oriented isora-polyester composites and oriented isoraepoxy
composites are given. The effect of hot air oven aging on the tensile and
flexural properties of oriented isora-polyester and isora-epoxy composites are
also reported in this thesis.
Description:
Department of Polymer Science and Rubber Technology,Cochin University of
Science and Technology