URI: | http://dyuthi.cusat.ac.in/purl/5219 |
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Dyuthi T-2254.pdf | (6.371Mb) |
Abstract: | Catalysis is a technologically important field which determines the quality of life in future. Catalyst research in pharmaceutical industry,fine chemical synthesis and emission control demands supported catalysts in bulk quantities.In the present work it was observed that clay supported catalysts mentioned in various chapters could also be used for the synthesis of similar molecules. The K10Ti catalyst can be used for the synthesis similar substituted imidazole derivatives under solvent free conditions and synthetically important Mannich bases of substrates containing various substitutes.Al-pillared saponite can be used for acetalation of other polyhydroxy compounds like glycerol,mannitol etc.Cu-Pd KSF catalyst has found application in C-C bond forming reactions which can be applied to other reactions and similar methods can be adopted for the synthesis of other catalyst by changing the transition metals. Montmorillonite K10 catalysed synthesis of triarylpyridines can be extended to the synthesis tetrasubstuted pyroles.K10Ti can also be utilized for the synthesis of similar heterocycles. |
Description: | Dept.of Applied Chemistry,Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/2934 |
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Dyuthi-T0925.pdf | (2.726Mb) |
Abstract: | The term 'organisation' is used in different contexts. In this study, organisation is considered as a 'socio—technical system. Alienation, as a term and as a theme, are found in many writings from very early times. But the concept and emphasis differ. The writers who have explained alienation includes theologians, philosophers, anthropologists, economists, political scientists, historians, psychologists and sociologists |
Description: | School of Management Studies, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3467 |
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Dyuthi-T1442.pdf | (6.746Mb) |
Abstract: | IT and related services played a major role for India’s current 9.2. GDP growth. Organized retailing in India is one more example for its open economy. The IT industries where able develop a demand for Indian talents all over the world and improved their living standards. It directly impacts only a small minority of Indian population while organized retail affects every single Indian and every sector of Indian society. The paper gives a glimpse of the slow evolution of retail market over the years in India and its contribution for economic growth. The likely positive impact of this revolution in different sectors is enumerated. Paper addresses its ability to manipulate consumption pattern of society, increased customer satisfaction and likely change in the market shares of the different types of sellers. Paper discusses its flip sides like increasing social tension among families below poverty line and greater loss of self employment opportunities by this revolution. The main theme of enquiry of this paper is what it all means for the Indian society. |
Description: | International Marketing Conference on Marketing & Society, 8-10 April, 2007, IIMK |
URI: | http://dyuthi.cusat.ac.in/purl/4482 |
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Organized Retai ... and the Indian Society.pdf | (216.9Kb) |
Abstract: | Knoevenagel condensation between carbonyl compounds and active methylene compounds as well as three component Mannich reaction between aldehydes, ketones and amines proceeded smoothly in water with good to excellent yield and high selectivity in the presence of zero and first generation poly(amidoamine) (PAMAM) dendrimers. The products and the catalyst were separated by simple biphasic extraction. The catalyst was found to be reusable. |
URI: | http://dyuthi.cusat.ac.in/xmlui/purl/1967 |
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Organocatalysis by poly...pdf | (240.0Kb) |
URI: | http://dyuthi.cusat.ac.in/xmlui/purl/1972 |
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K K M Yusuff,Organometallic Hydroxides ...pdf | (779.6Kb) |
Description: | CMFRI - Winter School Course Manual on “Recent Advances in Breeding and Larviculture of Marine Finfish and Shellfish”. 30.12.2008 - 19.1.2009 |
URI: | http://dyuthi.cusat.ac.in/purl/4084 |
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Ornamental Fish ... ir Management Measures.pdf | (90.89Kb) |
Abstract: | The vibrational overtone spectra 0f the liquid phase 1,2-dichloroethane and 1,2-dibromoethane in the spectral regions of CH stretching local mode overtones corresponding to delta v CH= = 2 to delta v CH=5 are reported. The observed spectral features are assigned using the local mode model. LocaI mode frequencies WCH and diagonal local mode anharmonicities XCH are obtained from an analysis of the spectra. The local-local combinations observed are interpreted on the basis of a coupled CH oscillator model hamiltonian. Local-normal combinations show complex structures and their possible assignments are given. |
URI: | http://dyuthi.cusat.ac.in/purl/2606 |
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Dyuthi-P0166.pdf | (472.3Kb) |
Abstract: | Vibrational overtone spectra of styrene (liquid) and polystyrene (solid), studied by the laser-induced thermal lens (for ΔV=6) and the conventional near infrared absorption (for ΔV=3–5) techniques, are reported. For polystyrene, the overtone energy-bond length correlation predicts that the aryl CH bonds are ∼0.0005 Å longer than that in benzene, while no such conclusions could be drawn on styrene. Thesp 3 CH overtones in polystyrene are observed on the low energy side of the aryl CH overtones. |
URI: | http://dyuthi.cusat.ac.in/purl/2631 |
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Dyuthi-P0190.pdf | (256.9Kb) |
