Rani, Joseph(John Wiley & Sons, Inc., November 1, 2000)
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Abstract:
ABSTRACT: p-Phenylenediamine was chemically attached to low molecular weight chlorinated
paraffin wax. The polymer-bound p-phenylenediamine was characterized by
vapor-phase osmometry (VPO), proton magnetic resonance spectroscopy ('H-NMR),
infrared spectroscopy (IR), and thermogravimetric analysis (TGA). The efficiency and
permanence of the polymer-bound p-phenylenediamine as an antioxidant was compared
with a conventional amine-type antioxidant in natural rubber vulcanizates. The
vulcanizates showed improved aging resistance in comparison to vulcanizates containing
a conventional antioxidant. The presence of liquid polymer-bound p-phenylenediamine
also reduces the amount of the plasticizer required for compounding.