Abdul Rasheed, T M; Nampoori, V P N; Sathianandan, K(Chemical Physics, 1986)
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Abstract:
The vibrational overtone spectra 0f the liquid phase 1,2-dichloroethane and 1,2-dibromoethane in the spectral regions of
CH stretching local mode overtones corresponding to delta v CH= = 2 to delta v CH=5 are reported. The observed spectral features are
assigned using the local mode model. LocaI mode frequencies WCH and diagonal local mode anharmonicities XCH are
obtained from an analysis of the spectra. The local-local combinations observed are interpreted on the basis of a coupled CH
oscillator model hamiltonian. Local-normal combinations show complex structures and their possible assignments are given.
Sudha Kartha, C; Ramachandran, T; Nampoori, V P N; Sathianandan, K(Solid State Communications, 1986)
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Abstract:
Variations in the decay times of the characteristic green emissions at 522.7, 551.3, 549.6, 547.6, 542.2, 540.2, 535.9 and 533.5nm from
CaF2 :H03+ with concentration are studied at RT and LNT. A pulsed N2
laser beam of power density 1.5 MW cm-2 is used for the excitation.
Temperature dependent concentration quenching of the decay times are
observed for all the emission bands. But an increase in the decay time due
to the reabsorption process is also observed for a few of the above bands.