Abstract: | The metal complex, [Ni(en)2(H2O)2](NO3)2 (en = ethylenediamine), was decomposed in a static furnace at 200 C by autogenous decomposition to obtain phase pure metallic nickel nanocrystallites. The nickel metal thus obtained was studied by XRD, IR spectra, SEM and CHN analysis. The nickel crystallites are in the nanometer range as indicated by XRD studies. The IR spectral studies and CHN analyses show that the surface is covered with a nitrogen containing species. Thermogravimetric mass gain shows that the product purity is high (93%). The formed nickel is stable and resistant to oxidation up to 350 C probably due to the coverage of nitrogen containing species. Activation energy for the oxidation of the prepared nickel nanocrystallites was determined by non-isothermal methods and was found to depend on the conversion ratio. The oxidation kinetics of the nickel crystallites obeyed a Johnson–Mehl–Avrami mechanism probably due to the special morphology and crystallite strain present on the metal. |
URI: | http://dyuthi.cusat.ac.in/purl/1654 |
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robinson j thermal analysis.pdf | (401.4Kb) |
Abstract: | A series of supported vanadia systems have been prepared by excess solvent technique using La203 and DY203 as supports. Physical characterization has been carried out using XRD, FTIR, TG studies, BET surface area measurement, pore volume analysis etc. Cyclohexanol decomposition has been used as a test reaction for evaluating the acid base properties of the supported system. The oxidative dehydrogenation of ethylbenzene has been employed as a chemical probe reaction to examine the catalytic activity. The active species correspond to amorphous and crystalline tetrahedral vanadyl units in the supported system. |
URI: | http://dyuthi.cusat.ac.in/purl/2211 |
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Dyuthi-SS13.pdf | (624.7Kb) |
Abstract: | We define a new graph operator called the P3 intersection graph, P3(G)- the intersection graph of all induced 3-paths in G. A characterization of graphs G for which P-3 (G) is bipartite is given . Forbidden subgraph characterization for P3 (G) having properties of being chordal , H-free, complete are also obtained . For integers a and b with a > 1 and b > a - 1, it is shown that there exists a graph G such that X(G) = a, X(P3( G)) = b, where X is the chromatic number of G. For the domination number -y(G), we construct graphs G such that -y(G) = a and -y (P3(G)) = b for any two positive numbers a > 1 and b. Similar construction for the independence number and radius, diameter relations are also discussed. |
URI: | http://dyuthi.cusat.ac.in/purl/1531 |
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Utilities Mathematica.PDF | (5.904Mb) |
Abstract: | Packaging is important not only in extending the shellife of fish and fishery products but also improving their marketability. In the recent years, significant development have taken place in the packaging industry. During the past decade in India, there is almost a packaging revolution with the availability of variety packaging materials, thus generating better packaging consciousness in other producer/manufacturing industries. But unfortunately, such realisation is not forthcoming in the fisheries sector and packaging techniques for local and export trade continues to be on traditional lines with their inherent drawbacks and limitations. Better packaging ensures improved quality and presentation of the products and ensures higher returns to the producer. Among several packaging materials used in fishery industry, ISI specifications had been formulated only for corrugated fibre board boxes for export of seafoods and froglegs. This standard was formulated before containersiation came into existance in the export of marine products. Before containerisation, the standards were stringent in view of the rough handling, transportation and storage. Two of the common defects reported in the master cartons exported from India are low mechanical strength and tendency to get wet. They are weakened by the deposits of moisture caused by temperature fluctuations during loading, unloading and other handling stages. It is necessary to rectify the above defects in packaging aquatic products and hence in the present study extensive investigations are carried out to find out the reasons for the damage of master cartons, to evolve code of practice for the packaging oi frozen shrimp for exports, development of alternative style of packaging for the shipping container, development of suitable consumer packaging materials for fish soup powder, cured dried mackeral, fish pickles in oil and frozen shrimp. For the development of suitable packaging materials, it is absolutely essential to know the properties of packaging materials, effect of different packaging materials on theirshelf life and their suitability for food contact applications. |
Description: | Department of Industrial Fisheries, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3233 |
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Dyuthi-T1207.pdf | (5.847Mb) |
Description: | School of Environmental Studies, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/2927 |
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Dyuthi-T0918.pdf | (3.409Mb) |
Abstract: | The reactions involving fulvenes and its derivatives have received a great deal of attention over the years in synthetic organic chemistry. Functionalizations of fulvenes provide versatile and powerful approaches to various polycyclic systems and natural products. They serve as versatile intermediates in the construction of various ring systems through inter- as well as intramolecular cycloadditions. Compared to the rich literature on the cycloaddition reactions of pentafulvenes, much less attention has been paid to the synthetic utilization of their cycloadducts. Tactical manipulations on the chosen adduct offer the prospects for designing a variety of useful molecular skeletons. Addition of heterodienophiles to fulvenes offers an efficient strategy towards the synthesis of azabicyclic olefins. However, there have been no serious attempts to study the synthetic utility of these substrates. In this context and with the intention of utilizing pentafulvenes towards synthetically important molecules, author decided to explore the reactivity of pentafulvene derived azabicyclic olefins. Our attention was focused on the synthetic potential associated with the ring opening of fulvene derived bicyclic hydrazines under palladium catalysis. It was envisioned that the desymmetrization of these adducts using various soft nucleophiles will provide a novel access to synthetically and biologically important alkylidene cyclopentenes. The investigations along this line form the focal theme of this thesis entitled “PALLADIUM CATALYZED CARBONCARBON/ CARBON-HETEROATOM BOND FORMATION REACTIONS UTILIZING PENTAFULVENE DERIVED BICYCLIC HYDRAZINES |
Description: | Organic Chemistry Section, National Institute for Interdisciplinary Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3536 |
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Dyuthi-T1505.pdf | (2.395Mb) |
Abstract: | Paper industry is one of the oldest and largest industries in Kerala. Despite the developments in the industry in terms of growth in output , value added and employment generation, many of the units face grave problems. Irrespective of the size of the plant, the problems of the industry are general in nature. The problems are galore in the supply, not the demand side. Amomg the problems, the important ones are: raw material scarcity, energy deficiency and obsolete technology. Further, the industry is subject to many controls by the Government — price control, product control and raw materials control — which result in the dwindling of profits and investments. Equally important are the reservations against the industry for polluting the environment byeffluent disposal on the one hand and affecting ecological balance by depleting the existing forest on the other. Apart from the large, medium and small pulp and paper mills, there are about 30 hand made paper units in Kerala which can be categorised as village and cottage industry. Almost all of these units began at the initiative and support of Khadi and Village Industries Commission. The primary purpose of these units is employment generation, and not profit making. Currently many of these units are in the red and many others are on the verge of closure. Therefore, a separate analysis of the growth performance, and problems and prospects of the hand made paper industry has also been attempted. It is analysed separately because of the very small size of the hand made paper units |
Description: | Department of Applied Economics, Cochin University of Science and Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3638 |
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Dyuthi-T1617.pdf | (6.214Mb) |
Abstract: | This work proposes a parallel genetic algorithm for compressing scanned document images. A fitness function is designed with Hausdorff distance which determines the terminating condition. The algorithm helps to locate the text lines. A greater compression ratio has achieved with lesser distortion |
Description: | 2010 International Conference on Electronics and Information Engineering (ICEIE 2010) vol 2,V2-483-V2-487 |
URI: | http://dyuthi.cusat.ac.in/purl/4215 |
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Parallel Geneti ... mpression Optimization.pdf | (793.8Kb) |
Abstract: | In this article it is proved that the stationary Markov sequences generated by minification models are ergodic and uniformly mixing. These results are used to establish the optimal properties of estimators for the parameters in the model. The problem of estimating the parameters in the exponential minification model is discussed in detail. |
URI: | http://dyuthi.cusat.ac.in/xmlui/purl/2105 |
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Parameter Estimation in Minification Processes.pdf | (212.4Kb) |
URI: | http://dyuthi.cusat.ac.in/purl/1234 |
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Jalajakumar V S 1989.PDF | (385.2Kb) |
Abstract: | In order to check the damage caused by the parasites, even though it is difficult in open waters, a proper understanding of the seasonal variation in the distribution of the parasite and other factors like age of the host, sex of the host, which affect distribution of parasite is a must. Although several workers have carried out investigations on the taxonomy of metazoan parasites of marine and brackish water Fishes of India, very little attempt is made to correlate such investigations with the host and the environment. In this thesis such an attempt is made by the researcher. In chapter one the literature related to the prevalence, mean intensity of infection, and histopathological changes caused by the metazoan parasites, in particular by helminths, copepods and isopods, was reviewed. Chapter two contains observations on the distribution pattern of parasites in relation to the season, sex, and size of the host. It was found that the prevalence rate of radiorynchus_indicus infecting the alimentary canal of Tachysurugs mgacuglatus, Ergasilus sp. infecting the gills of T maculatus, and Lernaeeniicus ramosus found on the body surface of Qeimgipteirfugs jagonicus was higher during monsoon season. But agarna malayi found in the opercular chamber and Ehilometra cephalus infecting the gonads of valamugil speiglari showed a higher prevalence rate during the postmonsoon season. This was discussed on the basis of the hydrographical characteristics prevailing in the study area during the three different seasons. It was also observed that the sex of the host did not influence significantly the distribution pattern of the parasites. The reasons for this were also discussed. Invariably, the size of the host was found to influence the parasite distribution pattern. It was observed that the prevalence rate showed an increase with increase in size of the fish. This was discussed on the basis of food habits of the host, along with other aspects An attempt was made in chapter three to study the histopathological effects of‘ the various parasites on their respective sites of attachments on host Fishes. It was found that except Rhadinorhyhchugs indicus, all other parasites produced damages of varying intensity, in the form of hypertrophy, rhyperplasia, haemorrhage, tissue disruption and ulcers. Interestingly, E. indicus, an acantho— cephalid with a powerful proboscis for attachment was found not to cause any serious damage to the intestine of the host Fish. All these aspects are included in the third and final chapter of the thesis. |
Description: | School of marine sciences, Cochin University of Science And Technology |
URI: | http://dyuthi.cusat.ac.in/purl/3290 |
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Dyuthi-T1272.pdf | (14.01Mb) |
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